Compatibility enhancement of silica and natural rubber compound using UVA-induced silane-grafted saponified skim natural rubber
Silane coupling agents are potential reagents widely used to improve the compatibility between silica and less polar rubber, especially natural rubber (NR). Nevertheless, high temperature is generally required to generate the interaction between the components during the mixing process. Accordingly,...
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| Veröffentlicht in: | Journal of polymer research 2018, Vol.25 (1), p.1-12, Article 17 |
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| container_title | Journal of polymer research |
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| creator | Dechnarong, Nattanee Nimpaiboon, Adun Kumarn, Sirirat Phinyocheep, Pranee Sakdapipanich, Jitladda |
| description | Silane coupling agents are potential reagents widely used to improve the compatibility between silica and less polar rubber, especially natural rubber (NR). Nevertheless, high temperature is generally required to generate the interaction between the components during the mixing process. Accordingly, an alternative method by grafting the silane coupling agent onto the rubber molecules would be a desirable approach to develop a compatibilizer for the silica-filled NR compound. In this work, skim NR was used as a starting material due to its linear structure. The optimal conditions of the grafting reaction were found to be 1 phr of an alkoxy silane and 5 phr of benzoyl peroxide under 8 min of UVA irradiation time. These conditions were applied for producing the rubber material used in the mixing process of STR 5L and silica. The cure characteristics, silica dispersion and mechanical properties of the rubber compounds were improved, suggesting that the modified rubber was an efficient material for increasing the compatibility between silica and NR. |
| doi_str_mv | 10.1007/s10965-017-1420-3 |
| format | Article |
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Nevertheless, high temperature is generally required to generate the interaction between the components during the mixing process. Accordingly, an alternative method by grafting the silane coupling agent onto the rubber molecules would be a desirable approach to develop a compatibilizer for the silica-filled NR compound. In this work, skim NR was used as a starting material due to its linear structure. The optimal conditions of the grafting reaction were found to be 1 phr of an alkoxy silane and 5 phr of benzoyl peroxide under 8 min of UVA irradiation time. These conditions were applied for producing the rubber material used in the mixing process of STR 5L and silica. The cure characteristics, silica dispersion and mechanical properties of the rubber compounds were improved, suggesting that the modified rubber was an efficient material for increasing the compatibility between silica and NR.</description><identifier>ISSN: 1022-9760</identifier><identifier>EISSN: 1572-8935</identifier><identifier>DOI: 10.1007/s10965-017-1420-3</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Benzoyl peroxide ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Compatibility ; Coupling (molecular) ; Coupling agents ; Grafting ; Industrial Chemistry/Chemical Engineering ; Mechanical properties ; Natural rubber ; Original Paper ; Polymer Sciences ; Reagents ; Rubber ; Silicon dioxide</subject><ispartof>Journal of polymer research, 2018, Vol.25 (1), p.1-12, Article 17</ispartof><rights>Springer Science+Business Media B.V., part of Springer Nature 2017</rights><rights>Journal of Polymer Research is a copyright of Springer, (2017). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-6f9e41ade1f267a03095ed59285eb2b1c83abf6b9b0719516170cb75f952d9ef3</citedby><cites>FETCH-LOGICAL-c316t-6f9e41ade1f267a03095ed59285eb2b1c83abf6b9b0719516170cb75f952d9ef3</cites><orcidid>0000-0001-5812-4186</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10965-017-1420-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10965-017-1420-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Dechnarong, Nattanee</creatorcontrib><creatorcontrib>Nimpaiboon, Adun</creatorcontrib><creatorcontrib>Kumarn, Sirirat</creatorcontrib><creatorcontrib>Phinyocheep, Pranee</creatorcontrib><creatorcontrib>Sakdapipanich, Jitladda</creatorcontrib><title>Compatibility enhancement of silica and natural rubber compound using UVA-induced silane-grafted saponified skim natural rubber</title><title>Journal of polymer research</title><addtitle>J Polym Res</addtitle><description>Silane coupling agents are potential reagents widely used to improve the compatibility between silica and less polar rubber, especially natural rubber (NR). Nevertheless, high temperature is generally required to generate the interaction between the components during the mixing process. Accordingly, an alternative method by grafting the silane coupling agent onto the rubber molecules would be a desirable approach to develop a compatibilizer for the silica-filled NR compound. In this work, skim NR was used as a starting material due to its linear structure. The optimal conditions of the grafting reaction were found to be 1 phr of an alkoxy silane and 5 phr of benzoyl peroxide under 8 min of UVA irradiation time. These conditions were applied for producing the rubber material used in the mixing process of STR 5L and silica. The cure characteristics, silica dispersion and mechanical properties of the rubber compounds were improved, suggesting that the modified rubber was an efficient material for increasing the compatibility between silica and NR.</description><subject>Benzoyl peroxide</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Compatibility</subject><subject>Coupling (molecular)</subject><subject>Coupling agents</subject><subject>Grafting</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Mechanical properties</subject><subject>Natural rubber</subject><subject>Original Paper</subject><subject>Polymer Sciences</subject><subject>Reagents</subject><subject>Rubber</subject><subject>Silicon dioxide</subject><issn>1022-9760</issn><issn>1572-8935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kEtLAzEUhYMoWKs_wF3AdTTJNMlkWYovKLixbkOSSWpqJ1OTmUVX_nUzjAsRhAv3wfnOhQPANcG3BGNxlwmWnCFMBCILilF1AmaECYpqWbHTMmNKkRQcn4OLnHcYMyZ4PQNfq6496D6YsA_9Ebr4rqN1rYs97DzM5Wo11LGBUfdD0nuYBmNcgrZg3VDuQw5xCzdvSxRiM1jXjJCODm2T9v246kMXgw_j-BHaP0aX4MzrfXZXP30ONg_3r6sntH55fF4t18hWhPeIe-kWRDeOeMqFxhWWzDVM0po5Qw2xdaWN50YaLIhkhBOBrRHMS0Yb6Xw1BzeT7yF1n4PLvdp1Q4rlpSJSSCF4qaIik8qmLufkvDqk0Op0VASrMWc15axKzmrMWVWFoROTizZuXfrl_C_0DRKIgpU</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Dechnarong, Nattanee</creator><creator>Nimpaiboon, Adun</creator><creator>Kumarn, Sirirat</creator><creator>Phinyocheep, Pranee</creator><creator>Sakdapipanich, Jitladda</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0001-5812-4186</orcidid></search><sort><creationdate>2018</creationdate><title>Compatibility enhancement of silica and natural rubber compound using UVA-induced silane-grafted saponified skim natural rubber</title><author>Dechnarong, Nattanee ; 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| subjects | Benzoyl peroxide Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Compatibility Coupling (molecular) Coupling agents Grafting Industrial Chemistry/Chemical Engineering Mechanical properties Natural rubber Original Paper Polymer Sciences Reagents Rubber Silicon dioxide |
| title | Compatibility enhancement of silica and natural rubber compound using UVA-induced silane-grafted saponified skim natural rubber |
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