Synthesis and characterization of Ln2O2SO4 (Ln = Gd, Ho, Dy and Lu) nanoparticles obtained by coprecipitation method and study of their reduction reaction under H2 flow
We have proposed an optimized homogeneous precipitation method for the synthesis of spherical and well-dispersed pure Ln 2 O 2 SO 4 (Ln = Gd, Ho, Dy and Lu) nanoparticles (NPs) using synthesized lanthanide sulfates and urea as starting materials. Ln 2 O 2 SO 4 NPs can be easily transformed to Ln 2 O...
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| Veröffentlicht in: | Journal of nanostructure in chemistry 2017-12, Vol.7 (4), p.337-343 |
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| container_title | Journal of nanostructure in chemistry |
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| creator | Osseni, Sèmiyou. A. Denisenko, Yu. G. Fatombi, Jacques. K. Sal’nikova, Elena. I. Andreev, Oleeg. V. |
| description | We have proposed an optimized homogeneous precipitation method for the synthesis of spherical and well-dispersed pure Ln
2
O
2
SO
4
(Ln = Gd, Ho, Dy and Lu) nanoparticles (NPs) using synthesized lanthanide sulfates and urea as starting materials. Ln
2
O
2
SO
4
NPs can be easily transformed to Ln
2
O
2
S by reduction under H
2
flow at 650 °C for Gd, Dy and Ho whereas the reduction with Lu gave only Lu
2
O
3
. Particle size was between 500 nm and 3.5 µm. This reduction method allows to obtain Ln
2
O
2
S without using H
2
S which is highly toxic and uncomfortable gas. Ln
2
O
2
SO
4
/Ln
2
O
2
S synthetized can be used for release and oxygen storage or doped with luminescent centers for multimodal medical imaging applications.
Graphical abstract |
| doi_str_mv | 10.1007/s40097-017-0243-4 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1977295083</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1977295083</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2744-268b6aa10090422d62e76937552b729b8a1fcdd9b6806c1fc24ac93d4e3e34953</originalsourceid><addsrcrecordid>eNp1kc1KAzEUhQdRsGgfwF3AjUJHM0nmJwsX4k8rDHRRXYdMkrEpbTImGWR8Ih_TtOPCjRfCPYtzvgs5SXKRwZsMwvLWEwhpmcIsPkRwSo6SCcooTquqyI-jhrBKKSLkNJl6v4FxKMW0gpPkezWYsFZee8CNBGLNHRdBOf3Fg7YG2BbUBi3RaknAVW3AHZjLGVjYGXgcDom6vwaGG9txF7TYKg9sE7g2SoJmAMJ2Tgnd6TDidiqsrTwEfejlsOfH89oBp2QvDh6n-Ch6I5UDCwTarf08T05avvVq-rvPkrfnp9eHRVov5y8P93UqUElIioqqKTiP30IhQUgWSJUFxWWeo6ZEtKl41gopaVNUsBBRI8IFxZIorDChOT5LLkdu5-xHr3xgG9s7E0-yjJYRkcMKR1c2uoSz3jvVss7pHXcDyyDbd8LGTljshO07YSRm0Jjx0WvelftD_jf0A50JjlQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1977295083</pqid></control><display><type>article</type><title>Synthesis and characterization of Ln2O2SO4 (Ln = Gd, Ho, Dy and Lu) nanoparticles obtained by coprecipitation method and study of their reduction reaction under H2 flow</title><source>SpringerLink Journals</source><creator>Osseni, Sèmiyou. A. ; Denisenko, Yu. G. ; Fatombi, Jacques. K. ; Sal’nikova, Elena. I. ; Andreev, Oleeg. V.</creator><creatorcontrib>Osseni, Sèmiyou. A. ; Denisenko, Yu. G. ; Fatombi, Jacques. K. ; Sal’nikova, Elena. I. ; Andreev, Oleeg. V.</creatorcontrib><description>We have proposed an optimized homogeneous precipitation method for the synthesis of spherical and well-dispersed pure Ln
2
O
2
SO
4
(Ln = Gd, Ho, Dy and Lu) nanoparticles (NPs) using synthesized lanthanide sulfates and urea as starting materials. Ln
2
O
2
SO
4
NPs can be easily transformed to Ln
2
O
2
S by reduction under H
2
flow at 650 °C for Gd, Dy and Ho whereas the reduction with Lu gave only Lu
2
O
3
. Particle size was between 500 nm and 3.5 µm. This reduction method allows to obtain Ln
2
O
2
S without using H
2
S which is highly toxic and uncomfortable gas. Ln
2
O
2
SO
4
/Ln
2
O
2
S synthetized can be used for release and oxygen storage or doped with luminescent centers for multimodal medical imaging applications.
Graphical abstract</description><identifier>ISSN: 2008-9244</identifier><identifier>EISSN: 2193-8865</identifier><identifier>DOI: 10.1007/s40097-017-0243-4</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Chemistry ; Chemistry and Materials Science ; Computer Applications in Chemistry ; Dysprosium ; Gadolinium ; Hydrogen sulfide ; Inorganic Chemistry ; Medical imaging ; Nanochemistry ; Nanoparticles ; Organic Chemistry ; Original Research ; Physical Chemistry ; Polymer Sciences ; Reduction ; Synthesis</subject><ispartof>Journal of nanostructure in chemistry, 2017-12, Vol.7 (4), p.337-343</ispartof><rights>The Author(s) 2017</rights><rights>Journal of Nanostructure in Chemistry is a copyright of Springer, (2017). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2744-268b6aa10090422d62e76937552b729b8a1fcdd9b6806c1fc24ac93d4e3e34953</citedby><cites>FETCH-LOGICAL-c2744-268b6aa10090422d62e76937552b729b8a1fcdd9b6806c1fc24ac93d4e3e34953</cites><orcidid>0000-0002-2436-4728</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s40097-017-0243-4$$EPDF$$P50$$Gspringer$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s40097-017-0243-4$$EHTML$$P50$$Gspringer$$Hfree_for_read</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Osseni, Sèmiyou. A.</creatorcontrib><creatorcontrib>Denisenko, Yu. G.</creatorcontrib><creatorcontrib>Fatombi, Jacques. K.</creatorcontrib><creatorcontrib>Sal’nikova, Elena. I.</creatorcontrib><creatorcontrib>Andreev, Oleeg. V.</creatorcontrib><title>Synthesis and characterization of Ln2O2SO4 (Ln = Gd, Ho, Dy and Lu) nanoparticles obtained by coprecipitation method and study of their reduction reaction under H2 flow</title><title>Journal of nanostructure in chemistry</title><addtitle>J Nanostruct Chem</addtitle><description>We have proposed an optimized homogeneous precipitation method for the synthesis of spherical and well-dispersed pure Ln
2
O
2
SO
4
(Ln = Gd, Ho, Dy and Lu) nanoparticles (NPs) using synthesized lanthanide sulfates and urea as starting materials. Ln
2
O
2
SO
4
NPs can be easily transformed to Ln
2
O
2
S by reduction under H
2
flow at 650 °C for Gd, Dy and Ho whereas the reduction with Lu gave only Lu
2
O
3
. Particle size was between 500 nm and 3.5 µm. This reduction method allows to obtain Ln
2
O
2
S without using H
2
S which is highly toxic and uncomfortable gas. Ln
2
O
2
SO
4
/Ln
2
O
2
S synthetized can be used for release and oxygen storage or doped with luminescent centers for multimodal medical imaging applications.
Graphical abstract</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Computer Applications in Chemistry</subject><subject>Dysprosium</subject><subject>Gadolinium</subject><subject>Hydrogen sulfide</subject><subject>Inorganic Chemistry</subject><subject>Medical imaging</subject><subject>Nanochemistry</subject><subject>Nanoparticles</subject><subject>Organic Chemistry</subject><subject>Original Research</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Reduction</subject><subject>Synthesis</subject><issn>2008-9244</issn><issn>2193-8865</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>BENPR</sourceid><recordid>eNp1kc1KAzEUhQdRsGgfwF3AjUJHM0nmJwsX4k8rDHRRXYdMkrEpbTImGWR8Ih_TtOPCjRfCPYtzvgs5SXKRwZsMwvLWEwhpmcIsPkRwSo6SCcooTquqyI-jhrBKKSLkNJl6v4FxKMW0gpPkezWYsFZee8CNBGLNHRdBOf3Fg7YG2BbUBi3RaknAVW3AHZjLGVjYGXgcDom6vwaGG9txF7TYKg9sE7g2SoJmAMJ2Tgnd6TDidiqsrTwEfejlsOfH89oBp2QvDh6n-Ch6I5UDCwTarf08T05avvVq-rvPkrfnp9eHRVov5y8P93UqUElIioqqKTiP30IhQUgWSJUFxWWeo6ZEtKl41gopaVNUsBBRI8IFxZIorDChOT5LLkdu5-xHr3xgG9s7E0-yjJYRkcMKR1c2uoSz3jvVss7pHXcDyyDbd8LGTljshO07YSRm0Jjx0WvelftD_jf0A50JjlQ</recordid><startdate>20171201</startdate><enddate>20171201</enddate><creator>Osseni, Sèmiyou. A.</creator><creator>Denisenko, Yu. G.</creator><creator>Fatombi, Jacques. K.</creator><creator>Sal’nikova, Elena. I.</creator><creator>Andreev, Oleeg. V.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0002-2436-4728</orcidid></search><sort><creationdate>20171201</creationdate><title>Synthesis and characterization of Ln2O2SO4 (Ln = Gd, Ho, Dy and Lu) nanoparticles obtained by coprecipitation method and study of their reduction reaction under H2 flow</title><author>Osseni, Sèmiyou. A. ; Denisenko, Yu. G. ; Fatombi, Jacques. K. ; Sal’nikova, Elena. I. ; Andreev, Oleeg. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2744-268b6aa10090422d62e76937552b729b8a1fcdd9b6806c1fc24ac93d4e3e34953</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Computer Applications in Chemistry</topic><topic>Dysprosium</topic><topic>Gadolinium</topic><topic>Hydrogen sulfide</topic><topic>Inorganic Chemistry</topic><topic>Medical imaging</topic><topic>Nanochemistry</topic><topic>Nanoparticles</topic><topic>Organic Chemistry</topic><topic>Original Research</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Reduction</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Osseni, Sèmiyou. A.</creatorcontrib><creatorcontrib>Denisenko, Yu. G.</creatorcontrib><creatorcontrib>Fatombi, Jacques. K.</creatorcontrib><creatorcontrib>Sal’nikova, Elena. I.</creatorcontrib><creatorcontrib>Andreev, Oleeg. V.</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Journal of nanostructure in chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Osseni, Sèmiyou. A.</au><au>Denisenko, Yu. G.</au><au>Fatombi, Jacques. K.</au><au>Sal’nikova, Elena. I.</au><au>Andreev, Oleeg. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of Ln2O2SO4 (Ln = Gd, Ho, Dy and Lu) nanoparticles obtained by coprecipitation method and study of their reduction reaction under H2 flow</atitle><jtitle>Journal of nanostructure in chemistry</jtitle><stitle>J Nanostruct Chem</stitle><date>2017-12-01</date><risdate>2017</risdate><volume>7</volume><issue>4</issue><spage>337</spage><epage>343</epage><pages>337-343</pages><issn>2008-9244</issn><eissn>2193-8865</eissn><abstract>We have proposed an optimized homogeneous precipitation method for the synthesis of spherical and well-dispersed pure Ln
2
O
2
SO
4
(Ln = Gd, Ho, Dy and Lu) nanoparticles (NPs) using synthesized lanthanide sulfates and urea as starting materials. Ln
2
O
2
SO
4
NPs can be easily transformed to Ln
2
O
2
S by reduction under H
2
flow at 650 °C for Gd, Dy and Ho whereas the reduction with Lu gave only Lu
2
O
3
. Particle size was between 500 nm and 3.5 µm. This reduction method allows to obtain Ln
2
O
2
S without using H
2
S which is highly toxic and uncomfortable gas. Ln
2
O
2
SO
4
/Ln
2
O
2
S synthetized can be used for release and oxygen storage or doped with luminescent centers for multimodal medical imaging applications.
Graphical abstract</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s40097-017-0243-4</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-2436-4728</orcidid><oa>free_for_read</oa></addata></record> |
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| issn | 2008-9244 2193-8865 |
| language | eng |
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| subjects | Chemistry Chemistry and Materials Science Computer Applications in Chemistry Dysprosium Gadolinium Hydrogen sulfide Inorganic Chemistry Medical imaging Nanochemistry Nanoparticles Organic Chemistry Original Research Physical Chemistry Polymer Sciences Reduction Synthesis |
| title | Synthesis and characterization of Ln2O2SO4 (Ln = Gd, Ho, Dy and Lu) nanoparticles obtained by coprecipitation method and study of their reduction reaction under H2 flow |
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