Promising Cu-doped polyvinyl alcohol films for optical and photoconductive applications

Pure and Cu-doped Poly Vinyl Alcohol (PVA) film samples with different concentrations of copper (5%, 10%, 15% and 20% weight percent) were prepared by the conventional castling technique. The structural, optical and photoconductive properties of pure and doped films were studied. X-ray diffraction p...

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Veröffentlicht in:Physica. B, Condensed matter Condensed matter, 2017-12, Vol.527, p.24-29
Hauptverfasser: Ali, F.M., Ashraf, I.M., Alqahtani, Sh.M.
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description Pure and Cu-doped Poly Vinyl Alcohol (PVA) film samples with different concentrations of copper (5%, 10%, 15% and 20% weight percent) were prepared by the conventional castling technique. The structural, optical and photoconductive properties of pure and doped films were studied. X-ray diffraction pattern of the investigated samples reveals the interaction between the filler and polymer which leads to decrease the crystallinity with riching amorphous phase. Optical spectrophotometric measurements showed blocking of UV range in transmission spectra of 20% wt Cu-content where the determined indirect Optical energy gap strongly decrease from 4.96eV for pure PVA to about 2.85eV for this sample. Film samples exhibit positive photoconduction effect where the light reduce the resistance or increases its conduction in addition to that photosensitivity strongly increase by increasing both light intensity and copper concentration in the polymer matrix.
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The structural, optical and photoconductive properties of pure and doped films were studied. X-ray diffraction pattern of the investigated samples reveals the interaction between the filler and polymer which leads to decrease the crystallinity with riching amorphous phase. Optical spectrophotometric measurements showed blocking of UV range in transmission spectra of 20% wt Cu-content where the determined indirect Optical energy gap strongly decrease from 4.96eV for pure PVA to about 2.85eV for this sample. Film samples exhibit positive photoconduction effect where the light reduce the resistance or increases its conduction in addition to that photosensitivity strongly increase by increasing both light intensity and copper concentration in the polymer matrix.</description><identifier>ISSN: 0921-4526</identifier><identifier>EISSN: 1873-2135</identifier><identifier>DOI: 10.1016/j.physb.2017.09.107</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Casting technique ; Conductivity ; Copper ; Diffraction ; Diffraction patterns ; Doped films ; Energy gap ; Energy transmission ; Luminous intensity ; Optical absorption ; Optical properties ; Optics ; Photoconductivity ; Photosensitivity ; Polymer films ; Polymers ; Polyvinyl alcohol ; Spectrophotometry</subject><ispartof>Physica. 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subjects Casting technique
Conductivity
Copper
Diffraction
Diffraction patterns
Doped films
Energy gap
Energy transmission
Luminous intensity
Optical absorption
Optical properties
Optics
Photoconductivity
Photosensitivity
Polymer films
Polymers
Polyvinyl alcohol
Spectrophotometry
title Promising Cu-doped polyvinyl alcohol films for optical and photoconductive applications
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