Effect of the tether length upon Truce‐Smiles rearrangement reactions

This report examines the effect of substrate design upon the Truce‐Smiles rearrangement, an intramolecular nucleophilic aromatic substitution reaction. The length of the molecular spacer that tethers the carbanion nucleophile to the substituted benzene ring was found to have a strong influence on th...

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Veröffentlicht in:	Journal of physical organic chemistry 2018-01, Vol.31 (1), p.n/a
Hauptverfasser:	Fuss, David, Wu, Yu Qi, Grossi, Michael R., Hollett, Joshua W., Wood, Tabitha E.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds aromatic substitution Benzene cyclization nucleophilic substitution rearrangement Substitution reactions Substrates synthetic methods Tethers
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