Tailoring the Hydrothermal Synthesis of Stainless Steel Wire Sieve-Supported Ag-Doped ZnO Nanowires to Optimize Their Photo-catalytic Activity

Batches of un-doped and Ag-doped ZnO nanowires (ZnONWs) were prepared hydrothermally on stainless steel wire sieves at varied Zn 2+ concentrations of the growth solution and at different Ag + concentrations of the silver nitrate solution. Methylene blue solution was degraded with these as-prepared Z...

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Veröffentlicht in:Journal of electronic materials 2018-03, Vol.47 (3), p.1847-1858
Hauptverfasser: Jing, W. X., Shi, J. F., Xu, Z. P., Jiang, Z. D., Wei, Z. Y., Zhou, F., Wu, Q., Cui, Q. B.
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container_issue 3
container_start_page 1847
container_title Journal of electronic materials
container_volume 47
creator Jing, W. X.
Shi, J. F.
Xu, Z. P.
Jiang, Z. D.
Wei, Z. Y.
Zhou, F.
Wu, Q.
Cui, Q. B.
description Batches of un-doped and Ag-doped ZnO nanowires (ZnONWs) were prepared hydrothermally on stainless steel wire sieves at varied Zn 2+ concentrations of the growth solution and at different Ag + concentrations of the silver nitrate solution. Methylene blue solution was degraded with these as-prepared ZnONWs in the presences of ultraviolet irradiation. It is found that both the processing parameters greatly affect the surface textures, wettability, and photo-activity of the ZnONWs. The latter synthesizing parameter is optimized only after the former one has been finely regulated. The un-doped and Ag-doped ZnONWs at Zn 2+ concentration of 75 mM of the growth solution and at Ag + concentration of3 mM of the silver nitrate solution both produce Gaussian rough surfaces and in each batch are most hydrophilic. Therefore, in the related batch the contacting surface area of the catalyst is the largest, the hydroxyl radicals attached on the top ends of corresponding ZnONWs the most, and the catalytic activity of these catalysts the optimal. Besides these, the latter synthesizing parameter affects the photo-activity of Ag-doped ZnONWs more significantly than the former one does that of un-doped ZnONWs.
doi_str_mv 10.1007/s11664-017-5972-0
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X. ; Shi, J. F. ; Xu, Z. P. ; Jiang, Z. D. ; Wei, Z. Y. ; Zhou, F. ; Wu, Q. ; Cui, Q. B.</creator><creatorcontrib>Jing, W. X. ; Shi, J. F. ; Xu, Z. P. ; Jiang, Z. D. ; Wei, Z. Y. ; Zhou, F. ; Wu, Q. ; Cui, Q. B.</creatorcontrib><description>Batches of un-doped and Ag-doped ZnO nanowires (ZnONWs) were prepared hydrothermally on stainless steel wire sieves at varied Zn 2+ concentrations of the growth solution and at different Ag + concentrations of the silver nitrate solution. Methylene blue solution was degraded with these as-prepared ZnONWs in the presences of ultraviolet irradiation. It is found that both the processing parameters greatly affect the surface textures, wettability, and photo-activity of the ZnONWs. The latter synthesizing parameter is optimized only after the former one has been finely regulated. The un-doped and Ag-doped ZnONWs at Zn 2+ concentration of 75 mM of the growth solution and at Ag + concentration of3 mM of the silver nitrate solution both produce Gaussian rough surfaces and in each batch are most hydrophilic. Therefore, in the related batch the contacting surface area of the catalyst is the largest, the hydroxyl radicals attached on the top ends of corresponding ZnONWs the most, and the catalytic activity of these catalysts the optimal. 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subjects Catalysis
Catalysts
Catalytic activity
Characterization and Evaluation of Materials
Chemical synthesis
Chemistry and Materials Science
Electronics and Microelectronics
Hydroxyl radicals
Instrumentation
Materials research
Materials Science
Methylene blue
Nanowires
Optical and Electronic Materials
Optimization
Process parameters
Silver
Solid State Physics
Stainless steel
Stainless steels
Steel wire
Ultraviolet radiation
Wettability
Zinc oxide
title Tailoring the Hydrothermal Synthesis of Stainless Steel Wire Sieve-Supported Ag-Doped ZnO Nanowires to Optimize Their Photo-catalytic Activity
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