Ziminaite, Fe3+VO4, a new howardevansite-group mineral from the Bezymyannyi volcano, Kamchatka, Russia

The new mineral ziminaite, ideally Fe 3+ VO 4 , was found in fumarole sublimates at the Bezymyannyi volcano, Kamchatka, Russia. Ziminaite occurs as lamellar, tabular or flattened prismatic crystals up to 10 × 30 × 50 μm typically epitaxially overgrowing koksharovite, and as aggregates (up to 0.15 mm...

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Veröffentlicht in:Mineralogy and petrology 2018-06, Vol.112 (3), p.371-379
Hauptverfasser: Pekov, Igor V., Siidra, Oleg I., Yapaskurt, Vasiliy O., Polekhovsky, Yury S., Kartashov, Pavel M.
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container_title Mineralogy and petrology
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Siidra, Oleg I.
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Polekhovsky, Yury S.
Kartashov, Pavel M.
description The new mineral ziminaite, ideally Fe 3+ VO 4 , was found in fumarole sublimates at the Bezymyannyi volcano, Kamchatka, Russia. Ziminaite occurs as lamellar, tabular or flattened prismatic crystals up to 10 × 30 × 50 μm typically epitaxially overgrowing koksharovite, and as aggregates (up to 0.15 mm) associated with bannermanite in cavities in volcanic scoria. The mineral is translucent, yellowish-brown with an adamantine luster. The calculated density is 3.45 g cm − 3 . In reflected light, ziminaite is light grey. Bireflectance is weak, internal reflections are deep yellow. The reflectance values [ R max –R min , % (λ, nm)] are: 17.7–16.3 (470), 15.7–14.1 (546), 15.1–13.8 (589), 14.7–13.6 (650). Chemical composition (wt%) is: MgO 2.20, CaO 0.01, Al 2 O 3 7.81, Fe 2 O 3 27.18, TiO 2 4.50, SiO 2 0.26, P 2 O 5 0.09, V 2 O 5 57.01, total 99.06. The empirical formula, based on 24 O atoms, is: (Fe 3 +   3.29 Al 1.48 Ti 0.54 Mg 0.53 ) Σ5.84 (V 6.05 Si 0.04 P 0.01 ) Σ6.10 O 24 (Z = 1). Ziminaite is triclinic, P 1 ¯ , a 8.012(4), b 9.345(5), c 6.678(3) Å, α 106.992(10), β 101.547(8), γ 96.594(11)º, V 460.4(4) Å 3 , Z = 6. The strongest reflections of the powder X-ray diffraction pattern [ d ,Å( I )( hkl )] are: 3.751(17)(1–21, 12 − 1), 3.539(86)(120), 3.270(67)(01–2), 3.209(100)(2–20), 3.090(20)(2–11, 002), 3.041(18)(03 − 1, 02–2), 2.934(14)(12 − 2, 030) and 1.665(24)(023, 12 − 4). The crystal structure, solved from single-crystal data ( R 1  = 0.085), is based upon heteropolyhedral framework built by VO 4 tetrahedra and Fe 3+ -centred octahedra and five-fold polyhedra. Ziminaite belongs to the howardevansite group being its first member without species-defining uni- or divalent cations and with all large cation sites vacant. The mineral is named after the Zimina volcano situated near the discovery locality.
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Ziminaite occurs as lamellar, tabular or flattened prismatic crystals up to 10 × 30 × 50 μm typically epitaxially overgrowing koksharovite, and as aggregates (up to 0.15 mm) associated with bannermanite in cavities in volcanic scoria. The mineral is translucent, yellowish-brown with an adamantine luster. The calculated density is 3.45 g cm − 3 . In reflected light, ziminaite is light grey. Bireflectance is weak, internal reflections are deep yellow. The reflectance values [ R max –R min , % (λ, nm)] are: 17.7–16.3 (470), 15.7–14.1 (546), 15.1–13.8 (589), 14.7–13.6 (650). Chemical composition (wt%) is: MgO 2.20, CaO 0.01, Al 2 O 3 7.81, Fe 2 O 3 27.18, TiO 2 4.50, SiO 2 0.26, P 2 O 5 0.09, V 2 O 5 57.01, total 99.06. The empirical formula, based on 24 O atoms, is: (Fe 3 +   3.29 Al 1.48 Ti 0.54 Mg 0.53 ) Σ5.84 (V 6.05 Si 0.04 P 0.01 ) Σ6.10 O 24 (Z = 1). Ziminaite is triclinic, P 1 ¯ , a 8.012(4), b 9.345(5), c 6.678(3) Å, α 106.992(10), β 101.547(8), γ 96.594(11)º, V 460.4(4) Å 3 , Z = 6. The strongest reflections of the powder X-ray diffraction pattern [ d ,Å( I )( hkl )] are: 3.751(17)(1–21, 12 − 1), 3.539(86)(120), 3.270(67)(01–2), 3.209(100)(2–20), 3.090(20)(2–11, 002), 3.041(18)(03 − 1, 02–2), 2.934(14)(12 − 2, 030) and 1.665(24)(023, 12 − 4). The crystal structure, solved from single-crystal data ( R 1  = 0.085), is based upon heteropolyhedral framework built by VO 4 tetrahedra and Fe 3+ -centred octahedra and five-fold polyhedra. Ziminaite belongs to the howardevansite group being its first member without species-defining uni- or divalent cations and with all large cation sites vacant. 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All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c246t-d209a396e0f5d2e5f15095898aaf1d9f7cd05df63a75ef70af4849723fd002943</citedby><cites>FETCH-LOGICAL-c246t-d209a396e0f5d2e5f15095898aaf1d9f7cd05df63a75ef70af4849723fd002943</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00710-017-0550-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00710-017-0550-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27907,27908,41471,42540,51302</link.rule.ids></links><search><creatorcontrib>Pekov, Igor V.</creatorcontrib><creatorcontrib>Siidra, Oleg I.</creatorcontrib><creatorcontrib>Yapaskurt, Vasiliy O.</creatorcontrib><creatorcontrib>Polekhovsky, Yury S.</creatorcontrib><creatorcontrib>Kartashov, Pavel M.</creatorcontrib><title>Ziminaite, Fe3+VO4, a new howardevansite-group mineral from the Bezymyannyi volcano, Kamchatka, Russia</title><title>Mineralogy and petrology</title><addtitle>Miner Petrol</addtitle><description>The new mineral ziminaite, ideally Fe 3+ VO 4 , was found in fumarole sublimates at the Bezymyannyi volcano, Kamchatka, Russia. Ziminaite occurs as lamellar, tabular or flattened prismatic crystals up to 10 × 30 × 50 μm typically epitaxially overgrowing koksharovite, and as aggregates (up to 0.15 mm) associated with bannermanite in cavities in volcanic scoria. The mineral is translucent, yellowish-brown with an adamantine luster. The calculated density is 3.45 g cm − 3 . In reflected light, ziminaite is light grey. Bireflectance is weak, internal reflections are deep yellow. The reflectance values [ R max –R min , % (λ, nm)] are: 17.7–16.3 (470), 15.7–14.1 (546), 15.1–13.8 (589), 14.7–13.6 (650). Chemical composition (wt%) is: MgO 2.20, CaO 0.01, Al 2 O 3 7.81, Fe 2 O 3 27.18, TiO 2 4.50, SiO 2 0.26, P 2 O 5 0.09, V 2 O 5 57.01, total 99.06. The empirical formula, based on 24 O atoms, is: (Fe 3 +   3.29 Al 1.48 Ti 0.54 Mg 0.53 ) Σ5.84 (V 6.05 Si 0.04 P 0.01 ) Σ6.10 O 24 (Z = 1). Ziminaite is triclinic, P 1 ¯ , a 8.012(4), b 9.345(5), c 6.678(3) Å, α 106.992(10), β 101.547(8), γ 96.594(11)º, V 460.4(4) Å 3 , Z = 6. The strongest reflections of the powder X-ray diffraction pattern [ d ,Å( I )( hkl )] are: 3.751(17)(1–21, 12 − 1), 3.539(86)(120), 3.270(67)(01–2), 3.209(100)(2–20), 3.090(20)(2–11, 002), 3.041(18)(03 − 1, 02–2), 2.934(14)(12 − 2, 030) and 1.665(24)(023, 12 − 4). The crystal structure, solved from single-crystal data ( R 1  = 0.085), is based upon heteropolyhedral framework built by VO 4 tetrahedra and Fe 3+ -centred octahedra and five-fold polyhedra. Ziminaite belongs to the howardevansite group being its first member without species-defining uni- or divalent cations and with all large cation sites vacant. 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Ziminaite occurs as lamellar, tabular or flattened prismatic crystals up to 10 × 30 × 50 μm typically epitaxially overgrowing koksharovite, and as aggregates (up to 0.15 mm) associated with bannermanite in cavities in volcanic scoria. The mineral is translucent, yellowish-brown with an adamantine luster. The calculated density is 3.45 g cm − 3 . In reflected light, ziminaite is light grey. Bireflectance is weak, internal reflections are deep yellow. The reflectance values [ R max –R min , % (λ, nm)] are: 17.7–16.3 (470), 15.7–14.1 (546), 15.1–13.8 (589), 14.7–13.6 (650). Chemical composition (wt%) is: MgO 2.20, CaO 0.01, Al 2 O 3 7.81, Fe 2 O 3 27.18, TiO 2 4.50, SiO 2 0.26, P 2 O 5 0.09, V 2 O 5 57.01, total 99.06. The empirical formula, based on 24 O atoms, is: (Fe 3 +   3.29 Al 1.48 Ti 0.54 Mg 0.53 ) Σ5.84 (V 6.05 Si 0.04 P 0.01 ) Σ6.10 O 24 (Z = 1). Ziminaite is triclinic, P 1 ¯ , a 8.012(4), b 9.345(5), c 6.678(3) Å, α 106.992(10), β 101.547(8), γ 96.594(11)º, V 460.4(4) Å 3 , Z = 6. The strongest reflections of the powder X-ray diffraction pattern [ d ,Å( I )( hkl )] are: 3.751(17)(1–21, 12 − 1), 3.539(86)(120), 3.270(67)(01–2), 3.209(100)(2–20), 3.090(20)(2–11, 002), 3.041(18)(03 − 1, 02–2), 2.934(14)(12 − 2, 030) and 1.665(24)(023, 12 − 4). The crystal structure, solved from single-crystal data ( R 1  = 0.085), is based upon heteropolyhedral framework built by VO 4 tetrahedra and Fe 3+ -centred octahedra and five-fold polyhedra. Ziminaite belongs to the howardevansite group being its first member without species-defining uni- or divalent cations and with all large cation sites vacant. The mineral is named after the Zimina volcano situated near the discovery locality.</abstract><cop>Vienna</cop><pub>Springer Vienna</pub><doi>10.1007/s00710-017-0550-y</doi><tpages>9</tpages></addata></record>
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subjects Aluminum oxide
Cations
Composition
Crystal structure
Crystals
Diffraction
Diffraction patterns
Divalent cations
Earth and Environmental Science
Earth Sciences
Frameworks
Geochemistry
Inorganic Chemistry
Iron
Luster
Mineralogy
Original Paper
Polyhedra
Reflectance
Silicon dioxide
Single crystals
Titanium dioxide
Vanadium pentoxide
Volcanic activity
Volcanoes
X ray powder diffraction
X-ray diffraction
X-rays
title Ziminaite, Fe3+VO4, a new howardevansite-group mineral from the Bezymyannyi volcano, Kamchatka, Russia
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