PPC-based Reactive Hot Melt Polyurethane Adhesive(RHMPA)——Efficient Glues for Multiple Types of Substrates

Tens of billion metric tons of anthropogenic CO2 discharged from the burning of fossil fuels lead to an enormous environmental and resource burden. It is charming to transform CO2 to desirable, economical chemicals and materials. Poly(propylene carbonate)(PPC) is an emerging CO2-based material. Here...

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Veröffentlicht in:Chinese journal of polymer science 2018, Vol.36 (1), p.58-64
Hauptverfasser: Liu, Zeng-He, Huang, Ji-Qing, Sun, Li-Jie, Lei, Dong, Cao, Jing, Chen, Shuo, Shih, Wen-Chang, Qing, Feng-Ling, You, Zheng-Wei
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container_end_page 64
container_issue 1
container_start_page 58
container_title Chinese journal of polymer science
container_volume 36
creator Liu, Zeng-He
Huang, Ji-Qing
Sun, Li-Jie
Lei, Dong
Cao, Jing
Chen, Shuo
Shih, Wen-Chang
Qing, Feng-Ling
You, Zheng-Wei
description Tens of billion metric tons of anthropogenic CO2 discharged from the burning of fossil fuels lead to an enormous environmental and resource burden. It is charming to transform CO2 to desirable, economical chemicals and materials. Poly(propylene carbonate)(PPC) is an emerging CO2-based material. Herein, we report the design, synthesis and characterization of the reactive hot melt polyurethane adhesive(RHMPA) based on PPC polyol. The resultant RHMPAs exhibit good adhesion properties to multiple substrates including plastics(PC, PMMA, ABS) and metals(aluminium, steel), which is comparable to or even better than conventional RHMPAs prepared from petro-based polyol. Furthermore, the PPC-based RHMPAs have tunable mechanical properties, and are thermally stable in the typical working range of bonding process(up to 270 °C). The study is expected to expand the applications of PPC and provide a new type of CO2-based renewable and eco-friendly materials.
doi_str_mv 10.1007/s10118-018-2011-4
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source Springer Nature - Complete Springer Journals; Alma/SFX Local Collection
subjects Adhesive bonding
Aluminum
Carbon dioxide
Characterization and Evaluation of Materials
Chemical bonds
Chemistry
Chemistry and Materials Science
Condensed Matter Physics
Fossil fuels
Glues
Industrial Chemistry/Chemical Engineering
Mechanical properties
Polymer Sciences
Polymers
Polymethyl methacrylate
Polyurethane resins
Propylene
Substrates
Thermal stability
title PPC-based Reactive Hot Melt Polyurethane Adhesive(RHMPA)——Efficient Glues for Multiple Types of Substrates
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