Application of HDTMA-intercalated bentonites in water waste treatment for U(VI) removal

Bentonite deposits in Slovakia are systematically investigated as potential adsorbents for wastewater and radioactive waste treatment applications. Herein, adsorption properties (isotherms, kinetics and thermodynamics) of raw and organo-modified bentonites towards uranium species in aquaeous solutio...

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Veröffentlicht in:Journal of radioanalytical and nuclear chemistry 2017-12, Vol.314 (3), p.2489-2499
Hauptverfasser: Krajňák, Adrián, Viglašová, Eva, Galamboš, Michal, Krivosudský, Lukáš
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container_start_page 2489
container_title Journal of radioanalytical and nuclear chemistry
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creator Krajňák, Adrián
Viglašová, Eva
Galamboš, Michal
Krivosudský, Lukáš
description Bentonite deposits in Slovakia are systematically investigated as potential adsorbents for wastewater and radioactive waste treatment applications. Herein, adsorption properties (isotherms, kinetics and thermodynamics) of raw and organo-modified bentonites towards uranium species in aquaeous solutions were investigated. Organo-modified bentonites was prepared by practical and simple chemical modification method with hexadecyltrimethylammonium bromide (denoted as HDTMA-bentonites). The adsorption processes of U(VI) on HDTMA-bentonites were spontaneous and endothermic, and well simulated by pseudo-second-order model. The maximum adsorption capacity of U(VI) was calculated to be 31.45 mg/g at pH 8.5 and T  = 298 K. Slovak bentonites Jelšový potok and Kopernica, their natural and HDTMA-modified forms might be a promising sorbent for the treatment of U(VI) contaminants in aqueous solutions.
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subjects Adsorption
Bentonite
Cetyltrimethylammonium bromide
Chemistry
Chemistry and Materials Science
Computer simulation
Contaminants
Diagnostic Radiology
Endothermic reactions
Hadrons
Heavy Ions
Inorganic Chemistry
Nuclear Chemistry
Nuclear energy
Nuclear environmental management
Nuclear Physics
Physical Chemistry
Radioactive pollution
Radioactive wastes
Surface active agents
Uranium
Waste management
Waste treatment
Waste treatment equipment
Wastewater treatment
title Application of HDTMA-intercalated bentonites in water waste treatment for U(VI) removal
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