FT-IR studies of factors affecting the diffusivity of oligo (oxyethylene) fatty acid ester in PE films: Effect of temperature, ethylene oxide chain length and base resin type
A migration kinetics study of a series of oligo (oxyethylene) fatty acid esters of various chain lengths in polyethylene film was studied using Fourier transform infrared (FT-IR) spectroscopy. Diffusion coefficients (D) were determined as a function of temperature, ethylene oxide (EO) chain length a...
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| Veröffentlicht in: | Polymer (Guilford) 2017-11, Vol.130, p.150-160 |
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| creator | Zhou, Yuanyuan Hou, Lei Chen, Hongyu Steenbakkers, Rudi Sehanobish, Kalyan Wu, Peiyi Shi, Qing |
| description | A migration kinetics study of a series of oligo (oxyethylene) fatty acid esters of various chain lengths in polyethylene film was studied using Fourier transform infrared (FT-IR) spectroscopy. Diffusion coefficients (D) were determined as a function of temperature, ethylene oxide (EO) chain length and base resin type. The activation energy of diffusion (Ea) for each oligo (oxyethylene) fatty acid ester was determined using the Arrhenius plot of D dependence on inverse temperature. The correlation between obtained D and the number-averaged molecular weight Mn of oligo (oxyethylene) fatty acid ester was described well by a power law expression (D=bMn−a), and the parameters a and b were determined from experimental data. Two other models, which have the form of an Eyring expression, were derived to express the effects of temperature and EO chain length on the diffusion process of oligo (oxyethylene) fatty acid esters. Diffusivity of oligo (oxyethylene) fatty acid ester in linear low density polyethylene (LLDPE) was higher than in high density polyethylene (HDPE) and low density polyethylene (LDPE).
[Display omitted]
•Effects of temperature, EO chain length and resin type on diffusivity are studied.•The molar mass dependence of diffusivity is described by a power law (D=bMn−a).•Two Eyring-type models involved in effects of temperature and EO number are given. |
| doi_str_mv | 10.1016/j.polymer.2017.10.001 |
| format | Article |
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[Display omitted]
•Effects of temperature, EO chain length and resin type on diffusivity are studied.•The molar mass dependence of diffusivity is described by a power law (D=bMn−a).•Two Eyring-type models involved in effects of temperature and EO number are given.</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/j.polymer.2017.10.001</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Chains ; Density ; Diffusion ; Diffusivity ; Esters ; Ethylene ; Ethylene oxide ; Fatty acids ; Fourier transforms ; High density polyethylenes ; Infrared spectroscopy ; Kinetics ; Low density polyethylenes ; Migration ; Molecular weight ; Oligo (oxyethylene) fatty acid ester ; Polyethylene ; Polyethylene film ; Polyethylene films ; Temperature effects</subject><ispartof>Polymer (Guilford), 2017-11, Vol.130, p.150-160</ispartof><rights>2017 Elsevier Ltd</rights><rights>Copyright Elsevier BV Nov 9, 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-7594a9abe04c9f64a655c82ec84741e721730e3c4dd8ec9fb005dd59443537043</citedby><cites>FETCH-LOGICAL-c337t-7594a9abe04c9f64a655c82ec84741e721730e3c4dd8ec9fb005dd59443537043</cites><orcidid>0000-0001-7235-210X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.polymer.2017.10.001$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Zhou, Yuanyuan</creatorcontrib><creatorcontrib>Hou, Lei</creatorcontrib><creatorcontrib>Chen, Hongyu</creatorcontrib><creatorcontrib>Steenbakkers, Rudi</creatorcontrib><creatorcontrib>Sehanobish, Kalyan</creatorcontrib><creatorcontrib>Wu, Peiyi</creatorcontrib><creatorcontrib>Shi, Qing</creatorcontrib><title>FT-IR studies of factors affecting the diffusivity of oligo (oxyethylene) fatty acid ester in PE films: Effect of temperature, ethylene oxide chain length and base resin type</title><title>Polymer (Guilford)</title><description>A migration kinetics study of a series of oligo (oxyethylene) fatty acid esters of various chain lengths in polyethylene film was studied using Fourier transform infrared (FT-IR) spectroscopy. Diffusion coefficients (D) were determined as a function of temperature, ethylene oxide (EO) chain length and base resin type. The activation energy of diffusion (Ea) for each oligo (oxyethylene) fatty acid ester was determined using the Arrhenius plot of D dependence on inverse temperature. The correlation between obtained D and the number-averaged molecular weight Mn of oligo (oxyethylene) fatty acid ester was described well by a power law expression (D=bMn−a), and the parameters a and b were determined from experimental data. Two other models, which have the form of an Eyring expression, were derived to express the effects of temperature and EO chain length on the diffusion process of oligo (oxyethylene) fatty acid esters. Diffusivity of oligo (oxyethylene) fatty acid ester in linear low density polyethylene (LLDPE) was higher than in high density polyethylene (HDPE) and low density polyethylene (LDPE).
[Display omitted]
•Effects of temperature, EO chain length and resin type on diffusivity are studied.•The molar mass dependence of diffusivity is described by a power law (D=bMn−a).•Two Eyring-type models involved in effects of temperature and EO number are given.</description><subject>Chains</subject><subject>Density</subject><subject>Diffusion</subject><subject>Diffusivity</subject><subject>Esters</subject><subject>Ethylene</subject><subject>Ethylene oxide</subject><subject>Fatty acids</subject><subject>Fourier transforms</subject><subject>High density polyethylenes</subject><subject>Infrared spectroscopy</subject><subject>Kinetics</subject><subject>Low density polyethylenes</subject><subject>Migration</subject><subject>Molecular weight</subject><subject>Oligo (oxyethylene) fatty acid ester</subject><subject>Polyethylene</subject><subject>Polyethylene film</subject><subject>Polyethylene films</subject><subject>Temperature effects</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqFkd1q3DAQhU1podu0jxAY6E0L9VayZMvuTSlh8wOBlpJcC6002tXitVxJDvFL5Rkjd9PrXgnOnO-ImVMU55SsKaHN18N69P18xLCuCBVZWxNCXxUr2gpWVlVHXxcrQlhVsrahb4t3MR4IIVVd8VXxdHlX3vyGmCbjMIK3YJVOPkRQ1qJObthB2iMYZ-0U3YNL82Lyvdt5-OQfZ0z7uccBP2cw5aHSzgDGhAHcAL82YF1_jN9g8zduYRMeRwwqTQG_wD8c_KMzCHqvMpWFXdqDGgxsVUQIGLOa5hHfF2-s6iN-eHnPivvLzd3FdXn78-rm4sdtqRkTqRR1x1Wntki47mzDVVPXuq1Qt1xwiqKighFkmhvTYnZsCamNyRBnNROEs7Pi4yl3DP7PlNeRBz-FIX8pade0XSsEqbOrPrl08DEGtHIM7qjCLCmRSzXyIF-qkUs1i5yrydz3E4d5hQeXp1E7HDQaF_KRpPHuPwnPnnucXg</recordid><startdate>20171109</startdate><enddate>20171109</enddate><creator>Zhou, Yuanyuan</creator><creator>Hou, Lei</creator><creator>Chen, Hongyu</creator><creator>Steenbakkers, Rudi</creator><creator>Sehanobish, Kalyan</creator><creator>Wu, Peiyi</creator><creator>Shi, Qing</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><orcidid>https://orcid.org/0000-0001-7235-210X</orcidid></search><sort><creationdate>20171109</creationdate><title>FT-IR studies of factors affecting the diffusivity of oligo (oxyethylene) fatty acid ester in PE films: Effect of temperature, ethylene oxide chain length and base resin type</title><author>Zhou, Yuanyuan ; Hou, Lei ; Chen, Hongyu ; Steenbakkers, Rudi ; Sehanobish, Kalyan ; Wu, Peiyi ; Shi, Qing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-7594a9abe04c9f64a655c82ec84741e721730e3c4dd8ec9fb005dd59443537043</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Chains</topic><topic>Density</topic><topic>Diffusion</topic><topic>Diffusivity</topic><topic>Esters</topic><topic>Ethylene</topic><topic>Ethylene oxide</topic><topic>Fatty acids</topic><topic>Fourier transforms</topic><topic>High density polyethylenes</topic><topic>Infrared spectroscopy</topic><topic>Kinetics</topic><topic>Low density polyethylenes</topic><topic>Migration</topic><topic>Molecular weight</topic><topic>Oligo (oxyethylene) fatty acid ester</topic><topic>Polyethylene</topic><topic>Polyethylene film</topic><topic>Polyethylene films</topic><topic>Temperature effects</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhou, Yuanyuan</creatorcontrib><creatorcontrib>Hou, Lei</creatorcontrib><creatorcontrib>Chen, Hongyu</creatorcontrib><creatorcontrib>Steenbakkers, Rudi</creatorcontrib><creatorcontrib>Sehanobish, Kalyan</creatorcontrib><creatorcontrib>Wu, Peiyi</creatorcontrib><creatorcontrib>Shi, Qing</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhou, Yuanyuan</au><au>Hou, Lei</au><au>Chen, Hongyu</au><au>Steenbakkers, Rudi</au><au>Sehanobish, Kalyan</au><au>Wu, Peiyi</au><au>Shi, Qing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>FT-IR studies of factors affecting the diffusivity of oligo (oxyethylene) fatty acid ester in PE films: Effect of temperature, ethylene oxide chain length and base resin type</atitle><jtitle>Polymer (Guilford)</jtitle><date>2017-11-09</date><risdate>2017</risdate><volume>130</volume><spage>150</spage><epage>160</epage><pages>150-160</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><abstract>A migration kinetics study of a series of oligo (oxyethylene) fatty acid esters of various chain lengths in polyethylene film was studied using Fourier transform infrared (FT-IR) spectroscopy. Diffusion coefficients (D) were determined as a function of temperature, ethylene oxide (EO) chain length and base resin type. The activation energy of diffusion (Ea) for each oligo (oxyethylene) fatty acid ester was determined using the Arrhenius plot of D dependence on inverse temperature. The correlation between obtained D and the number-averaged molecular weight Mn of oligo (oxyethylene) fatty acid ester was described well by a power law expression (D=bMn−a), and the parameters a and b were determined from experimental data. Two other models, which have the form of an Eyring expression, were derived to express the effects of temperature and EO chain length on the diffusion process of oligo (oxyethylene) fatty acid esters. Diffusivity of oligo (oxyethylene) fatty acid ester in linear low density polyethylene (LLDPE) was higher than in high density polyethylene (HDPE) and low density polyethylene (LDPE).
[Display omitted]
•Effects of temperature, EO chain length and resin type on diffusivity are studied.•The molar mass dependence of diffusivity is described by a power law (D=bMn−a).•Two Eyring-type models involved in effects of temperature and EO number are given.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.polymer.2017.10.001</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0001-7235-210X</orcidid></addata></record> |
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| subjects | Chains Density Diffusion Diffusivity Esters Ethylene Ethylene oxide Fatty acids Fourier transforms High density polyethylenes Infrared spectroscopy Kinetics Low density polyethylenes Migration Molecular weight Oligo (oxyethylene) fatty acid ester Polyethylene Polyethylene film Polyethylene films Temperature effects |
| title | FT-IR studies of factors affecting the diffusivity of oligo (oxyethylene) fatty acid ester in PE films: Effect of temperature, ethylene oxide chain length and base resin type |
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