Kinetics and Mechanism of Cumene Oxidation Initiated by N‐Hydroxyphthalimide
ABSTRACT This paper discusses the results of investigations on the kinetics of cumene oxidation to cumene hydroperoxide by molecular oxygen in the presence of N‐hydroxyphthalimide as a catalyst. A mathematical model has been developed on the basis of the regularities of hydroperoxide and by‐products...
Gespeichert in:
| Veröffentlicht in: | International journal of chemical kinetics 2018-01, Vol.50 (1), p.3-14 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 14 |
|---|---|
| container_issue | 1 |
| container_start_page | 3 |
| container_title | International journal of chemical kinetics |
| container_volume | 50 |
| creator | Sapunov, V. N. Kurganova, E. A. Koshel, G. N. |
| description | ABSTRACT
This paper discusses the results of investigations on the kinetics of cumene oxidation to cumene hydroperoxide by molecular oxygen in the presence of N‐hydroxyphthalimide as a catalyst. A mathematical model has been developed on the basis of the regularities of hydroperoxide and by‐products formation. The model adequately describes changes in all reaction components in the course of the reaction. It has also been established that the role of N‐hydroxyphthalimide in the process consists in the creation of a steady‐state concentration of N‐phthalimide radicals initiating oxidation by interacting with the hydrocarbon. |
| doi_str_mv | 10.1002/kin.21135 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1968421532</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1968421532</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2975-9de083d84ed7867ae9d991a75edc6374b7f3e6261146ea9ab3da8aadad1aba63</originalsourceid><addsrcrecordid>eNp1kLFOwzAURS0EEqUw8AeWmBjS2nHixCOqgEYt7dLdeolfVJfGKXEqmo1P4Bv5EgJhZXrLefdeHUJuOZtwxsLpq3WTkHMRn5ERZyoJIsn4ORmxWKRByqS8JFfe7xhjSvF4RFYL67C1hafgDH3BYgvO-orWJZ0dK3RI1ydroLW1o5mzrYUWDc07uvr6-Jx3pqlP3WHbbmFvK2vwmlyUsPd483fHZPP0uJnNg-X6OZs9LIMiVEkcKIMsFSaN0CSpTACV6edAEqMppEiiPCkFylByHkkEBbkwkAIYMBxykGJM7obYQ1O_HdG3elcfG9c3aq5kGoU8FmFP3Q9U0dTeN1jqQ2MraDrNmf6xpXtb-tdWz04H9t3usfsf1ItsNXx8AzvEbSw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1968421532</pqid></control><display><type>article</type><title>Kinetics and Mechanism of Cumene Oxidation Initiated by N‐Hydroxyphthalimide</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Sapunov, V. N. ; Kurganova, E. A. ; Koshel, G. N.</creator><creatorcontrib>Sapunov, V. N. ; Kurganova, E. A. ; Koshel, G. N.</creatorcontrib><description>ABSTRACT
This paper discusses the results of investigations on the kinetics of cumene oxidation to cumene hydroperoxide by molecular oxygen in the presence of N‐hydroxyphthalimide as a catalyst. A mathematical model has been developed on the basis of the regularities of hydroperoxide and by‐products formation. The model adequately describes changes in all reaction components in the course of the reaction. It has also been established that the role of N‐hydroxyphthalimide in the process consists in the creation of a steady‐state concentration of N‐phthalimide radicals initiating oxidation by interacting with the hydrocarbon.</description><identifier>ISSN: 0538-8066</identifier><identifier>EISSN: 1097-4601</identifier><identifier>DOI: 10.1002/kin.21135</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc</publisher><subject>Cumene ; Cumene hydroperoxide ; Oxidation ; Oxygen ; Reaction kinetics</subject><ispartof>International journal of chemical kinetics, 2018-01, Vol.50 (1), p.3-14</ispartof><rights>2017 Wiley Periodicals, Inc.</rights><rights>Copyright © 2018 Wiley Periodicals, Inc., A Wiley Company</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2975-9de083d84ed7867ae9d991a75edc6374b7f3e6261146ea9ab3da8aadad1aba63</citedby><cites>FETCH-LOGICAL-c2975-9de083d84ed7867ae9d991a75edc6374b7f3e6261146ea9ab3da8aadad1aba63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fkin.21135$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fkin.21135$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Sapunov, V. N.</creatorcontrib><creatorcontrib>Kurganova, E. A.</creatorcontrib><creatorcontrib>Koshel, G. N.</creatorcontrib><title>Kinetics and Mechanism of Cumene Oxidation Initiated by N‐Hydroxyphthalimide</title><title>International journal of chemical kinetics</title><description>ABSTRACT
This paper discusses the results of investigations on the kinetics of cumene oxidation to cumene hydroperoxide by molecular oxygen in the presence of N‐hydroxyphthalimide as a catalyst. A mathematical model has been developed on the basis of the regularities of hydroperoxide and by‐products formation. The model adequately describes changes in all reaction components in the course of the reaction. It has also been established that the role of N‐hydroxyphthalimide in the process consists in the creation of a steady‐state concentration of N‐phthalimide radicals initiating oxidation by interacting with the hydrocarbon.</description><subject>Cumene</subject><subject>Cumene hydroperoxide</subject><subject>Oxidation</subject><subject>Oxygen</subject><subject>Reaction kinetics</subject><issn>0538-8066</issn><issn>1097-4601</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kLFOwzAURS0EEqUw8AeWmBjS2nHixCOqgEYt7dLdeolfVJfGKXEqmo1P4Bv5EgJhZXrLefdeHUJuOZtwxsLpq3WTkHMRn5ERZyoJIsn4ORmxWKRByqS8JFfe7xhjSvF4RFYL67C1hafgDH3BYgvO-orWJZ0dK3RI1ydroLW1o5mzrYUWDc07uvr6-Jx3pqlP3WHbbmFvK2vwmlyUsPd483fHZPP0uJnNg-X6OZs9LIMiVEkcKIMsFSaN0CSpTACV6edAEqMppEiiPCkFylByHkkEBbkwkAIYMBxykGJM7obYQ1O_HdG3elcfG9c3aq5kGoU8FmFP3Q9U0dTeN1jqQ2MraDrNmf6xpXtb-tdWz04H9t3usfsf1ItsNXx8AzvEbSw</recordid><startdate>201801</startdate><enddate>201801</enddate><creator>Sapunov, V. N.</creator><creator>Kurganova, E. A.</creator><creator>Koshel, G. N.</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201801</creationdate><title>Kinetics and Mechanism of Cumene Oxidation Initiated by N‐Hydroxyphthalimide</title><author>Sapunov, V. N. ; Kurganova, E. A. ; Koshel, G. N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2975-9de083d84ed7867ae9d991a75edc6374b7f3e6261146ea9ab3da8aadad1aba63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Cumene</topic><topic>Cumene hydroperoxide</topic><topic>Oxidation</topic><topic>Oxygen</topic><topic>Reaction kinetics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sapunov, V. N.</creatorcontrib><creatorcontrib>Kurganova, E. A.</creatorcontrib><creatorcontrib>Koshel, G. N.</creatorcontrib><collection>CrossRef</collection><jtitle>International journal of chemical kinetics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sapunov, V. N.</au><au>Kurganova, E. A.</au><au>Koshel, G. N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Kinetics and Mechanism of Cumene Oxidation Initiated by N‐Hydroxyphthalimide</atitle><jtitle>International journal of chemical kinetics</jtitle><date>2018-01</date><risdate>2018</risdate><volume>50</volume><issue>1</issue><spage>3</spage><epage>14</epage><pages>3-14</pages><issn>0538-8066</issn><eissn>1097-4601</eissn><abstract>ABSTRACT
This paper discusses the results of investigations on the kinetics of cumene oxidation to cumene hydroperoxide by molecular oxygen in the presence of N‐hydroxyphthalimide as a catalyst. A mathematical model has been developed on the basis of the regularities of hydroperoxide and by‐products formation. The model adequately describes changes in all reaction components in the course of the reaction. It has also been established that the role of N‐hydroxyphthalimide in the process consists in the creation of a steady‐state concentration of N‐phthalimide radicals initiating oxidation by interacting with the hydrocarbon.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/kin.21135</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0538-8066 |
| ispartof | International journal of chemical kinetics, 2018-01, Vol.50 (1), p.3-14 |
| issn | 0538-8066 1097-4601 |
| language | eng |
| recordid | cdi_proquest_journals_1968421532 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Cumene Cumene hydroperoxide Oxidation Oxygen Reaction kinetics |
| title | Kinetics and Mechanism of Cumene Oxidation Initiated by N‐Hydroxyphthalimide |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T03%3A00%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Kinetics%20and%20Mechanism%20of%20Cumene%20Oxidation%20Initiated%20by%20N%E2%80%90Hydroxyphthalimide&rft.jtitle=International%20journal%20of%20chemical%20kinetics&rft.au=Sapunov,%20V.%20N.&rft.date=2018-01&rft.volume=50&rft.issue=1&rft.spage=3&rft.epage=14&rft.pages=3-14&rft.issn=0538-8066&rft.eissn=1097-4601&rft_id=info:doi/10.1002/kin.21135&rft_dat=%3Cproquest_cross%3E1968421532%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1968421532&rft_id=info:pmid/&rfr_iscdi=true |