On the elemental analysis of different cigarette brands using laser induced breakdown spectroscopy and laser-ablation time of flight mass spectrometry
We present qualitative and quantitative analysis of the trace elements present in different brands of tobacco available in Pakistan using laser induced breakdown spectroscopy (LIBS) and Laser ablation Time of Flight Mass Spectrometer (LA-TOFMS). The compositional analysis using the calibration free...
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| Veröffentlicht in: | Spectrochimica acta. Part B: Atomic spectroscopy 2017-10, Vol.136, p.39-44 |
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| container_title | Spectrochimica acta. Part B: Atomic spectroscopy |
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| creator | Ahmed, Nasar Umar, Zeshan A. Ahmed, Rizwan Aslam Baig, M. |
| description | We present qualitative and quantitative analysis of the trace elements present in different brands of tobacco available in Pakistan using laser induced breakdown spectroscopy (LIBS) and Laser ablation Time of Flight Mass Spectrometer (LA-TOFMS). The compositional analysis using the calibration free LIBS technique is based on the observed emission spectra of the laser produced plasma plume whereas the elemental composition analysis using LA-TOFMS is based on the mass spectra of the ions produced by laser ablation. The optical emission spectra of these samples contain spectral lines of calcium, magnesium, sodium, potassium, silicon, strontium, barium, lithium and aluminum with varying intensities. The corresponding mass spectra of the elements were detected in LA-TOF-MS with their composition concentration. The analysis of different brands of cigarettes demonstrates that LIBS coupled with a LA-TOF-MS is a powerful technique for the elemental analysis of the trace elements in any solid sample.
•Elemental analysis of 13 different brands of Cigarettes in Pakistan.•Laser Induced Breakdown Spectroscopic technique•Laser-ablation Time of Flight Mass spectrometric analysis. |
| doi_str_mv | 10.1016/j.sab.2017.08.006 |
| format | Article |
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•Elemental analysis of 13 different brands of Cigarettes in Pakistan.•Laser Induced Breakdown Spectroscopic technique•Laser-ablation Time of Flight Mass spectrometric analysis.</description><subject>Ablation</subject><subject>Aluminium</subject><subject>Aluminum</subject><subject>Analysis</subject><subject>Analytical methods</subject><subject>Barium</subject><subject>Brands</subject><subject>Calcium</subject><subject>Calcium magnesium silicates</subject><subject>Chemical composition</subject><subject>Cigarette brands</subject><subject>Cigarettes</subject><subject>Elemental composition</subject><subject>Emission spectra</subject><subject>LA-TOF-mass spectrometry</subject><subject>Laser ablation</subject><subject>Laser induced breakdown spectroscopy</subject><subject>Lasers</subject><subject>LIBS</subject><subject>Line spectra</subject><subject>Lithium</subject><subject>Magnesium</subject><subject>Mass spectra</subject><subject>Mass spectrometry</subject><subject>Mass spectroscopy</subject><subject>Plasma parameters</subject><subject>Potassium</subject><subject>Qualitative analysis</subject><subject>Quantitative analysis</subject><subject>Smoking</subject><subject>Sodium</subject><subject>Spectra</subject><subject>Spectroscopy</subject><subject>Strontium</subject><subject>Tobacco</subject><subject>Trace elements</subject><issn>0584-8547</issn><issn>1873-3565</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp9kM9u2zAMxoWiA5Zme4DdBOxsT7ItW0FPQ9C1AwLk0p4FWqISpf6TicqGvMietwrSXXciQH4fye_H2BcpSilk--1QEvRlJWRXCl0K0d6whdRdXdSqVbdsIZRuCq2a7iO7IzoIISpVqQX7u5142iPHAUecEgwcJhjOFIjPnrvgPcbc5zbsIGJKyPsIkyN-ojDt-ACEkYfJnSy6PEJ4dfOfidMRbYoz2fl4zhvdVVhAP0AKcz4ZRrwc8EPY7RMfgeifZ8QUz5_YBw8D4ef3umQvPx6e10_FZvv4c_19U9i6UqnwHfRSVZ31zrsGnQenu6ZbtVi36HVjW7AgJaKSK6WVb6rao4QVVF72uhf1kn297j3G-dcJKZnDfIqZABm5arWoVdV0WSWvKpsjUURvjjGMEM9GCnPBbw4m4zcX_EZok_Fnz_3Vg_n93wGjIRtwyphCzDmNm8N_3G_HL5I0</recordid><startdate>20171001</startdate><enddate>20171001</enddate><creator>Ahmed, Nasar</creator><creator>Umar, Zeshan A.</creator><creator>Ahmed, Rizwan</creator><creator>Aslam Baig, M.</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7SR</scope><scope>7U5</scope><scope>7UA</scope><scope>8FD</scope><scope>C1K</scope><scope>F1W</scope><scope>H97</scope><scope>JG9</scope><scope>L.G</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0003-0460-6571</orcidid></search><sort><creationdate>20171001</creationdate><title>On the elemental analysis of different cigarette brands using laser induced breakdown spectroscopy and laser-ablation time of flight mass spectrometry</title><author>Ahmed, Nasar ; Umar, Zeshan A. ; Ahmed, Rizwan ; Aslam Baig, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c325t-f7ab1527cfdfd4edfad874796e36ef84c6aca11ee519585f423fe1a9a2f1b8b03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Ablation</topic><topic>Aluminium</topic><topic>Aluminum</topic><topic>Analysis</topic><topic>Analytical methods</topic><topic>Barium</topic><topic>Brands</topic><topic>Calcium</topic><topic>Calcium magnesium silicates</topic><topic>Chemical composition</topic><topic>Cigarette brands</topic><topic>Cigarettes</topic><topic>Elemental composition</topic><topic>Emission spectra</topic><topic>LA-TOF-mass spectrometry</topic><topic>Laser ablation</topic><topic>Laser induced breakdown spectroscopy</topic><topic>Lasers</topic><topic>LIBS</topic><topic>Line spectra</topic><topic>Lithium</topic><topic>Magnesium</topic><topic>Mass spectra</topic><topic>Mass spectrometry</topic><topic>Mass spectroscopy</topic><topic>Plasma parameters</topic><topic>Potassium</topic><topic>Qualitative analysis</topic><topic>Quantitative analysis</topic><topic>Smoking</topic><topic>Sodium</topic><topic>Spectra</topic><topic>Spectroscopy</topic><topic>Strontium</topic><topic>Tobacco</topic><topic>Trace elements</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ahmed, Nasar</creatorcontrib><creatorcontrib>Umar, Zeshan A.</creatorcontrib><creatorcontrib>Ahmed, Rizwan</creatorcontrib><creatorcontrib>Aslam Baig, M.</creatorcontrib><collection>CrossRef</collection><collection>Aqualine</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>Materials Research Database</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Spectrochimica acta. Part B: Atomic spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ahmed, Nasar</au><au>Umar, Zeshan A.</au><au>Ahmed, Rizwan</au><au>Aslam Baig, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>On the elemental analysis of different cigarette brands using laser induced breakdown spectroscopy and laser-ablation time of flight mass spectrometry</atitle><jtitle>Spectrochimica acta. Part B: Atomic spectroscopy</jtitle><date>2017-10-01</date><risdate>2017</risdate><volume>136</volume><spage>39</spage><epage>44</epage><pages>39-44</pages><issn>0584-8547</issn><eissn>1873-3565</eissn><abstract>We present qualitative and quantitative analysis of the trace elements present in different brands of tobacco available in Pakistan using laser induced breakdown spectroscopy (LIBS) and Laser ablation Time of Flight Mass Spectrometer (LA-TOFMS). The compositional analysis using the calibration free LIBS technique is based on the observed emission spectra of the laser produced plasma plume whereas the elemental composition analysis using LA-TOFMS is based on the mass spectra of the ions produced by laser ablation. The optical emission spectra of these samples contain spectral lines of calcium, magnesium, sodium, potassium, silicon, strontium, barium, lithium and aluminum with varying intensities. The corresponding mass spectra of the elements were detected in LA-TOF-MS with their composition concentration. The analysis of different brands of cigarettes demonstrates that LIBS coupled with a LA-TOF-MS is a powerful technique for the elemental analysis of the trace elements in any solid sample.
•Elemental analysis of 13 different brands of Cigarettes in Pakistan.•Laser Induced Breakdown Spectroscopic technique•Laser-ablation Time of Flight Mass spectrometric analysis.</abstract><cop>Oxford</cop><pub>Elsevier B.V</pub><doi>10.1016/j.sab.2017.08.006</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-0460-6571</orcidid></addata></record> |
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| subjects | Ablation Aluminium Aluminum Analysis Analytical methods Barium Brands Calcium Calcium magnesium silicates Chemical composition Cigarette brands Cigarettes Elemental composition Emission spectra LA-TOF-mass spectrometry Laser ablation Laser induced breakdown spectroscopy Lasers LIBS Line spectra Lithium Magnesium Mass spectra Mass spectrometry Mass spectroscopy Plasma parameters Potassium Qualitative analysis Quantitative analysis Smoking Sodium Spectra Spectroscopy Strontium Tobacco Trace elements |
| title | On the elemental analysis of different cigarette brands using laser induced breakdown spectroscopy and laser-ablation time of flight mass spectrometry |
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