Fast microwave synthesis of SnO2@graphene/N-doped carbons as anode materials in sodium ion batteries

Hybrid SnO2@graphene (SG) and SnO2@graphene/N-doped carbon (SGN) structures are synthesized by a fast microwave method and tested as anode materials for Na-ion batteries. In these structures, graphene not only acts as a conducting material but also as supporting material to prevent the volume expans...

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Veröffentlicht in:Journal of alloys and compounds 2017-12, Vol.728, p.1305-1314
Hauptverfasser: Dursun, Burcu, Topac, Erdal, Alibeyli, Rafig, Ata, Ali, Ozturk, Osman, Demir-Cakan, Rezan
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container_end_page 1314
container_issue
container_start_page 1305
container_title Journal of alloys and compounds
container_volume 728
creator Dursun, Burcu
Topac, Erdal
Alibeyli, Rafig
Ata, Ali
Ozturk, Osman
Demir-Cakan, Rezan
description Hybrid SnO2@graphene (SG) and SnO2@graphene/N-doped carbon (SGN) structures are synthesized by a fast microwave method and tested as anode materials for Na-ion batteries. In these structures, graphene not only acts as a conducting material but also as supporting material to prevent the volume expansion of the SnO2 nanoparticles. Additional N-doped carbon coating leads to improved electrochemical performances providing better electronic conductivity resulting over 423 mAh/g capacity after 180 cycles at C/5 with SGN, while SG only provides 170 mAh/g capacities. •A microwave-assisted method is used to obtain anode materials for Na-ion batteries.•Hybrid SnO2@graphene and SnO2@graphene/N-doped carbon structures are synthesized.•Chemical composition of N-doped composite is studied by XPS survey.•N-doped composite exhibites much higher reversible capacities.
doi_str_mv 10.1016/j.jallcom.2017.09.081
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subjects Alloys
Anodes
Batteries
Chemical synthesis
Electrode materials
Graphene
Graphene oxide
Heat conductivity
Microwave synthesis
N-doped carbon
Na-ion battery
Nanoparticles
Performance enhancement
Rechargeable batteries
Sodium-ion batteries
Tin dioxide
Tin oxide
title Fast microwave synthesis of SnO2@graphene/N-doped carbons as anode materials in sodium ion batteries
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