Highly selective gas sensors from photo-activated ZnO/PANI thin films synthesized by mSILAR

•ZnO/PANI based gas, temperature and photo sensor.•Cost-effective microwave assisted successive ionic layer adsorption and reaction (mSILAR) technique was used to prepare ZnO.•The sensor showed good sensitivity and selectivity towards liquid petroleum gas. Zinc oxide (ZnO) nano-polycrystalline thin...

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Veröffentlicht in:Synthetic metals 2017-10, Vol.232, p.123-130
Hauptverfasser: Thomas, Deepu, Thomas, Ajith, Tom, Anju Elsa, Sadasivuni, Kishor Kumar, Ponnamma, Deepalekshmi, Goutham, Solleti, Cabibihan, John-John, Venkateswara Rao, Kalagadda
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container_issue
container_start_page 123
container_title Synthetic metals
container_volume 232
creator Thomas, Deepu
Thomas, Ajith
Tom, Anju Elsa
Sadasivuni, Kishor Kumar
Ponnamma, Deepalekshmi
Goutham, Solleti
Cabibihan, John-John
Venkateswara Rao, Kalagadda
description •ZnO/PANI based gas, temperature and photo sensor.•Cost-effective microwave assisted successive ionic layer adsorption and reaction (mSILAR) technique was used to prepare ZnO.•The sensor showed good sensitivity and selectivity towards liquid petroleum gas. Zinc oxide (ZnO) nano-polycrystalline thin films has been prepared by cost-effective microwave assisted successive ionic layer adsorption and reaction (mSILAR) technique. ZnO/PANI prepared by in situ polymerization technique and thin films were fabricated using spin coating. X-ray Diffraction analysis confirms the presence of hexagonal wurtzite ZnO structure in the ZnO/PANI composite. The field emission scanning electron microscope revealed the porous nature of ZnO/PANI films with nanosized grains. We observed PANI intensively affected the structural and electrical properties of ZnO films. The examination of sensors was carried out in the liquefied petroleum gas (LPG) concentration range of 30 to 450ppm. It was noticed that ZnO/PANI nanocomposite film possesses excellent LPG sensing properties at a room temperature compared with other volatile organic compounds, at an applied voltage of 1.5V. The composite films also exhibited significant sensing response of ∼6.11×102 towards temperature and light with recovery and response time of ∼3.5min and 2.16min, respectively. Finally, the fabricated sensor showed good repeatability and sensitivity upon cyclic exposure to gas, light, and temperature. The ZnO/PANI nanocomposite film demonstrated overall sensing behavior in terms of sensor recovery time and response as well as repeatability.
doi_str_mv 10.1016/j.synthmet.2017.08.006
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Zinc oxide (ZnO) nano-polycrystalline thin films has been prepared by cost-effective microwave assisted successive ionic layer adsorption and reaction (mSILAR) technique. ZnO/PANI prepared by in situ polymerization technique and thin films were fabricated using spin coating. X-ray Diffraction analysis confirms the presence of hexagonal wurtzite ZnO structure in the ZnO/PANI composite. The field emission scanning electron microscope revealed the porous nature of ZnO/PANI films with nanosized grains. We observed PANI intensively affected the structural and electrical properties of ZnO films. The examination of sensors was carried out in the liquefied petroleum gas (LPG) concentration range of 30 to 450ppm. It was noticed that ZnO/PANI nanocomposite film possesses excellent LPG sensing properties at a room temperature compared with other volatile organic compounds, at an applied voltage of 1.5V. The composite films also exhibited significant sensing response of ∼6.11×102 towards temperature and light with recovery and response time of ∼3.5min and 2.16min, respectively. Finally, the fabricated sensor showed good repeatability and sensitivity upon cyclic exposure to gas, light, and temperature. 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The composite films also exhibited significant sensing response of ∼6.11×102 towards temperature and light with recovery and response time of ∼3.5min and 2.16min, respectively. Finally, the fabricated sensor showed good repeatability and sensitivity upon cyclic exposure to gas, light, and temperature. The ZnO/PANI nanocomposite film demonstrated overall sensing behavior in terms of sensor recovery time and response as well as repeatability.</description><subject>Detection</subject><subject>Electrical properties</subject><subject>Gas sensors</subject><subject>Liquefied petroleum gas</subject><subject>LPG</subject><subject>mSILAR</subject><subject>Nanocomposites</subject><subject>Organic compounds</subject><subject>Particulate composites</subject><subject>Photo and gas sensor</subject><subject>Polyaniline</subject><subject>Polycrystals</subject><subject>Polymerization</subject><subject>Recovery time</subject><subject>Reproducibility</subject><subject>Response time</subject><subject>Selectivity</subject><subject>Sensors</subject><subject>Spin coating</subject><subject>Thin films</subject><subject>Wurtzite</subject><subject>Zinc oxide</subject><subject>Zinc oxide (ZnO)</subject><subject>Zinc oxides</subject><issn>0379-6779</issn><issn>1879-3290</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqFkE1Lw0AQhhdRsFb_ggQ8J51tkv24WYraQlHx46KHZZNMmg1NUnfTQvz1bqmePc0M77zz8RByTSGiQNmkjtzQ9lWDfTQFyiMQEQA7ISMquAzjqYRTMoLY54xzeU4unKsBgMppOiKfC7OuNkPgcIN5b_YYrLXzVes664LSdk2wrbq-C_VB1T0WwUf7NHmePS6DvjJtUJpN4w2HC9CZb69nQ9C8Llezl0tyVuqNw6vfOCbv93dv80W4enpYzmerMI8T6MMyj1EyHefIdVwUgCkVTIoMOUtymdKEJ5hyDToWQEUCSSZ5mVFMtcxEpst4TG6Oc7e2-9qh61Xd7WzrVyoqGRPpFJjwXezYldvOOYul2lrTaDsoCuoAUtXqD6Q6gFQglAfpjbdHI_of9gatcrnBNsfCWM9MFZ35b8QPmTWAYA</recordid><startdate>201710</startdate><enddate>201710</enddate><creator>Thomas, Deepu</creator><creator>Thomas, Ajith</creator><creator>Tom, Anju Elsa</creator><creator>Sadasivuni, Kishor Kumar</creator><creator>Ponnamma, Deepalekshmi</creator><creator>Goutham, Solleti</creator><creator>Cabibihan, John-John</creator><creator>Venkateswara Rao, Kalagadda</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>201710</creationdate><title>Highly selective gas sensors from photo-activated ZnO/PANI thin films synthesized by mSILAR</title><author>Thomas, Deepu ; Thomas, Ajith ; Tom, Anju Elsa ; Sadasivuni, Kishor Kumar ; Ponnamma, Deepalekshmi ; Goutham, Solleti ; Cabibihan, John-John ; Venkateswara Rao, Kalagadda</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c340t-fc3e96a3ce7a3dd0e518698be764c951474e57a0a38018404b97fb1e5a9b8baf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Detection</topic><topic>Electrical properties</topic><topic>Gas sensors</topic><topic>Liquefied petroleum gas</topic><topic>LPG</topic><topic>mSILAR</topic><topic>Nanocomposites</topic><topic>Organic compounds</topic><topic>Particulate composites</topic><topic>Photo and gas sensor</topic><topic>Polyaniline</topic><topic>Polycrystals</topic><topic>Polymerization</topic><topic>Recovery time</topic><topic>Reproducibility</topic><topic>Response time</topic><topic>Selectivity</topic><topic>Sensors</topic><topic>Spin coating</topic><topic>Thin films</topic><topic>Wurtzite</topic><topic>Zinc oxide</topic><topic>Zinc oxide (ZnO)</topic><topic>Zinc oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Thomas, Deepu</creatorcontrib><creatorcontrib>Thomas, Ajith</creatorcontrib><creatorcontrib>Tom, Anju Elsa</creatorcontrib><creatorcontrib>Sadasivuni, Kishor Kumar</creatorcontrib><creatorcontrib>Ponnamma, Deepalekshmi</creatorcontrib><creatorcontrib>Goutham, Solleti</creatorcontrib><creatorcontrib>Cabibihan, John-John</creatorcontrib><creatorcontrib>Venkateswara Rao, Kalagadda</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Synthetic metals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Thomas, Deepu</au><au>Thomas, Ajith</au><au>Tom, Anju Elsa</au><au>Sadasivuni, Kishor Kumar</au><au>Ponnamma, Deepalekshmi</au><au>Goutham, Solleti</au><au>Cabibihan, John-John</au><au>Venkateswara Rao, Kalagadda</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Highly selective gas sensors from photo-activated ZnO/PANI thin films synthesized by mSILAR</atitle><jtitle>Synthetic metals</jtitle><date>2017-10</date><risdate>2017</risdate><volume>232</volume><spage>123</spage><epage>130</epage><pages>123-130</pages><issn>0379-6779</issn><eissn>1879-3290</eissn><abstract>•ZnO/PANI based gas, temperature and photo sensor.•Cost-effective microwave assisted successive ionic layer adsorption and reaction (mSILAR) technique was used to prepare ZnO.•The sensor showed good sensitivity and selectivity towards liquid petroleum gas. 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The composite films also exhibited significant sensing response of ∼6.11×102 towards temperature and light with recovery and response time of ∼3.5min and 2.16min, respectively. Finally, the fabricated sensor showed good repeatability and sensitivity upon cyclic exposure to gas, light, and temperature. The ZnO/PANI nanocomposite film demonstrated overall sensing behavior in terms of sensor recovery time and response as well as repeatability.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.synthmet.2017.08.006</doi><tpages>8</tpages></addata></record>
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subjects Detection
Electrical properties
Gas sensors
Liquefied petroleum gas
LPG
mSILAR
Nanocomposites
Organic compounds
Particulate composites
Photo and gas sensor
Polyaniline
Polycrystals
Polymerization
Recovery time
Reproducibility
Response time
Selectivity
Sensors
Spin coating
Thin films
Wurtzite
Zinc oxide
Zinc oxide (ZnO)
Zinc oxides
title Highly selective gas sensors from photo-activated ZnO/PANI thin films synthesized by mSILAR
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