Time-Resolved InSitu MAS NMR Monitoring of the Nucleation and Growth of Zeolite BEA Catalysts under Hydrothermal Conditions

Time-resolved 13C, 23Na, 27Al, and 29Si MAS NMR has been applied insitu for monitoring the hydrothermal synthesis of zeolite BEA. Isotopic labelling with 29Si and 13C isotopes has been used to follow the fate of siliceous species and structure directing agent ((13CH3-CH2)4NOH). Two mechanistic pathw...

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Veröffentlicht in:	Angewandte Chemie International Edition 2017-11, Vol.56 (48), p.15344
Hauptverfasser:	Ivanova, Irina I, Kolyagin, Yury G, Kasyanov, Ivan A, Yakimov, Alexander V, Bok, Tatiana O, Zarubin, Dmitry N
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysts Cations Isotopes Labeling Metal-organic frameworks Monitoring NMR NMR spectroscopy Nuclear magnetic resonance Synthesis Zeolites
Online-Zugang:	Volltext
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