Preparation and enhanced mechanical properties of hydroxyapatite hybrid hydrogels via novel photocatalytic polymerization
Hydroxyapatite (HA) hybridized poly(N-isopropylacrylamide)-co-acrylic acid (PNIPAM-co-AAc) hydrogel on thermoplastic polyurethane (TPU) were successfully prepared via photocatalytic polymerization technique. Low temperature plasma processing of HMDSZ and O 2 plasma were deposition on substrate. The...
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| Veröffentlicht in: | Journal of polymer research 2017-11, Vol.24 (12), p.1-9, Article 227 |
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| creator | Chiu, Da-Jhan Li, Ying Feng, Chi-Kuang Yang, Mu-Rong Chen, Ko-Shao Swieszkowski, Wojciech |
| description | Hydroxyapatite (HA) hybridized poly(N-isopropylacrylamide)-co-acrylic acid (PNIPAM-co-AAc) hydrogel on thermoplastic polyurethane (TPU) were successfully prepared via photocatalytic polymerization technique. Low temperature plasma processing of HMDSZ and O
2
plasma were deposition on substrate. The HA/hydrogel were stabilized by HA of which the wettability was modified by calcium nitrate and ammonium phosphate dibasic. The HA gradually increases with the increase of time cycles. The deposition of organic silicone group by the HMDSZ on the TPU substrate is hydrophobic surface. When deposition of O
2
, the water contact angles (WCA) was changed to |
| doi_str_mv | 10.1007/s10965-017-1382-5 |
| format | Article |
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2
plasma were deposition on substrate. The HA/hydrogel were stabilized by HA of which the wettability was modified by calcium nitrate and ammonium phosphate dibasic. The HA gradually increases with the increase of time cycles. The deposition of organic silicone group by the HMDSZ on the TPU substrate is hydrophobic surface. When deposition of O
2
, the water contact angles (WCA) was changed to <10° and surface hydrophilicity. The materials were characterized by OM, SEM, FT-IR, XPS and XRD. The results showed that the NIPAM: AAc (1:1 mol) polymers possess macropores ranging from 2 to 20 μm, and their large numbers of carboxyl groups and hydroxyl groups result in a favorable adsorption capacity for HA. Swelling studies indicated that NIPAM: AAc (1:1 mol) was 446 ± 0.3%. This work provided a promising alternative method for the fabrication of polymer materials with tunable and interconnected pores structures for the HA.</description><identifier>ISSN: 1022-9760</identifier><identifier>EISSN: 1572-8935</identifier><identifier>DOI: 10.1007/s10965-017-1382-5</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Acrylic acid ; Calcium nitrate ; Calcium phosphates ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Contact angle ; Deposition ; Hydrogels ; Hydroxyapatite ; Hydroxyl groups ; Industrial Chemistry/Chemical Engineering ; Isopropylacrylamide ; Mechanical properties ; Original Paper ; Plasma processing ; Polymer Sciences ; Polymerization ; Polyurethane resins ; Urethane thermoplastic elastomers ; Wettability ; X ray photoelectron spectroscopy</subject><ispartof>Journal of polymer research, 2017-11, Vol.24 (12), p.1-9, Article 227</ispartof><rights>Springer Science+Business Media B.V., part of Springer Nature 2017</rights><rights>Journal of Polymer Research is a copyright of Springer, (2017). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-c62b2112d64c6162792632f932c43a61ae5c67c269d4fda7771e0a2788d773793</citedby><cites>FETCH-LOGICAL-c316t-c62b2112d64c6162792632f932c43a61ae5c67c269d4fda7771e0a2788d773793</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10965-017-1382-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10965-017-1382-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Chiu, Da-Jhan</creatorcontrib><creatorcontrib>Li, Ying</creatorcontrib><creatorcontrib>Feng, Chi-Kuang</creatorcontrib><creatorcontrib>Yang, Mu-Rong</creatorcontrib><creatorcontrib>Chen, Ko-Shao</creatorcontrib><creatorcontrib>Swieszkowski, Wojciech</creatorcontrib><title>Preparation and enhanced mechanical properties of hydroxyapatite hybrid hydrogels via novel photocatalytic polymerization</title><title>Journal of polymer research</title><addtitle>J Polym Res</addtitle><description>Hydroxyapatite (HA) hybridized poly(N-isopropylacrylamide)-co-acrylic acid (PNIPAM-co-AAc) hydrogel on thermoplastic polyurethane (TPU) were successfully prepared via photocatalytic polymerization technique. Low temperature plasma processing of HMDSZ and O
2
plasma were deposition on substrate. The HA/hydrogel were stabilized by HA of which the wettability was modified by calcium nitrate and ammonium phosphate dibasic. The HA gradually increases with the increase of time cycles. The deposition of organic silicone group by the HMDSZ on the TPU substrate is hydrophobic surface. When deposition of O
2
, the water contact angles (WCA) was changed to <10° and surface hydrophilicity. The materials were characterized by OM, SEM, FT-IR, XPS and XRD. The results showed that the NIPAM: AAc (1:1 mol) polymers possess macropores ranging from 2 to 20 μm, and their large numbers of carboxyl groups and hydroxyl groups result in a favorable adsorption capacity for HA. Swelling studies indicated that NIPAM: AAc (1:1 mol) was 446 ± 0.3%. This work provided a promising alternative method for the fabrication of polymer materials with tunable and interconnected pores structures for the HA.</description><subject>Acrylic acid</subject><subject>Calcium nitrate</subject><subject>Calcium phosphates</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Contact angle</subject><subject>Deposition</subject><subject>Hydrogels</subject><subject>Hydroxyapatite</subject><subject>Hydroxyl groups</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Isopropylacrylamide</subject><subject>Mechanical properties</subject><subject>Original Paper</subject><subject>Plasma processing</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Polyurethane resins</subject><subject>Urethane thermoplastic elastomers</subject><subject>Wettability</subject><subject>X ray photoelectron spectroscopy</subject><issn>1022-9760</issn><issn>1572-8935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kEtPAyEUhYnRxFr9Ae5IXKM8BhiWpvGVNNGFrgllmJZmOoxAG8dfLzou3Li6j5zvntwDwCXB1wRjeZMIVoIjTCQirKaIH4EZ4ZKiWjF-XHpMKVJS4FNwltIWY86lqGdgfIluMNFkH3po-ga6fmN66xq4c7Z03poODjEMLmbvEgwt3IxNDB-jGQqUXRlX0TfTdu26BA_ewD4cXOE2IQdrsunG7C0cQjfuXPSfP27n4KQ1XXIXv3UO3u7vXhePaPn88LS4XSLLiMjICrqihNBGVFYQQaWigtFWMWorZgQxjlshLRWqqdrGSCmJw4bKum6kZFKxObia7pYv3vcuZb0N-9gXS02UEKySWNVFRSaVjSGl6Fo9RL8zcdQE6--E9ZSwLgnr74Q1LwydmFS0_drFP5f_hb4AbKKAzA</recordid><startdate>20171101</startdate><enddate>20171101</enddate><creator>Chiu, Da-Jhan</creator><creator>Li, Ying</creator><creator>Feng, Chi-Kuang</creator><creator>Yang, Mu-Rong</creator><creator>Chen, Ko-Shao</creator><creator>Swieszkowski, Wojciech</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20171101</creationdate><title>Preparation and enhanced mechanical properties of hydroxyapatite hybrid hydrogels via novel photocatalytic polymerization</title><author>Chiu, Da-Jhan ; Li, Ying ; Feng, Chi-Kuang ; Yang, Mu-Rong ; Chen, Ko-Shao ; Swieszkowski, Wojciech</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-c62b2112d64c6162792632f932c43a61ae5c67c269d4fda7771e0a2788d773793</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Acrylic acid</topic><topic>Calcium nitrate</topic><topic>Calcium phosphates</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Contact angle</topic><topic>Deposition</topic><topic>Hydrogels</topic><topic>Hydroxyapatite</topic><topic>Hydroxyl groups</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Isopropylacrylamide</topic><topic>Mechanical properties</topic><topic>Original Paper</topic><topic>Plasma processing</topic><topic>Polymer Sciences</topic><topic>Polymerization</topic><topic>Polyurethane resins</topic><topic>Urethane thermoplastic elastomers</topic><topic>Wettability</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chiu, Da-Jhan</creatorcontrib><creatorcontrib>Li, Ying</creatorcontrib><creatorcontrib>Feng, Chi-Kuang</creatorcontrib><creatorcontrib>Yang, Mu-Rong</creatorcontrib><creatorcontrib>Chen, Ko-Shao</creatorcontrib><creatorcontrib>Swieszkowski, Wojciech</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Journal of polymer research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chiu, Da-Jhan</au><au>Li, Ying</au><au>Feng, Chi-Kuang</au><au>Yang, Mu-Rong</au><au>Chen, Ko-Shao</au><au>Swieszkowski, Wojciech</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation and enhanced mechanical properties of hydroxyapatite hybrid hydrogels via novel photocatalytic polymerization</atitle><jtitle>Journal of polymer research</jtitle><stitle>J Polym Res</stitle><date>2017-11-01</date><risdate>2017</risdate><volume>24</volume><issue>12</issue><spage>1</spage><epage>9</epage><pages>1-9</pages><artnum>227</artnum><issn>1022-9760</issn><eissn>1572-8935</eissn><abstract>Hydroxyapatite (HA) hybridized poly(N-isopropylacrylamide)-co-acrylic acid (PNIPAM-co-AAc) hydrogel on thermoplastic polyurethane (TPU) were successfully prepared via photocatalytic polymerization technique. Low temperature plasma processing of HMDSZ and O
2
plasma were deposition on substrate. The HA/hydrogel were stabilized by HA of which the wettability was modified by calcium nitrate and ammonium phosphate dibasic. The HA gradually increases with the increase of time cycles. The deposition of organic silicone group by the HMDSZ on the TPU substrate is hydrophobic surface. When deposition of O
2
, the water contact angles (WCA) was changed to <10° and surface hydrophilicity. The materials were characterized by OM, SEM, FT-IR, XPS and XRD. The results showed that the NIPAM: AAc (1:1 mol) polymers possess macropores ranging from 2 to 20 μm, and their large numbers of carboxyl groups and hydroxyl groups result in a favorable adsorption capacity for HA. Swelling studies indicated that NIPAM: AAc (1:1 mol) was 446 ± 0.3%. This work provided a promising alternative method for the fabrication of polymer materials with tunable and interconnected pores structures for the HA.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10965-017-1382-5</doi><tpages>9</tpages></addata></record> |
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| subjects | Acrylic acid Calcium nitrate Calcium phosphates Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Contact angle Deposition Hydrogels Hydroxyapatite Hydroxyl groups Industrial Chemistry/Chemical Engineering Isopropylacrylamide Mechanical properties Original Paper Plasma processing Polymer Sciences Polymerization Polyurethane resins Urethane thermoplastic elastomers Wettability X ray photoelectron spectroscopy |
| title | Preparation and enhanced mechanical properties of hydroxyapatite hybrid hydrogels via novel photocatalytic polymerization |
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