Binary phase diagrams of pyridinecarboxamide isomers
Pyridinecarboxamide binary phase diagrams have been established using differential scanning calorimetry, infrared spectroscopy and X-ray powder diffraction. Simulated diagrams obtained using with the Schröder-van Laar and Prigogine–Defay equations are in very good agreement with experimental data. T...
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| Veröffentlicht in: | Journal of thermal analysis and calorimetry 2017-12, Vol.130 (3), p.1727-1733 |
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| container_title | Journal of thermal analysis and calorimetry |
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| creator | Cortesão, Ana M. Henriques, João G. Castro, Ricardo A. E. Maria, Teresa M. R. Canotilho, João Eusébio, M. Ermelinda S. |
| description | Pyridinecarboxamide binary phase diagrams have been established using differential scanning calorimetry, infrared spectroscopy and X-ray powder diffraction. Simulated diagrams obtained using with the Schröder-van Laar and Prigogine–Defay equations are in very good agreement with experimental data. The binary systems nicotinamide (Form I)–picolinamide (Form II) and isonicotinamide (Form II)—picolinamide (Form I and Form II) occur as eutectic mixtures. Nicotinamide (Form I)—isonicotinamide (Forms II and Form I) solid–liquid phase diagram confirms formation of the cocrystal with molar ratio of 1:1, whose crystal structure was already solved by Báthori et al. (Cryst Growth Des 11:75–87,
12
) with X-ray diffraction on single crystals obtained by crystallization from common solution of nicotinamide and isonicotinamide. The corresponding eutectic composition and temperatures, beyond polymorphism of isonicotinamide and picolinamide under these molecular environments are discussed. |
| doi_str_mv | 10.1007/s10973-017-6474-2 |
| format | Article |
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12
) with X-ray diffraction on single crystals obtained by crystallization from common solution of nicotinamide and isonicotinamide. The corresponding eutectic composition and temperatures, beyond polymorphism of isonicotinamide and picolinamide under these molecular environments are discussed.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>DOI: 10.1007/s10973-017-6474-2</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Analytical Chemistry ; Binary systems ; Calorimetry ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Crystallization ; Diffraction ; Eutectic composition ; Infrared spectroscopy ; Inorganic Chemistry ; Isomers ; Measurement Science and Instrumentation ; Niacinamide ; Nicotinamide ; Phase diagrams ; Physical Chemistry ; Polymer Sciences ; Polymorphism ; Pyridine ; Single crystals ; X ray powder diffraction ; X-ray diffraction</subject><ispartof>Journal of thermal analysis and calorimetry, 2017-12, Vol.130 (3), p.1727-1733</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2017</rights><rights>COPYRIGHT 2017 Springer</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c454t-59971ca175ca47abc6c772dd7792633371a98126671044204d45573c60d3fc653</citedby><cites>FETCH-LOGICAL-c454t-59971ca175ca47abc6c772dd7792633371a98126671044204d45573c60d3fc653</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10973-017-6474-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10973-017-6474-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Cortesão, Ana M.</creatorcontrib><creatorcontrib>Henriques, João G.</creatorcontrib><creatorcontrib>Castro, Ricardo A. E.</creatorcontrib><creatorcontrib>Maria, Teresa M. R.</creatorcontrib><creatorcontrib>Canotilho, João</creatorcontrib><creatorcontrib>Eusébio, M. Ermelinda S.</creatorcontrib><title>Binary phase diagrams of pyridinecarboxamide isomers</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>Pyridinecarboxamide binary phase diagrams have been established using differential scanning calorimetry, infrared spectroscopy and X-ray powder diffraction. Simulated diagrams obtained using with the Schröder-van Laar and Prigogine–Defay equations are in very good agreement with experimental data. The binary systems nicotinamide (Form I)–picolinamide (Form II) and isonicotinamide (Form II)—picolinamide (Form I and Form II) occur as eutectic mixtures. Nicotinamide (Form I)—isonicotinamide (Forms II and Form I) solid–liquid phase diagram confirms formation of the cocrystal with molar ratio of 1:1, whose crystal structure was already solved by Báthori et al. (Cryst Growth Des 11:75–87,
12
) with X-ray diffraction on single crystals obtained by crystallization from common solution of nicotinamide and isonicotinamide. The corresponding eutectic composition and temperatures, beyond polymorphism of isonicotinamide and picolinamide under these molecular environments are discussed.</description><subject>Analytical Chemistry</subject><subject>Binary systems</subject><subject>Calorimetry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Crystallization</subject><subject>Diffraction</subject><subject>Eutectic composition</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Isomers</subject><subject>Measurement Science and Instrumentation</subject><subject>Niacinamide</subject><subject>Nicotinamide</subject><subject>Phase diagrams</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Polymorphism</subject><subject>Pyridine</subject><subject>Single crystals</subject><subject>X ray powder diffraction</subject><subject>X-ray diffraction</subject><issn>1388-6150</issn><issn>1588-2926</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kctKAzEUhoMoWKsP4G7AlYupObk2y1q8FAqCl3VIM5kxpXMxmYJ9e1PGRQtKFjkcvi_JyY_QNeAJYCzvImAlaY5B5oJJlpMTNAI-neZEEXGaappqARyfo4sY1xhjpTCMELv3jQm7rPs00WWFN1UwdczaMut2wRe-cdaEVfttal-4zMe2diFeorPSbKK7-t3H6OPx4X3-nC9fnhbz2TK3jLM-50pJsAYkt4ZJs7LCSkmKQsr0JkqpBKOmQISQgBkjmBWMc0mtwAUtreB0jG6Gc7vQfm1d7PW63YYmXalBCSYIh0OqMhunfVO2fTC29tHqGQcmuCR4T03-oNIqXO1t27jSp_6RcHskJKZ3331ltjHqxdvrMQsDa0MbY3Cl7oKv079qwHqfjx7y0Skfvc9Hk-SQwYmJbSoXDob7V_oBc4aN5g</recordid><startdate>20171201</startdate><enddate>20171201</enddate><creator>Cortesão, Ana M.</creator><creator>Henriques, João G.</creator><creator>Castro, Ricardo A. E.</creator><creator>Maria, Teresa M. R.</creator><creator>Canotilho, João</creator><creator>Eusébio, M. Ermelinda S.</creator><general>Springer Netherlands</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20171201</creationdate><title>Binary phase diagrams of pyridinecarboxamide isomers</title><author>Cortesão, Ana M. ; Henriques, João G. ; Castro, Ricardo A. E. ; Maria, Teresa M. R. ; Canotilho, João ; Eusébio, M. Ermelinda S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c454t-59971ca175ca47abc6c772dd7792633371a98126671044204d45573c60d3fc653</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Analytical Chemistry</topic><topic>Binary systems</topic><topic>Calorimetry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Crystallization</topic><topic>Diffraction</topic><topic>Eutectic composition</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Isomers</topic><topic>Measurement Science and Instrumentation</topic><topic>Niacinamide</topic><topic>Nicotinamide</topic><topic>Phase diagrams</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Polymorphism</topic><topic>Pyridine</topic><topic>Single crystals</topic><topic>X ray powder diffraction</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cortesão, Ana M.</creatorcontrib><creatorcontrib>Henriques, João G.</creatorcontrib><creatorcontrib>Castro, Ricardo A. E.</creatorcontrib><creatorcontrib>Maria, Teresa M. R.</creatorcontrib><creatorcontrib>Canotilho, João</creatorcontrib><creatorcontrib>Eusébio, M. Ermelinda S.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cortesão, Ana M.</au><au>Henriques, João G.</au><au>Castro, Ricardo A. E.</au><au>Maria, Teresa M. R.</au><au>Canotilho, João</au><au>Eusébio, M. Ermelinda S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Binary phase diagrams of pyridinecarboxamide isomers</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2017-12-01</date><risdate>2017</risdate><volume>130</volume><issue>3</issue><spage>1727</spage><epage>1733</epage><pages>1727-1733</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><abstract>Pyridinecarboxamide binary phase diagrams have been established using differential scanning calorimetry, infrared spectroscopy and X-ray powder diffraction. Simulated diagrams obtained using with the Schröder-van Laar and Prigogine–Defay equations are in very good agreement with experimental data. The binary systems nicotinamide (Form I)–picolinamide (Form II) and isonicotinamide (Form II)—picolinamide (Form I and Form II) occur as eutectic mixtures. Nicotinamide (Form I)—isonicotinamide (Forms II and Form I) solid–liquid phase diagram confirms formation of the cocrystal with molar ratio of 1:1, whose crystal structure was already solved by Báthori et al. (Cryst Growth Des 11:75–87,
12
) with X-ray diffraction on single crystals obtained by crystallization from common solution of nicotinamide and isonicotinamide. The corresponding eutectic composition and temperatures, beyond polymorphism of isonicotinamide and picolinamide under these molecular environments are discussed.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10973-017-6474-2</doi><tpages>7</tpages></addata></record> |
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| subjects | Analytical Chemistry Binary systems Calorimetry Chemistry Chemistry and Materials Science Crystal structure Crystallization Diffraction Eutectic composition Infrared spectroscopy Inorganic Chemistry Isomers Measurement Science and Instrumentation Niacinamide Nicotinamide Phase diagrams Physical Chemistry Polymer Sciences Polymorphism Pyridine Single crystals X ray powder diffraction X-ray diffraction |
| title | Binary phase diagrams of pyridinecarboxamide isomers |
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