Al-Pillared-Montmorillonite (AlPMt)/Poly(Methyl Methacrylate)(PMMA) Nanocomposites: The Effects of Solvent Types and Synthesis Methods
Al-pillared-montmorillonite (AlPMt)/poly(methyl methacrylate)(PMMA) nanocomposites were synthesized via melt blending method (MBM) and solution blending method (SBM). FTIR-ATR spectroscopy proved the interaction of AlPMt with PMMA polymer matrix. The thermogravimetric and differential scanning calor...
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Veröffentlicht in: | Advances in materials science 2017-09, Vol.17 (3), p.5-23 |
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creator | Kizilduman, B. K. Alkan, M. Doğan, M. Turhan, Y. |
description | Al-pillared-montmorillonite (AlPMt)/poly(methyl methacrylate)(PMMA) nanocomposites were synthesized via melt blending method (MBM) and solution blending method (SBM). FTIR-ATR spectroscopy proved the interaction of AlPMt with PMMA polymer matrix. The thermogravimetric and differential scanning calorimeter analyses showed that the thermal stability and the glass transition temperature (T
) of polymer matrix shifted to higher temperatures with increasing AlPMt content. Images showed that AlPMt dispersed at nanometer scale in polymer matrix. Contact angle measurements demonstrated that the hydrophilicity of the PMMA increased with incorporation of AlPMt. However, the thermal stability of clay/polymer nanocomposites (CPNs) was significantly changed with CPN preparation method. |
doi_str_mv | 10.1515/adms-2017-0012 |
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) of polymer matrix shifted to higher temperatures with increasing AlPMt content. Images showed that AlPMt dispersed at nanometer scale in polymer matrix. Contact angle measurements demonstrated that the hydrophilicity of the PMMA increased with incorporation of AlPMt. However, the thermal stability of clay/polymer nanocomposites (CPNs) was significantly changed with CPN preparation method.</description><identifier>ISSN: 2083-4799</identifier><identifier>ISSN: 1730-2439</identifier><identifier>EISSN: 2083-4799</identifier><identifier>DOI: 10.1515/adms-2017-0012</identifier><language>eng</language><publisher>Gdansk: De Gruyter Open</publisher><subject>Al-pillared-montmorillonite ; Clay ; Contact angle ; Differential scanning calorimetry ; Fourier transforms ; Glass fiber reinforced plastics ; Glass transition temperature ; Melt blending ; Montmorillonite ; nanocomposite ; Nanocomposites ; Poly(methyl methacrylate) ; Polymers ; Polymethyl methacrylate ; Solution blending ; Solvent effect ; Solvents ; Stability analysis ; Thermal analysis ; Thermal stability</subject><ispartof>Advances in materials science, 2017-09, Vol.17 (3), p.5-23</ispartof><rights>Copyright De Gruyter Open Sp. z o.o. 2017</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c288t-e4cbd940127e75b8d97df0afec7f486d229b6c509f47994faf62b98e22b79ab73</citedby><cites>FETCH-LOGICAL-c288t-e4cbd940127e75b8d97df0afec7f486d229b6c509f47994faf62b98e22b79ab73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.degruyter.com/document/doi/10.1515/adms-2017-0012/pdf$$EPDF$$P50$$Gwalterdegruyter$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.degruyter.com/document/doi/10.1515/adms-2017-0012/html$$EHTML$$P50$$Gwalterdegruyter$$Hfree_for_read</linktohtml><link.rule.ids>314,776,780,27901,27902,66901,68685</link.rule.ids></links><search><creatorcontrib>Kizilduman, B. K.</creatorcontrib><creatorcontrib>Alkan, M.</creatorcontrib><creatorcontrib>Doğan, M.</creatorcontrib><creatorcontrib>Turhan, Y.</creatorcontrib><title>Al-Pillared-Montmorillonite (AlPMt)/Poly(Methyl Methacrylate)(PMMA) Nanocomposites: The Effects of Solvent Types and Synthesis Methods</title><title>Advances in materials science</title><description>Al-pillared-montmorillonite (AlPMt)/poly(methyl methacrylate)(PMMA) nanocomposites were synthesized via melt blending method (MBM) and solution blending method (SBM). FTIR-ATR spectroscopy proved the interaction of AlPMt with PMMA polymer matrix. The thermogravimetric and differential scanning calorimeter analyses showed that the thermal stability and the glass transition temperature (T
) of polymer matrix shifted to higher temperatures with increasing AlPMt content. Images showed that AlPMt dispersed at nanometer scale in polymer matrix. Contact angle measurements demonstrated that the hydrophilicity of the PMMA increased with incorporation of AlPMt. However, the thermal stability of clay/polymer nanocomposites (CPNs) was significantly changed with CPN preparation method.</description><subject>Al-pillared-montmorillonite</subject><subject>Clay</subject><subject>Contact angle</subject><subject>Differential scanning calorimetry</subject><subject>Fourier transforms</subject><subject>Glass fiber reinforced plastics</subject><subject>Glass transition temperature</subject><subject>Melt blending</subject><subject>Montmorillonite</subject><subject>nanocomposite</subject><subject>Nanocomposites</subject><subject>Poly(methyl methacrylate)</subject><subject>Polymers</subject><subject>Polymethyl methacrylate</subject><subject>Solution blending</subject><subject>Solvent effect</subject><subject>Solvents</subject><subject>Stability analysis</subject><subject>Thermal analysis</subject><subject>Thermal stability</subject><issn>2083-4799</issn><issn>1730-2439</issn><issn>2083-4799</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNptULtOwzAUjRBIlMLKbImlHdLazsNxtwqVh9RApZY5cuJr2sqNi-2C8gN8Nwll6MB0z5XOQ-cEwS3BI5KQZCzkzoUUExZiTOhZ0KM4i8KYcX5-gi-DK-e2GKcRZVEv-J7qcLHRWliQYW5qvzO2fU298YAGU73I_XC8MLoZ5ODXjUbdEZVttPAwHCzyfDpEL6I2ldntjWtVboJWa0AzpaDyDhmFlkZ_Qu3RqtmDQ6KWaNnUfg1u437tjHTXwYUS2sHN3-0Hbw-z1f1TOH99fL6fzsOKZpkPIa5KyeO2HgOWlJnkTCos2iSm4iyVlPIyrRLMVVc1VkKltOQZUFoyLkoW9YO7o-_emo8DOF9szcHWbWRBeEqSiFGetqzRkVVZ45wFVeztZidsUxBcdFsX3dZFt3XRbd0KJkfBl9AerIR3e2hacOL-r5CwKIl-APyXhw8</recordid><startdate>20170901</startdate><enddate>20170901</enddate><creator>Kizilduman, B. 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K. ; Alkan, M. ; Doğan, M. ; Turhan, Y.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c288t-e4cbd940127e75b8d97df0afec7f486d229b6c509f47994faf62b98e22b79ab73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Al-pillared-montmorillonite</topic><topic>Clay</topic><topic>Contact angle</topic><topic>Differential scanning calorimetry</topic><topic>Fourier transforms</topic><topic>Glass fiber reinforced plastics</topic><topic>Glass transition temperature</topic><topic>Melt blending</topic><topic>Montmorillonite</topic><topic>nanocomposite</topic><topic>Nanocomposites</topic><topic>Poly(methyl methacrylate)</topic><topic>Polymers</topic><topic>Polymethyl methacrylate</topic><topic>Solution blending</topic><topic>Solvent effect</topic><topic>Solvents</topic><topic>Stability analysis</topic><topic>Thermal analysis</topic><topic>Thermal stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kizilduman, B. 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K.</au><au>Alkan, M.</au><au>Doğan, M.</au><au>Turhan, Y.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Al-Pillared-Montmorillonite (AlPMt)/Poly(Methyl Methacrylate)(PMMA) Nanocomposites: The Effects of Solvent Types and Synthesis Methods</atitle><jtitle>Advances in materials science</jtitle><date>2017-09-01</date><risdate>2017</risdate><volume>17</volume><issue>3</issue><spage>5</spage><epage>23</epage><pages>5-23</pages><issn>2083-4799</issn><issn>1730-2439</issn><eissn>2083-4799</eissn><abstract>Al-pillared-montmorillonite (AlPMt)/poly(methyl methacrylate)(PMMA) nanocomposites were synthesized via melt blending method (MBM) and solution blending method (SBM). FTIR-ATR spectroscopy proved the interaction of AlPMt with PMMA polymer matrix. The thermogravimetric and differential scanning calorimeter analyses showed that the thermal stability and the glass transition temperature (T
) of polymer matrix shifted to higher temperatures with increasing AlPMt content. Images showed that AlPMt dispersed at nanometer scale in polymer matrix. Contact angle measurements demonstrated that the hydrophilicity of the PMMA increased with incorporation of AlPMt. However, the thermal stability of clay/polymer nanocomposites (CPNs) was significantly changed with CPN preparation method.</abstract><cop>Gdansk</cop><pub>De Gruyter Open</pub><doi>10.1515/adms-2017-0012</doi><tpages>19</tpages><oa>free_for_read</oa></addata></record> |
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source | De Gruyter Open Access Journals; EZB-FREE-00999 freely available EZB journals |
subjects | Al-pillared-montmorillonite Clay Contact angle Differential scanning calorimetry Fourier transforms Glass fiber reinforced plastics Glass transition temperature Melt blending Montmorillonite nanocomposite Nanocomposites Poly(methyl methacrylate) Polymers Polymethyl methacrylate Solution blending Solvent effect Solvents Stability analysis Thermal analysis Thermal stability |
title | Al-Pillared-Montmorillonite (AlPMt)/Poly(Methyl Methacrylate)(PMMA) Nanocomposites: The Effects of Solvent Types and Synthesis Methods |
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