Al-Pillared-Montmorillonite (AlPMt)/Poly(Methyl Methacrylate)(PMMA) Nanocomposites: The Effects of Solvent Types and Synthesis Methods

Al-pillared-montmorillonite (AlPMt)/poly(methyl methacrylate)(PMMA) nanocomposites were synthesized via melt blending method (MBM) and solution blending method (SBM). FTIR-ATR spectroscopy proved the interaction of AlPMt with PMMA polymer matrix. The thermogravimetric and differential scanning calor...

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Veröffentlicht in:Advances in materials science 2017-09, Vol.17 (3), p.5-23
Hauptverfasser: Kizilduman, B. K., Alkan, M., Doğan, M., Turhan, Y.
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container_title Advances in materials science
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creator Kizilduman, B. K.
Alkan, M.
Doğan, M.
Turhan, Y.
description Al-pillared-montmorillonite (AlPMt)/poly(methyl methacrylate)(PMMA) nanocomposites were synthesized via melt blending method (MBM) and solution blending method (SBM). FTIR-ATR spectroscopy proved the interaction of AlPMt with PMMA polymer matrix. The thermogravimetric and differential scanning calorimeter analyses showed that the thermal stability and the glass transition temperature (T ) of polymer matrix shifted to higher temperatures with increasing AlPMt content. Images showed that AlPMt dispersed at nanometer scale in polymer matrix. Contact angle measurements demonstrated that the hydrophilicity of the PMMA increased with incorporation of AlPMt. However, the thermal stability of clay/polymer nanocomposites (CPNs) was significantly changed with CPN preparation method.
doi_str_mv 10.1515/adms-2017-0012
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source De Gruyter Open Access Journals; EZB-FREE-00999 freely available EZB journals
subjects Al-pillared-montmorillonite
Clay
Contact angle
Differential scanning calorimetry
Fourier transforms
Glass fiber reinforced plastics
Glass transition temperature
Melt blending
Montmorillonite
nanocomposite
Nanocomposites
Poly(methyl methacrylate)
Polymers
Polymethyl methacrylate
Solution blending
Solvent effect
Solvents
Stability analysis
Thermal analysis
Thermal stability
title Al-Pillared-Montmorillonite (AlPMt)/Poly(Methyl Methacrylate)(PMMA) Nanocomposites: The Effects of Solvent Types and Synthesis Methods
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