Binder-free polyaniline interconnected metal hexacyanoferrates nanocomposites (Metal = Ni, Co) on carbon fibers for flexible supercapacitors
Improvement of the electrical conductivity, specific capacitance and binder-free polyaniline (PANI) interconnected with metal(II) hexacyanoferrate(III) (MHCF) nanocomposites (M = Ni, Co) on flexible carbon fibers (CF) were designed in our present research goal. PANI/MHCF/CF nanocomposites were prepa...
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| Veröffentlicht in: | Journal of materials science. Materials in electronics 2017-12, Vol.28 (23), p.17405-17413 |
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| container_issue | 23 |
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| container_title | Journal of materials science. Materials in electronics |
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| creator | Maier, M. A. Suresh Babu, R. Sampaio, D. M. de Barros, A. L. F. |
| description | Improvement of the electrical conductivity, specific capacitance and binder-free polyaniline (PANI) interconnected with metal(II) hexacyanoferrate(III) (MHCF) nanocomposites (M = Ni, Co) on flexible carbon fibers (CF) were designed in our present research goal. PANI/MHCF/CF nanocomposites were prepared by one-step co-polymerization method. Electrochemical studies like cyclic voltammetry, galvanostatic charge–discharge and electrochemical impedance spectroscopy were analyzed. Under the optimized conditions, the nanocomposites demonstrated remarkable electrochemical performances as supercapacitor electrode with outstanding specific capacitances of ~725 F g
−1
at a current density of 1 A g
−1
, and retained ~325 F g
−1
even at a high current density of 20 A g
−1
in 0.5 M H
2
SO
4
+ 0.5 M Na
2
SO
4
solution. The excellent cycling stability with capacitance retention of 80% after 1000 cycles may be a potential electrode material for future supercapacitor when its cycling stability and rate performance are addressed. |
| doi_str_mv | 10.1007/s10854-017-7674-z |
| format | Article |
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−1
at a current density of 1 A g
−1
, and retained ~325 F g
−1
even at a high current density of 20 A g
−1
in 0.5 M H
2
SO
4
+ 0.5 M Na
2
SO
4
solution. The excellent cycling stability with capacitance retention of 80% after 1000 cycles may be a potential electrode material for future supercapacitor when its cycling stability and rate performance are addressed.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-017-7674-z</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Capacitance ; Carbon fibers ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Cobalt ; Copolymerization ; Current density ; Electrical resistivity ; Electrochemical impedance spectroscopy ; Electrode materials ; Electrodes ; Materials Science ; Nanocomposites ; Nickel ; Optical and Electronic Materials ; Polyanilines ; Stability ; Supercapacitors</subject><ispartof>Journal of materials science. Materials in electronics, 2017-12, Vol.28 (23), p.17405-17413</ispartof><rights>Springer Science+Business Media, LLC 2017</rights><rights>Journal of Materials Science: Materials in Electronics is a copyright of Springer, 2017.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c355t-aaecf8896b94566bede98e5e3e1999add11d38578e1b26b3ddb5367ee96d3d6a3</citedby><cites>FETCH-LOGICAL-c355t-aaecf8896b94566bede98e5e3e1999add11d38578e1b26b3ddb5367ee96d3d6a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10854-017-7674-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10854-017-7674-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Maier, M. A.</creatorcontrib><creatorcontrib>Suresh Babu, R.</creatorcontrib><creatorcontrib>Sampaio, D. M.</creatorcontrib><creatorcontrib>de Barros, A. L. F.</creatorcontrib><title>Binder-free polyaniline interconnected metal hexacyanoferrates nanocomposites (Metal = Ni, Co) on carbon fibers for flexible supercapacitors</title><title>Journal of materials science. Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>Improvement of the electrical conductivity, specific capacitance and binder-free polyaniline (PANI) interconnected with metal(II) hexacyanoferrate(III) (MHCF) nanocomposites (M = Ni, Co) on flexible carbon fibers (CF) were designed in our present research goal. PANI/MHCF/CF nanocomposites were prepared by one-step co-polymerization method. Electrochemical studies like cyclic voltammetry, galvanostatic charge–discharge and electrochemical impedance spectroscopy were analyzed. Under the optimized conditions, the nanocomposites demonstrated remarkable electrochemical performances as supercapacitor electrode with outstanding specific capacitances of ~725 F g
−1
at a current density of 1 A g
−1
, and retained ~325 F g
−1
even at a high current density of 20 A g
−1
in 0.5 M H
2
SO
4
+ 0.5 M Na
2
SO
4
solution. The excellent cycling stability with capacitance retention of 80% after 1000 cycles may be a potential electrode material for future supercapacitor when its cycling stability and rate performance are addressed.</description><subject>Capacitance</subject><subject>Carbon fibers</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Cobalt</subject><subject>Copolymerization</subject><subject>Current density</subject><subject>Electrical resistivity</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrode materials</subject><subject>Electrodes</subject><subject>Materials Science</subject><subject>Nanocomposites</subject><subject>Nickel</subject><subject>Optical and Electronic Materials</subject><subject>Polyanilines</subject><subject>Stability</subject><subject>Supercapacitors</subject><issn>0957-4522</issn><issn>1573-482X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kL1qHDEUhUWIIWs7D5BOkCaGyJZGI41UpLCX-Af808TgTmikO4nMrDSRZsF25dZdnjFPEi3rwk2Ky-HCd86Bg9AnRg8Zpd1RYVSJllDWkU52LXl6hxZMdJy0qrl7jxZUi460omk-oN1S7imlsuVqgf6chOghkyED4CmNjzaGMUTAIc6QXYoR3Awer2C2I_4FD9ZVJA2Qs52h4Fgfl1ZTKmHzfrnacH-fX77Vuw5f8TId4BSxs7mvMoQecsFDyngY4SH0I-CynmqRnawLc8plH-0Mdizw8VX30O3p9x_Lc3J5c3axPL4kjgsxE2vBDUpp2etWSNmDB61AAAemtbbeM-a5Ep0C1jey5973gssOQEvPvbR8D33e5k45_V5Dmc19WudYKw3TQrVaMdVUim0pl1MpGQYz5bCy-dEwajbDm-3wpg5vNsObp-pptp5S2fgT8pvk_5r-ARDCjKw</recordid><startdate>20171201</startdate><enddate>20171201</enddate><creator>Maier, M. A.</creator><creator>Suresh Babu, R.</creator><creator>Sampaio, D. M.</creator><creator>de Barros, A. L. 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M. ; de Barros, A. L. F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c355t-aaecf8896b94566bede98e5e3e1999add11d38578e1b26b3ddb5367ee96d3d6a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Capacitance</topic><topic>Carbon fibers</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Cobalt</topic><topic>Copolymerization</topic><topic>Current density</topic><topic>Electrical resistivity</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrode materials</topic><topic>Electrodes</topic><topic>Materials Science</topic><topic>Nanocomposites</topic><topic>Nickel</topic><topic>Optical and Electronic Materials</topic><topic>Polyanilines</topic><topic>Stability</topic><topic>Supercapacitors</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Maier, M. A.</creatorcontrib><creatorcontrib>Suresh Babu, R.</creatorcontrib><creatorcontrib>Sampaio, D. M.</creatorcontrib><creatorcontrib>de Barros, A. L. 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Materials in electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Maier, M. A.</au><au>Suresh Babu, R.</au><au>Sampaio, D. M.</au><au>de Barros, A. L. F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Binder-free polyaniline interconnected metal hexacyanoferrates nanocomposites (Metal = Ni, Co) on carbon fibers for flexible supercapacitors</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2017-12-01</date><risdate>2017</risdate><volume>28</volume><issue>23</issue><spage>17405</spage><epage>17413</epage><pages>17405-17413</pages><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>Improvement of the electrical conductivity, specific capacitance and binder-free polyaniline (PANI) interconnected with metal(II) hexacyanoferrate(III) (MHCF) nanocomposites (M = Ni, Co) on flexible carbon fibers (CF) were designed in our present research goal. PANI/MHCF/CF nanocomposites were prepared by one-step co-polymerization method. Electrochemical studies like cyclic voltammetry, galvanostatic charge–discharge and electrochemical impedance spectroscopy were analyzed. Under the optimized conditions, the nanocomposites demonstrated remarkable electrochemical performances as supercapacitor electrode with outstanding specific capacitances of ~725 F g
−1
at a current density of 1 A g
−1
, and retained ~325 F g
−1
even at a high current density of 20 A g
−1
in 0.5 M H
2
SO
4
+ 0.5 M Na
2
SO
4
solution. The excellent cycling stability with capacitance retention of 80% after 1000 cycles may be a potential electrode material for future supercapacitor when its cycling stability and rate performance are addressed.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-017-7674-z</doi><tpages>9</tpages></addata></record> |
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| subjects | Capacitance Carbon fibers Characterization and Evaluation of Materials Chemistry and Materials Science Cobalt Copolymerization Current density Electrical resistivity Electrochemical impedance spectroscopy Electrode materials Electrodes Materials Science Nanocomposites Nickel Optical and Electronic Materials Polyanilines Stability Supercapacitors |
| title | Binder-free polyaniline interconnected metal hexacyanoferrates nanocomposites (Metal = Ni, Co) on carbon fibers for flexible supercapacitors |
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