Novel low melting point binary nitrates for thermal energy storage applications

19 kinds of different ratio of binary mixed molten salt have been formulated, and the formulation of a low melting point binary molten salt has been exploited and its primary thermophysical properties were presented here. The eutectic temperature of the selected binary salt mixture was determined to...

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Veröffentlicht in:Solar energy materials and solar cells 2017-05, Vol.164, p.114-121
Hauptverfasser: WU, Yu-ting, LI, Ying, LU, Yuan-wei, Wang, Hui-fu, MA, Chong-fang
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container_title Solar energy materials and solar cells
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creator WU, Yu-ting
LI, Ying
LU, Yuan-wei
Wang, Hui-fu
MA, Chong-fang
description 19 kinds of different ratio of binary mixed molten salt have been formulated, and the formulation of a low melting point binary molten salt has been exploited and its primary thermophysical properties were presented here. The eutectic temperature of the selected binary salt mixture was determined to be 116.9℃. Further the decomposition point, specific heat, density, viscosity, thermal conductivity and corrosion were determined respectively. Sensible thermal storage cost of the novel eutectic mixture was found to be lower than that of conventional solar salt and HITEC salt. The performance of the binary salt mixture taken at different stages during the test of 1200-h exposure to constant high temperature was discussed based on the results obtained from long-term thermal stability studies. The results show that thermodynamic properties of the molten salt show perfect repeatability before and after the experiments, and most variations rate of the thermal physical properties is within±10%, which can be considered as an implication that the candidate has good thermal stability. Therefore, this new kind of binary molten salt thermal storage materials is more competitive and promising to be used in solar power generation systems while providing a comprehensive data for its engineering application and theoretical research. •A novel binary low melting nitrates with low cost and good thermal stability was obtained.•Main thermophysical properties of the novel binary nitrates were measured.•The long-term stability test of 1200-h constant high temperature experiments were measured for the novel binary nitrates.
doi_str_mv 10.1016/j.solmat.2017.02.021
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Therefore, this new kind of binary molten salt thermal storage materials is more competitive and promising to be used in solar power generation systems while providing a comprehensive data for its engineering application and theoretical research. •A novel binary low melting nitrates with low cost and good thermal stability was obtained.•Main thermophysical properties of the novel binary nitrates were measured.•The long-term stability test of 1200-h constant high temperature experiments were measured for the novel binary nitrates.</description><identifier>ISSN: 0927-0248</identifier><identifier>EISSN: 1879-3398</identifier><identifier>DOI: 10.1016/j.solmat.2017.02.021</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Binary eutectic temperature ; Binary molten salt ; Competitive materials ; Data processing ; Decomposition ; Electric power generation ; Energy storage ; Eutectics ; Heat conductivity ; High temperature ; Melting ; Melting point ; Molten salts ; Nitrates ; Physical properties ; Salts ; Solar generators ; Solar power ; Specific heat ; Studies ; Thermal conductivity ; Thermal energy ; Thermal stability ; Thermal storage ; Thermal storage materials ; Thermodynamic properties ; Thermodynamics ; Thermophysical properties ; Viscosity</subject><ispartof>Solar energy materials and solar cells, 2017-05, Vol.164, p.114-121</ispartof><rights>2017 Elsevier B.V.</rights><rights>Copyright Elsevier BV May 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c334t-3266b1b505c2f7d981ba105e568aa91bb647a1619ec5b61a3f128dd25c8a84fb3</citedby><cites>FETCH-LOGICAL-c334t-3266b1b505c2f7d981ba105e568aa91bb647a1619ec5b61a3f128dd25c8a84fb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0927024817300739$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65534</link.rule.ids></links><search><creatorcontrib>WU, Yu-ting</creatorcontrib><creatorcontrib>LI, Ying</creatorcontrib><creatorcontrib>LU, Yuan-wei</creatorcontrib><creatorcontrib>Wang, Hui-fu</creatorcontrib><creatorcontrib>MA, Chong-fang</creatorcontrib><title>Novel low melting point binary nitrates for thermal energy storage applications</title><title>Solar energy materials and solar cells</title><description>19 kinds of different ratio of binary mixed molten salt have been formulated, and the formulation of a low melting point binary molten salt has been exploited and its primary thermophysical properties were presented here. 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The eutectic temperature of the selected binary salt mixture was determined to be 116.9℃. Further the decomposition point, specific heat, density, viscosity, thermal conductivity and corrosion were determined respectively. Sensible thermal storage cost of the novel eutectic mixture was found to be lower than that of conventional solar salt and HITEC salt. The performance of the binary salt mixture taken at different stages during the test of 1200-h exposure to constant high temperature was discussed based on the results obtained from long-term thermal stability studies. The results show that thermodynamic properties of the molten salt show perfect repeatability before and after the experiments, and most variations rate of the thermal physical properties is within±10%, which can be considered as an implication that the candidate has good thermal stability. 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subjects Binary eutectic temperature
Binary molten salt
Competitive materials
Data processing
Decomposition
Electric power generation
Energy storage
Eutectics
Heat conductivity
High temperature
Melting
Melting point
Molten salts
Nitrates
Physical properties
Salts
Solar generators
Solar power
Specific heat
Studies
Thermal conductivity
Thermal energy
Thermal stability
Thermal storage
Thermal storage materials
Thermodynamic properties
Thermodynamics
Thermophysical properties
Viscosity
title Novel low melting point binary nitrates for thermal energy storage applications
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