Influence of Al2O3 on the performance of CeO2 used as catalyst in the direct carboxylation of methanol to dimethylcarbonate and the elucidation of the reaction mechanism

The reaction mechanism for the carboxylation of methanol to dimethylcarbonate has been elucidated by using DRIFT and solid state and solution multinuclear NMR spectroscopy. Modified ceria catalysts perform better than ceria. In this paper we show that modification of ceria by loading alumina strongl...

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Veröffentlicht in:	Journal of catalysis 2010, Vol.269 (1), p.44-52
Hauptverfasser:	ARESTA, Michele, DIBENEDETTO, Angela, PASTORE, Carlo, ANGELINI, Antonella, ARESTA, Brunella, PAPAI, Imre
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon Catalysis Catalysts Chemistry Exact sciences and technology General and physical chemistry Methanol Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Online-Zugang:	Volltext
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