Selective hydrogenation of chloronitrobenzene to chloroaniline in supercritical carbon dioxide over Ni/TiO2: Significance of molecular interactions

The chemoselective hydrogenation of chloronitrobenzene to chloroaniline can be achieved at any conversion levels up to 100% over Ni/TiO2 in scCO2 at 35°C. The hydrogenation of chloronitrobenzene to chloroaniline was investigated over Ni/TiO2 at 35°C in supercritical CO2 (scCO2 ), ethanol, and n-hexa...

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Veröffentlicht in:	Journal of catalysis 2010, Vol.269 (1), p.131-139
Hauptverfasser:	XIANGCHUN MENG, HAIYANG CHENG, FUJITA, Shin-Ichiro, YUFEN HAO, YANJIAO SHANG, YANCUN YU, SHUXIA CAI, FENGYU ZHAO, ARAI, Masahiko
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon dioxide Catalysis Chemistry Exact sciences and technology General and physical chemistry Hydrogenation Molecular biology Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Online-Zugang:	Volltext
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