Dramatic liquid-phase dehydrogenation rate enhancements using gas-phase hydrogen acceptors

The dehydrogenation of 1,2,3,4-tetrahydrocarbazole (THCZ) to form carbazole (CZ) over supported palladium catalysts was examined in the presence of hydrogen acceptors. As expected, liquid hydrogen acceptors increased the rate of reaction but, importantly, gaseous hydrogen acceptors also have been us...

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Veröffentlicht in:	Journal of catalysis 2007-10, Vol.251 (2), p.338-344
Hauptverfasser:	Hindle, K.T., Burch, R., Crawford, P., Hardacre, C., Hu, P., Kalirai, B., Rooney, D.W.
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbazole Catalysis Catalysts Chemical reactions Chemistry Dehydrogenation DFT Exact sciences and technology Gases General and physical chemistry Hydrogen Hydrogen acceptor Liquids Naphthalene Palladium Tetrahydrocarbazole Tetrahydronaphthalene Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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