Pd nanoparticles embedded in sponge-like porous silica as a Suzuki–Miyaura catalyst: Similarities and differences with homogeneous catalysts

Pd nanoparticles of homogeneous size were prepared by PdCl 2 reduction with hydrazine in an inverse micelle microemulsion. These Pd nanoparticles were stabilized with dodecanethiol and 3-mercaptopropyltrimethoxysilane. The latter ligands were co-condensed with tetraethylorthosilicate, yielding an am...

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