Synthesis of a new type of immobilized chiral salen Mn(III) complex as effective catalysts for asymmetric epoxidation of unfunctionalized olefins

A new type of inorganic–organic hybrid materials—zirconium poly(styrene-phenylvinylphosphonate)-phosphate (ZPS-PVPA) was designed and synthesized. A series of new heterogeneous catalysts was obtained by grafting diamine or polyamine on ZPS-PVPA and subsequently axial coordination with chiral salen M...

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Veröffentlicht in:	Journal of catalysis 2009-02, Vol.262 (1), p.9-17
Hauptverfasser:	Gong, Biwei, Fu, Xiangkai, Chen, Junxian, Li, Yuedong, Zou, Xiaochuan, Tu, Xiaobo, Ding, Pingping, Ma, Liping
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalysts Chemical reactions Chemical synthesis Chemistry Chiral salen Mn(III) Enantioselective epoxidation Exact sciences and technology General and physical chemistry Heterogeneous catalysts Materials science Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Unfunctionalized olefins Zirconium poly(styrene-phenylvinylphosphonate)-phosphate
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