Continuous catalytic oxidation of solid alcohols in supercritical CO2 : A parametric and spectroscopic study of the transformation of cinnamyl alcohol over Pd/Al2O3

Cinnamyl alcohol was oxidized to cinnamaldehyde in a continuous fixed-bed reactor with molecular oxygen over an alumina-supported palladium catalyst in supercritical carbon dioxide modified with toluene. A strong dependence of the reaction performance on pressure and oxygen concentration in the feed...

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Veröffentlicht in:Journal of catalysis 2006-06, Vol.240 (2), p.126-136
Hauptverfasser: CARAVATI, Matteo, MEIER, Daniel M, GRUNWALDT, Jan-Dierk, BAIKER, Alfons
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Sprache:eng
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