Balancing Steric and Electronic Effects in Carbonyl–Phosphine Molybdacarboranes

Analysis of the literature structures [(CO)(PPh3)2MC2B9H11] and [(CO)2(PPh3)MC2B9H11] suggests that in [L3MC2B9H11] metallacarboranes the trans influence of CO is greater than that of PPh3. Extending this study to the [L4MC2B9H11] system the new molybdacarboranes [3,3,3‐(CO)3‐3‐PPh3‐3,1,2‐closo‐MoC2...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	European journal of inorganic chemistry 2017-10, Vol.2017 (38-39), p.4581-4588
Hauptverfasser:	Robertson, Alasdair P. M., Reckziegel, Alexander, Jones, John J., Rosair, Georgina M., Welch, Alan J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Cages Carbonyl ligands Carbonyls Carboranes Crowding Electronic effects Inorganic chemistry Isomers Ligands Phosphane ligands Steric effects
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!