Polyhalogenated Decaborate and 1‐Ammoniododecaborate Ions: An Improved Synthesis with Elemental Halogens, and Physicochemical and Chemical Properties

Currently, the whole area of polyhalogenated polyhedral anions is undergoing a renaissance due to their high stability, the kinetic inertness of the cage B–X (X = F, Cl, Br, I) bonds and facile tuning of the physicochemical properties (stability, polarity, lipophilicity, pKa, solubility, electrochem...

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Veröffentlicht in:	European journal of inorganic chemistry 2017-10, Vol.2017 (38-39), p.4499-4509
Hauptverfasser:	Holub, Josef, El Anwar, Suzan, Jelínek, Tomáš, Fojt, Lukáš, Růžičková, Zdeňka, Šolínová, Veronika, Kašička, Václav, Gabel, Detlef, Grüner, Bohumír
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Boranes Borates Capillary electrophoresis Chemical bonds Chemical properties Chemical synthesis Electrochemistry Halogenation Halogens Inorganic chemistry Lipophilicity Polarity Stability
Online-Zugang:	Volltext
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