Hybrid Ti-MoS2 Coatings for Dry Machining of Aluminium Alloys
Combinatorial deposition, comprising filtered cathodic vacuum arc (FCVA) and physical vapor deposition (PVD) magnetron sputtering is employed to deposit molybdenum disulphide (MoS2) and titanium (Ti) thin films onto TiB2-coated tool inserts specifically designed for the dry machining of aluminium al...
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Veröffentlicht in: | Coatings (Basel) 2017-09, Vol.7 (9), p.149 |
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creator | Brzezinka, Tomasz Rao, Jeff Chowdhury, Mohamad Kohlscheen, Joern Fox Rabinovich, German Veldhuis, Stephen Endrino, Jose |
description | Combinatorial deposition, comprising filtered cathodic vacuum arc (FCVA) and physical vapor deposition (PVD) magnetron sputtering is employed to deposit molybdenum disulphide (MoS2) and titanium (Ti) thin films onto TiB2-coated tool inserts specifically designed for the dry machining of aluminium alloys. Titanium is deposited by FCVA while MoS2 is magnetron sputtered. The deposition set up allows several compositions of Ti-MoS2 to be deposited simultaneously, with Ti content ranging between 5 and 96 at. %, and their machining performances to be evaluated. Milling took place using a CNC Vertical Machining Center at a 877 mm/min feed rate. The effect of different coating compositional ratios on the degree of aluminium sticking when a milling insert is used to face mill an Al alloy (SAE 6061) was investigated using a combination of energy-dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy (XPS) analysis. XPS studies suggest that the greater degree of Al sticking on the rake face of the inserts is due to the formation of greater amounts of non-protective Ti-O phases. EDX mapping of the milling inserts after machining reveal that a Ti:MoS2 ratio of around 0.39 prevents Al from sticking to the tool edges. Since we prevent Al from sticking to the tool surface, the resultant machined surface finish is improved thus validating the machining performance of TiB2-coated tools using optimum compositions of Ti:MoS2 thin film coatings. |
doi_str_mv | 10.3390/coatings7090149 |
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Titanium is deposited by FCVA while MoS2 is magnetron sputtered. The deposition set up allows several compositions of Ti-MoS2 to be deposited simultaneously, with Ti content ranging between 5 and 96 at. %, and their machining performances to be evaluated. Milling took place using a CNC Vertical Machining Center at a 877 mm/min feed rate. The effect of different coating compositional ratios on the degree of aluminium sticking when a milling insert is used to face mill an Al alloy (SAE 6061) was investigated using a combination of energy-dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy (XPS) analysis. XPS studies suggest that the greater degree of Al sticking on the rake face of the inserts is due to the formation of greater amounts of non-protective Ti-O phases. EDX mapping of the milling inserts after machining reveal that a Ti:MoS2 ratio of around 0.39 prevents Al from sticking to the tool edges. Since we prevent Al from sticking to the tool surface, the resultant machined surface finish is improved thus validating the machining performance of TiB2-coated tools using optimum compositions of Ti:MoS2 thin film coatings.</description><identifier>ISSN: 2079-6412</identifier><identifier>EISSN: 2079-6412</identifier><identifier>DOI: 10.3390/coatings7090149</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Aluminum base alloys ; Arc deposition ; Coating effects ; Combinatorial analysis ; Composition effects ; Dry machining ; Energy consumption ; Feed rate ; Inserts ; Machining ; Magnetron sputtering ; Milling (machining) ; Molybdenum disulfide ; Numerical controls ; Physical vapor deposition ; Protective coatings ; Spectrum analysis ; Surface finish ; Thin film coatings ; Thin films ; Titanium base alloys ; Titanium diboride ; X ray photoelectron spectroscopy ; X-ray spectroscopy</subject><ispartof>Coatings (Basel), 2017-09, Vol.7 (9), p.149</ispartof><rights>Copyright MDPI AG 2017</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c240t-f5a36f7ac921f332337b1aed08090a909e9706da8d9f10871bf1975b265e47fb3</citedby><cites>FETCH-LOGICAL-c240t-f5a36f7ac921f332337b1aed08090a909e9706da8d9f10871bf1975b265e47fb3</cites><orcidid>0000-0001-8209-7499</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Brzezinka, Tomasz</creatorcontrib><creatorcontrib>Rao, Jeff</creatorcontrib><creatorcontrib>Chowdhury, Mohamad</creatorcontrib><creatorcontrib>Kohlscheen, Joern</creatorcontrib><creatorcontrib>Fox Rabinovich, German</creatorcontrib><creatorcontrib>Veldhuis, Stephen</creatorcontrib><creatorcontrib>Endrino, Jose</creatorcontrib><title>Hybrid Ti-MoS2 Coatings for Dry Machining of Aluminium Alloys</title><title>Coatings (Basel)</title><description>Combinatorial deposition, comprising filtered cathodic vacuum arc (FCVA) and physical vapor deposition (PVD) magnetron sputtering is employed to deposit molybdenum disulphide (MoS2) and titanium (Ti) thin films onto TiB2-coated tool inserts specifically designed for the dry machining of aluminium alloys. Titanium is deposited by FCVA while MoS2 is magnetron sputtered. The deposition set up allows several compositions of Ti-MoS2 to be deposited simultaneously, with Ti content ranging between 5 and 96 at. %, and their machining performances to be evaluated. Milling took place using a CNC Vertical Machining Center at a 877 mm/min feed rate. The effect of different coating compositional ratios on the degree of aluminium sticking when a milling insert is used to face mill an Al alloy (SAE 6061) was investigated using a combination of energy-dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy (XPS) analysis. XPS studies suggest that the greater degree of Al sticking on the rake face of the inserts is due to the formation of greater amounts of non-protective Ti-O phases. EDX mapping of the milling inserts after machining reveal that a Ti:MoS2 ratio of around 0.39 prevents Al from sticking to the tool edges. Since we prevent Al from sticking to the tool surface, the resultant machined surface finish is improved thus validating the machining performance of TiB2-coated tools using optimum compositions of Ti:MoS2 thin film coatings.</description><subject>Aluminum base alloys</subject><subject>Arc deposition</subject><subject>Coating effects</subject><subject>Combinatorial analysis</subject><subject>Composition effects</subject><subject>Dry machining</subject><subject>Energy consumption</subject><subject>Feed rate</subject><subject>Inserts</subject><subject>Machining</subject><subject>Magnetron sputtering</subject><subject>Milling (machining)</subject><subject>Molybdenum disulfide</subject><subject>Numerical controls</subject><subject>Physical vapor deposition</subject><subject>Protective coatings</subject><subject>Spectrum analysis</subject><subject>Surface finish</subject><subject>Thin film coatings</subject><subject>Thin films</subject><subject>Titanium base alloys</subject><subject>Titanium diboride</subject><subject>X ray photoelectron spectroscopy</subject><subject>X-ray spectroscopy</subject><issn>2079-6412</issn><issn>2079-6412</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdkL1PwzAQxS0EElXpzGqJOfRsJ3FuYKjCR5FaMVBmy0lsSJXExW6G_PcYtQPilnt3evrd6RFyy-BeCIRl7fSxHT6DBASW4gWZcZCY5Cnjl3_0NVmEsIdYyETBcEYe1lPl24bu2mTr3jktzyBqnaePfqJbXX-1Q1xRZ-mqG_s4jH1UnZvCDbmyugtmce5z8vH8tCvXyebt5bVcbZKap3BMbKZFbqWukTMrBBdCVkybBor4rkZAgxLyRhcNWgaFZJVlKLOK55lJpa3EnNyduAfvvkcTjmrvRj_Ek4phxvM0j6ToWp5ctXcheGPVwbe99pNioH5jUv9iEj8qglp2</recordid><startdate>20170916</startdate><enddate>20170916</enddate><creator>Brzezinka, Tomasz</creator><creator>Rao, Jeff</creator><creator>Chowdhury, Mohamad</creator><creator>Kohlscheen, Joern</creator><creator>Fox Rabinovich, German</creator><creator>Veldhuis, Stephen</creator><creator>Endrino, Jose</creator><general>MDPI AG</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0001-8209-7499</orcidid></search><sort><creationdate>20170916</creationdate><title>Hybrid Ti-MoS2 Coatings for Dry Machining of Aluminium Alloys</title><author>Brzezinka, Tomasz ; Rao, Jeff ; Chowdhury, Mohamad ; Kohlscheen, Joern ; Fox Rabinovich, German ; Veldhuis, Stephen ; Endrino, Jose</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c240t-f5a36f7ac921f332337b1aed08090a909e9706da8d9f10871bf1975b265e47fb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Aluminum base alloys</topic><topic>Arc deposition</topic><topic>Coating effects</topic><topic>Combinatorial analysis</topic><topic>Composition effects</topic><topic>Dry machining</topic><topic>Energy consumption</topic><topic>Feed rate</topic><topic>Inserts</topic><topic>Machining</topic><topic>Magnetron sputtering</topic><topic>Milling (machining)</topic><topic>Molybdenum disulfide</topic><topic>Numerical controls</topic><topic>Physical vapor deposition</topic><topic>Protective coatings</topic><topic>Spectrum analysis</topic><topic>Surface finish</topic><topic>Thin film coatings</topic><topic>Thin films</topic><topic>Titanium base alloys</topic><topic>Titanium diboride</topic><topic>X ray photoelectron spectroscopy</topic><topic>X-ray spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Brzezinka, Tomasz</creatorcontrib><creatorcontrib>Rao, Jeff</creatorcontrib><creatorcontrib>Chowdhury, Mohamad</creatorcontrib><creatorcontrib>Kohlscheen, Joern</creatorcontrib><creatorcontrib>Fox Rabinovich, German</creatorcontrib><creatorcontrib>Veldhuis, Stephen</creatorcontrib><creatorcontrib>Endrino, Jose</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection (Proquest) (PQ_SDU_P3)</collection><collection>Materials Research Database</collection><collection>https://resources.nclive.org/materials</collection><collection>Materials science collection</collection><collection>ProQuest - Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Coatings (Basel)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Brzezinka, Tomasz</au><au>Rao, Jeff</au><au>Chowdhury, Mohamad</au><au>Kohlscheen, Joern</au><au>Fox Rabinovich, German</au><au>Veldhuis, Stephen</au><au>Endrino, Jose</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hybrid Ti-MoS2 Coatings for Dry Machining of Aluminium Alloys</atitle><jtitle>Coatings (Basel)</jtitle><date>2017-09-16</date><risdate>2017</risdate><volume>7</volume><issue>9</issue><spage>149</spage><pages>149-</pages><issn>2079-6412</issn><eissn>2079-6412</eissn><abstract>Combinatorial deposition, comprising filtered cathodic vacuum arc (FCVA) and physical vapor deposition (PVD) magnetron sputtering is employed to deposit molybdenum disulphide (MoS2) and titanium (Ti) thin films onto TiB2-coated tool inserts specifically designed for the dry machining of aluminium alloys. Titanium is deposited by FCVA while MoS2 is magnetron sputtered. The deposition set up allows several compositions of Ti-MoS2 to be deposited simultaneously, with Ti content ranging between 5 and 96 at. %, and their machining performances to be evaluated. Milling took place using a CNC Vertical Machining Center at a 877 mm/min feed rate. The effect of different coating compositional ratios on the degree of aluminium sticking when a milling insert is used to face mill an Al alloy (SAE 6061) was investigated using a combination of energy-dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy (XPS) analysis. XPS studies suggest that the greater degree of Al sticking on the rake face of the inserts is due to the formation of greater amounts of non-protective Ti-O phases. EDX mapping of the milling inserts after machining reveal that a Ti:MoS2 ratio of around 0.39 prevents Al from sticking to the tool edges. Since we prevent Al from sticking to the tool surface, the resultant machined surface finish is improved thus validating the machining performance of TiB2-coated tools using optimum compositions of Ti:MoS2 thin film coatings.</abstract><cop>Basel</cop><pub>MDPI AG</pub><doi>10.3390/coatings7090149</doi><orcidid>https://orcid.org/0000-0001-8209-7499</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Aluminum base alloys Arc deposition Coating effects Combinatorial analysis Composition effects Dry machining Energy consumption Feed rate Inserts Machining Magnetron sputtering Milling (machining) Molybdenum disulfide Numerical controls Physical vapor deposition Protective coatings Spectrum analysis Surface finish Thin film coatings Thin films Titanium base alloys Titanium diboride X ray photoelectron spectroscopy X-ray spectroscopy |
title | Hybrid Ti-MoS2 Coatings for Dry Machining of Aluminium Alloys |
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