Electrochemical properties of the NiCl2 cathode with nickel foam substrate for thermal batteries

•We provide an alternative to the stainless steel substrate for NiCl2 thermal battery.•The impregnation of NiCl2 into the nickel foam was prepared by screen printing.•The peak voltage of NiCl2 cell with nickel foam substrate can reach 2.55V.•The NiCl2-based battery with nickel foam substrate has a h...

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Veröffentlicht in:Materials letters 2017-11, Vol.207, p.198-201
Hauptverfasser: Hu, Jing, Chu, Ying, Tian, Qianqiu, Guo, Shengnan, Yang, Ming, Wang, Xueying, Zhao, Lili, Zhu, Yongping
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container_end_page 201
container_issue
container_start_page 198
container_title Materials letters
container_volume 207
creator Hu, Jing
Chu, Ying
Tian, Qianqiu
Guo, Shengnan
Yang, Ming
Wang, Xueying
Zhao, Lili
Zhu, Yongping
description •We provide an alternative to the stainless steel substrate for NiCl2 thermal battery.•The impregnation of NiCl2 into the nickel foam was prepared by screen printing.•The peak voltage of NiCl2 cell with nickel foam substrate can reach 2.55V.•The NiCl2-based battery with nickel foam substrate has a higher specific capacity. In this study, The NiCl2 cathode with nickel foam substrate is prepared by screen printing. The NiCl2-based single cell with nickel foam substrate exhibits a 2.55V discharge voltage and a specific capacity of 684.61Asg−1 with the cut-off voltage of 1.5V. For comparison, the NiCl2 cell with stainless steel substrate also discharged, demonstrating a 2.43V discharge voltage and a specific capacity of 299.39Asg−1. These significant improvements can be attributed to the excellent impregnation of NiCl2 into the high-porosity nickel metal foam wherein the nickel metal foam acts as conductive agent and substrate. Due to their excellent electrochemical properties, the nickel foam substrate is suitable for use in high power NiCl2-based thermal batteries.
doi_str_mv 10.1016/j.matlet.2017.07.082
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In this study, The NiCl2 cathode with nickel foam substrate is prepared by screen printing. The NiCl2-based single cell with nickel foam substrate exhibits a 2.55V discharge voltage and a specific capacity of 684.61Asg−1 with the cut-off voltage of 1.5V. For comparison, the NiCl2 cell with stainless steel substrate also discharged, demonstrating a 2.43V discharge voltage and a specific capacity of 299.39Asg−1. These significant improvements can be attributed to the excellent impregnation of NiCl2 into the high-porosity nickel metal foam wherein the nickel metal foam acts as conductive agent and substrate. 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In this study, The NiCl2 cathode with nickel foam substrate is prepared by screen printing. The NiCl2-based single cell with nickel foam substrate exhibits a 2.55V discharge voltage and a specific capacity of 684.61Asg−1 with the cut-off voltage of 1.5V. For comparison, the NiCl2 cell with stainless steel substrate also discharged, demonstrating a 2.43V discharge voltage and a specific capacity of 299.39Asg−1. These significant improvements can be attributed to the excellent impregnation of NiCl2 into the high-porosity nickel metal foam wherein the nickel metal foam acts as conductive agent and substrate. 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In this study, The NiCl2 cathode with nickel foam substrate is prepared by screen printing. The NiCl2-based single cell with nickel foam substrate exhibits a 2.55V discharge voltage and a specific capacity of 684.61Asg−1 with the cut-off voltage of 1.5V. For comparison, the NiCl2 cell with stainless steel substrate also discharged, demonstrating a 2.43V discharge voltage and a specific capacity of 299.39Asg−1. These significant improvements can be attributed to the excellent impregnation of NiCl2 into the high-porosity nickel metal foam wherein the nickel metal foam acts as conductive agent and substrate. Due to their excellent electrochemical properties, the nickel foam substrate is suitable for use in high power NiCl2-based thermal batteries.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.matlet.2017.07.082</doi><tpages>4</tpages></addata></record>
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subjects Batteries
Cathodes
Discharge
Electric potential
Electrical properties
Electrochemical analysis
Materials science
Metal chlorides
Metal foams
Nickel chloride
Nickel compounds
Nickel foam
NiCl2 cathode
Porosity
Porous materials
Screen printing
Substrates
Thermal batteries
title Electrochemical properties of the NiCl2 cathode with nickel foam substrate for thermal batteries
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