Preparation and properties of solid polymer electrolyte based on imidazolium-based ionic liquids for structural capacitors
We prepared solid polymer electrolytes (SPEs) composed of poly(ethylene glycol) monomethyl ether acrylate (1A9OMe) and 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([EMIm][OTF]) and 1-ethyl-3-methylimidazolium bis(trifluoromethane sulfonyl) imide ([EMIm][TFSI]) as the ionic liquid. The SPEs...
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| Veröffentlicht in: | Fibers and polymers 2017-08, Vol.18 (8), p.1452-1458 |
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| creator | Cho, Bong-Sang Choi, Jun Kim, Ki-Young |
| description | We prepared solid polymer electrolytes (SPEs) composed of poly(ethylene glycol) monomethyl ether acrylate (1A9OMe) and 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([EMIm][OTF]) and 1-ethyl-3-methylimidazolium bis(trifluoromethane sulfonyl) imide ([EMIm][TFSI]) as the ionic liquid. The SPEs formed by appropriately adding ionic liquids in the 1A9OMe prior to thermal cure. The ratio of 1A9OMe and ionic liquid was 1:9, 3:7, and 5:5, respectively. The characterization of solid polymer electrolytes were investigated using Fourier transform infrared spectroscopy in the attenuated total reflectance mode (FTIR-ATR), Electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), and glavanostatic charge-discharge test. The highest ionic conductivity of SPEs was found to be 4.90×10
−4
S/cm in a 1A9OMe/[EMIm][OTF] of 3:7. As IL contents were increased, the specific capacitance of supercapacitor was increased. The specific capacitance of supercapacitor for ionic liquid with large ion size was lower than that for ionic liquid with smaller ion size. |
| doi_str_mv | 10.1007/s12221-017-7266-9 |
| format | Article |
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−4
S/cm in a 1A9OMe/[EMIm][OTF] of 3:7. As IL contents were increased, the specific capacitance of supercapacitor was increased. The specific capacitance of supercapacitor for ionic liquid with large ion size was lower than that for ionic liquid with smaller ion size.</description><identifier>ISSN: 1229-9197</identifier><identifier>EISSN: 1875-0052</identifier><identifier>DOI: 10.1007/s12221-017-7266-9</identifier><language>eng</language><publisher>Seoul: The Korean Fiber Society</publisher><subject>Capacitance ; Capacitors ; Chemistry ; Chemistry and Materials Science ; Electrochemical impedance spectroscopy ; Electrolytes ; Fourier transforms ; Ion currents ; Ionic liquids ; Ions ; Molten salt electrolytes ; Polyethylene glycol monomethyl ether acrylate ; Polymer Sciences ; Polymers ; Reflectance ; Solid electrolytes ; Solvents ; Spectrum analysis ; Trifluoromethane</subject><ispartof>Fibers and polymers, 2017-08, Vol.18 (8), p.1452-1458</ispartof><rights>The Korean Fiber Society and Springer Science+Business Media B.V. 2017</rights><rights>Fibers and Polymers is a copyright of Springer, 2017.</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c355t-7a2618ccb34430f451a21d5c893dc1b6cd8ebae8d582285ee589455c6314b953</citedby><cites>FETCH-LOGICAL-c355t-7a2618ccb34430f451a21d5c893dc1b6cd8ebae8d582285ee589455c6314b953</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12221-017-7266-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12221-017-7266-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Cho, Bong-Sang</creatorcontrib><creatorcontrib>Choi, Jun</creatorcontrib><creatorcontrib>Kim, Ki-Young</creatorcontrib><title>Preparation and properties of solid polymer electrolyte based on imidazolium-based ionic liquids for structural capacitors</title><title>Fibers and polymers</title><addtitle>Fibers Polym</addtitle><description>We prepared solid polymer electrolytes (SPEs) composed of poly(ethylene glycol) monomethyl ether acrylate (1A9OMe) and 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([EMIm][OTF]) and 1-ethyl-3-methylimidazolium bis(trifluoromethane sulfonyl) imide ([EMIm][TFSI]) as the ionic liquid. The SPEs formed by appropriately adding ionic liquids in the 1A9OMe prior to thermal cure. The ratio of 1A9OMe and ionic liquid was 1:9, 3:7, and 5:5, respectively. The characterization of solid polymer electrolytes were investigated using Fourier transform infrared spectroscopy in the attenuated total reflectance mode (FTIR-ATR), Electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), and glavanostatic charge-discharge test. The highest ionic conductivity of SPEs was found to be 4.90×10
−4
S/cm in a 1A9OMe/[EMIm][OTF] of 3:7. As IL contents were increased, the specific capacitance of supercapacitor was increased. The specific capacitance of supercapacitor for ionic liquid with large ion size was lower than that for ionic liquid with smaller ion size.</description><subject>Capacitance</subject><subject>Capacitors</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrolytes</subject><subject>Fourier transforms</subject><subject>Ion currents</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Molten salt electrolytes</subject><subject>Polyethylene glycol monomethyl ether acrylate</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Reflectance</subject><subject>Solid electrolytes</subject><subject>Solvents</subject><subject>Spectrum analysis</subject><subject>Trifluoromethane</subject><issn>1229-9197</issn><issn>1875-0052</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kEtPxCAUhYnRxHH0B7gjcY0CLQWWZuIrmUQXsycUqGHSlg7Qxcyvl0lduHF1Hznn3NwPgHuCHwnG_CkRSilBmHDEadMgeQFWRHCGMGb0svSUSiSJ5NfgJqU9xg2hvFqB01d0k446-zBCPVo4xTC5mL1LMHQwhd6XXeiPg4vQ9c7kWIbsYKuTs7CY_OCtPhXdPKBlWaK8gb0_zN4m2IUIU46zyXPUPTR60sbnENMtuOp0n9zdb12D3evLbvOOtp9vH5vnLTIVYxlxTRsijGmruq5wVzOiKbHMCFlZQ9rGWOFa7YRlglLBnGNC1oyZpiJ1K1m1Bg9LbPnsMLuU1T7McSwXFZEM11TyQmINyKIyMaQUXaem6Acdj4pgdSasFsKqEFZnwkoWD108qWjHbxf_JP9r-gFQA4Dv</recordid><startdate>20170801</startdate><enddate>20170801</enddate><creator>Cho, Bong-Sang</creator><creator>Choi, Jun</creator><creator>Kim, Ki-Young</creator><general>The Korean Fiber Society</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20170801</creationdate><title>Preparation and properties of solid polymer electrolyte based on imidazolium-based ionic liquids for structural capacitors</title><author>Cho, Bong-Sang ; Choi, Jun ; Kim, Ki-Young</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c355t-7a2618ccb34430f451a21d5c893dc1b6cd8ebae8d582285ee589455c6314b953</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Capacitance</topic><topic>Capacitors</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrolytes</topic><topic>Fourier transforms</topic><topic>Ion currents</topic><topic>Ionic liquids</topic><topic>Ions</topic><topic>Molten salt electrolytes</topic><topic>Polyethylene glycol monomethyl ether acrylate</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Reflectance</topic><topic>Solid electrolytes</topic><topic>Solvents</topic><topic>Spectrum analysis</topic><topic>Trifluoromethane</topic><toplevel>online_resources</toplevel><creatorcontrib>Cho, Bong-Sang</creatorcontrib><creatorcontrib>Choi, Jun</creatorcontrib><creatorcontrib>Kim, Ki-Young</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Fibers and polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cho, Bong-Sang</au><au>Choi, Jun</au><au>Kim, Ki-Young</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation and properties of solid polymer electrolyte based on imidazolium-based ionic liquids for structural capacitors</atitle><jtitle>Fibers and polymers</jtitle><stitle>Fibers Polym</stitle><date>2017-08-01</date><risdate>2017</risdate><volume>18</volume><issue>8</issue><spage>1452</spage><epage>1458</epage><pages>1452-1458</pages><issn>1229-9197</issn><eissn>1875-0052</eissn><abstract>We prepared solid polymer electrolytes (SPEs) composed of poly(ethylene glycol) monomethyl ether acrylate (1A9OMe) and 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([EMIm][OTF]) and 1-ethyl-3-methylimidazolium bis(trifluoromethane sulfonyl) imide ([EMIm][TFSI]) as the ionic liquid. The SPEs formed by appropriately adding ionic liquids in the 1A9OMe prior to thermal cure. The ratio of 1A9OMe and ionic liquid was 1:9, 3:7, and 5:5, respectively. The characterization of solid polymer electrolytes were investigated using Fourier transform infrared spectroscopy in the attenuated total reflectance mode (FTIR-ATR), Electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), and glavanostatic charge-discharge test. The highest ionic conductivity of SPEs was found to be 4.90×10
−4
S/cm in a 1A9OMe/[EMIm][OTF] of 3:7. As IL contents were increased, the specific capacitance of supercapacitor was increased. The specific capacitance of supercapacitor for ionic liquid with large ion size was lower than that for ionic liquid with smaller ion size.</abstract><cop>Seoul</cop><pub>The Korean Fiber Society</pub><doi>10.1007/s12221-017-7266-9</doi><tpages>7</tpages></addata></record> |
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| subjects | Capacitance Capacitors Chemistry Chemistry and Materials Science Electrochemical impedance spectroscopy Electrolytes Fourier transforms Ion currents Ionic liquids Ions Molten salt electrolytes Polyethylene glycol monomethyl ether acrylate Polymer Sciences Polymers Reflectance Solid electrolytes Solvents Spectrum analysis Trifluoromethane |
| title | Preparation and properties of solid polymer electrolyte based on imidazolium-based ionic liquids for structural capacitors |
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