Poly(phenylene-carborane) for boron-carbide/carbon ceramic precursor synthesized via nickel catalysis

High thermally and thermo-oxidatively stable poly(phenylene-carborane) (PPB) was synthesized via Ni(0)-catalyzed polymerization of bis(aryl chloride) monomer containing carborane. This polymer was soluble in THF and NMP at room temperature, thus allowing molecular weight and spectroscopic analysis....

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Veröffentlicht in:	Polymer (Guilford) 2017-04, Vol.115, p.224-231
Hauptverfasser:	Cheng, Shengli, Yuan, Kuanyu, Wang, Xin, Han, Jianhua, Jian, Xigao, Wang, Jinyan
Format:	Artikel
Sprache:	eng
Schlagworte:	Air temperature Aromatic compounds Boron Boron carbide Carborane Catalysis Ceramics Chemical synthesis Chloride Crystallization Magnetic resonance spectroscopy Molecular weight Ni-catalyzed polymerization Nickel Nitrogen NMR spectroscopy Poly(phenylene-carborane) Polymerization Precursors Stability analysis Temperature X-ray diffraction
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