Synthesis and Study of Organosoluble Aromatic Cardo (co)polyamides and Their Application in the Optical Fiber Primary Coating Technology
A series of organosoluble aromatic cardo copolyamides (PA) with chlorine and carboxylic side groups has been synthesised by low‐temperature polycondensation in N‐methyl‐2‐pyrrolidone (N‐MP) solution and their properties have been estimated. The obtained polymers are differed in high molar masses (ηi...
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| Veröffentlicht in: | Macromolecular symposia. 2017-10, Vol.375 (1), p.n/a |
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| creator | Sapozhnikov, Dmitriy A. Bayminov, Bato A. Popova, Nadezhda A. Zabegaeva, Olesya N. Alekseyeva, Diana D. Semjonov, Sergey L. Kosolapov, Alexey F. Plastinin, Evgeniy A. Vygodskii, Yakov S. |
| description | A series of organosoluble aromatic cardo copolyamides (PA) with chlorine and carboxylic side groups has been synthesised by low‐temperature polycondensation in N‐methyl‐2‐pyrrolidone (N‐MP) solution and their properties have been estimated. The obtained polymers are differed in high molar masses (ηinh = 0.7 ÷ 1.8 dL/g) and demonstrate the following thermal characteristics: 300 °C |
| doi_str_mv | 10.1002/masy.201700028 |
| format | Article |
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The obtained polymers are differed in high molar masses (ηinh = 0.7 ÷ 1.8 dL/g) and demonstrate the following thermal characteristics: 300 °C < Tg < 390 °C; 425 °C < T10% < 510 °C (in air). PA films are characterized by high tensile strength (100 ÷ 230 MPa) and modulus (1.6 ÷ 2.3 GPa). It was stated the obtained PAs form the high quality coatings with good adhesion to the optical fiber surface without any additional coupling agent. The fibers with elaborated PA coatings demonstrate high thermal stability. The study of the optical fiber bending strength before and after thermal tests has shown that this parameter decreases by 10% only after prolonged exposure to high temperatures, namely, 72 h at 200–300 °C. Some samples withstand more than 1 h treatment at 350 °C without any changes of the optical fiber bending strength.</description><identifier>ISSN: 1022-1360</identifier><identifier>EISSN: 1521-3900</identifier><identifier>DOI: 10.1002/masy.201700028</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Aramid fibers ; Bend strength ; cardo (co)polyamides ; Chlorine ; Coatings ; Coupling agents ; high‐performance optical fiber coating ; Mechanical properties ; N-Methyl-2-pyrrolidone ; Optical fibers ; Polyamide resins ; Polyamides ; Polymers ; Reagents ; Thermal stability</subject><ispartof>Macromolecular symposia., 2017-10, Vol.375 (1), p.n/a</ispartof><rights>2017 WILEY-VCH Verlag GmbH & Co. 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The obtained polymers are differed in high molar masses (ηinh = 0.7 ÷ 1.8 dL/g) and demonstrate the following thermal characteristics: 300 °C < Tg < 390 °C; 425 °C < T10% < 510 °C (in air). PA films are characterized by high tensile strength (100 ÷ 230 MPa) and modulus (1.6 ÷ 2.3 GPa). It was stated the obtained PAs form the high quality coatings with good adhesion to the optical fiber surface without any additional coupling agent. The fibers with elaborated PA coatings demonstrate high thermal stability. The study of the optical fiber bending strength before and after thermal tests has shown that this parameter decreases by 10% only after prolonged exposure to high temperatures, namely, 72 h at 200–300 °C. Some samples withstand more than 1 h treatment at 350 °C without any changes of the optical fiber bending strength.</description><subject>Aramid fibers</subject><subject>Bend strength</subject><subject>cardo (co)polyamides</subject><subject>Chlorine</subject><subject>Coatings</subject><subject>Coupling agents</subject><subject>high‐performance optical fiber coating</subject><subject>Mechanical properties</subject><subject>N-Methyl-2-pyrrolidone</subject><subject>Optical fibers</subject><subject>Polyamide resins</subject><subject>Polyamides</subject><subject>Polymers</subject><subject>Reagents</subject><subject>Thermal stability</subject><issn>1022-1360</issn><issn>1521-3900</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LxDAQhoMouK5ePQe86KFrPvqxOZbiqqCssL14CmmT7mZJm5p0kf4Df7ZZKnr0NDPwPDPDC8A1RguMELlvhR8XBOEMhWl5AmY4ITiiDKHT0CNCIkxTdA4uvN8HhLEMz8DXZuyGnfLaQ9FJuBkOcoS2gWu3FZ311hwqo2DubCsGXcNCOGnhbW3vemtG0WqpJrHcKe1g3vdG14G0HdQdDIvhug-eMHClK-Xgm9OtcCMsbIC6LSxVveussdvxEpw1wnh19VPnoFw9lMVT9LJ-fC7yl6imOFtGTFaZlFWDBE0qxBKsUpGmsRSionXKmiyJ4wpRQhIsUUozpIhSWFHMaJxSSufgZlrbO_txUH7ge3twXbjIMYuzBMUhmUAtJqp21nunGt5Pj3OM-DFsfgyb_4YdBDYJn9qo8R-av-ab9z_3GyduhL4</recordid><startdate>201710</startdate><enddate>201710</enddate><creator>Sapozhnikov, Dmitriy A.</creator><creator>Bayminov, Bato A.</creator><creator>Popova, Nadezhda A.</creator><creator>Zabegaeva, Olesya N.</creator><creator>Alekseyeva, Diana D.</creator><creator>Semjonov, Sergey L.</creator><creator>Kosolapov, Alexey F.</creator><creator>Plastinin, Evgeniy A.</creator><creator>Vygodskii, Yakov S.</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>201710</creationdate><title>Synthesis and Study of Organosoluble Aromatic Cardo (co)polyamides and Their Application in the Optical Fiber Primary Coating Technology</title><author>Sapozhnikov, Dmitriy A. ; Bayminov, Bato A. ; Popova, Nadezhda A. ; Zabegaeva, Olesya N. ; Alekseyeva, Diana D. ; Semjonov, Sergey L. ; Kosolapov, Alexey F. ; Plastinin, Evgeniy A. ; Vygodskii, Yakov S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3178-9db7ddbf0a35b0951e6a664daab3c69f7544b032251d06370e2ee1e319346333</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Aramid fibers</topic><topic>Bend strength</topic><topic>cardo (co)polyamides</topic><topic>Chlorine</topic><topic>Coatings</topic><topic>Coupling agents</topic><topic>high‐performance optical fiber coating</topic><topic>Mechanical properties</topic><topic>N-Methyl-2-pyrrolidone</topic><topic>Optical fibers</topic><topic>Polyamide resins</topic><topic>Polyamides</topic><topic>Polymers</topic><topic>Reagents</topic><topic>Thermal stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sapozhnikov, Dmitriy A.</creatorcontrib><creatorcontrib>Bayminov, Bato A.</creatorcontrib><creatorcontrib>Popova, Nadezhda A.</creatorcontrib><creatorcontrib>Zabegaeva, Olesya N.</creatorcontrib><creatorcontrib>Alekseyeva, Diana D.</creatorcontrib><creatorcontrib>Semjonov, Sergey L.</creatorcontrib><creatorcontrib>Kosolapov, Alexey F.</creatorcontrib><creatorcontrib>Plastinin, Evgeniy A.</creatorcontrib><creatorcontrib>Vygodskii, Yakov S.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Macromolecular symposia.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sapozhnikov, Dmitriy A.</au><au>Bayminov, Bato A.</au><au>Popova, Nadezhda A.</au><au>Zabegaeva, Olesya N.</au><au>Alekseyeva, Diana D.</au><au>Semjonov, Sergey L.</au><au>Kosolapov, Alexey F.</au><au>Plastinin, Evgeniy A.</au><au>Vygodskii, Yakov S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Study of Organosoluble Aromatic Cardo (co)polyamides and Their Application in the Optical Fiber Primary Coating Technology</atitle><jtitle>Macromolecular symposia.</jtitle><date>2017-10</date><risdate>2017</risdate><volume>375</volume><issue>1</issue><epage>n/a</epage><issn>1022-1360</issn><eissn>1521-3900</eissn><abstract>A series of organosoluble aromatic cardo copolyamides (PA) with chlorine and carboxylic side groups has been synthesised by low‐temperature polycondensation in N‐methyl‐2‐pyrrolidone (N‐MP) solution and their properties have been estimated. The obtained polymers are differed in high molar masses (ηinh = 0.7 ÷ 1.8 dL/g) and demonstrate the following thermal characteristics: 300 °C < Tg < 390 °C; 425 °C < T10% < 510 °C (in air). PA films are characterized by high tensile strength (100 ÷ 230 MPa) and modulus (1.6 ÷ 2.3 GPa). It was stated the obtained PAs form the high quality coatings with good adhesion to the optical fiber surface without any additional coupling agent. The fibers with elaborated PA coatings demonstrate high thermal stability. The study of the optical fiber bending strength before and after thermal tests has shown that this parameter decreases by 10% only after prolonged exposure to high temperatures, namely, 72 h at 200–300 °C. Some samples withstand more than 1 h treatment at 350 °C without any changes of the optical fiber bending strength.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/masy.201700028</doi><tpages>6</tpages></addata></record> |
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| subjects | Aramid fibers Bend strength cardo (co)polyamides Chlorine Coatings Coupling agents high‐performance optical fiber coating Mechanical properties N-Methyl-2-pyrrolidone Optical fibers Polyamide resins Polyamides Polymers Reagents Thermal stability |
| title | Synthesis and Study of Organosoluble Aromatic Cardo (co)polyamides and Their Application in the Optical Fiber Primary Coating Technology |
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