Synthesis of highly transparent poly(amide–imide)s based on trimellitic acid and dependence of thermal properties on monomer sequence

Transparent, thermally stable, and semiaromatic poly(amide–imide)s were prepared from hydrogenated trimellitic anhydride chloride (h-TAC) with various aromatic diamines. The dependence of thermostability on the monomer sequence and terminal group was investigated. Thermogravimetric/differential ther...

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Veröffentlicht in:Reactive & functional polymers 2016-11, Vol.108, p.78-85
Hauptverfasser: Kobayashi, Yutaro, Fujiwara, Yumi, Kitaoka, Takuya, Oishi, Yoshiyuki, Shibasaki, Yuji
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container_issue
container_start_page 78
container_title Reactive & functional polymers
container_volume 108
creator Kobayashi, Yutaro
Fujiwara, Yumi
Kitaoka, Takuya
Oishi, Yoshiyuki
Shibasaki, Yuji
description Transparent, thermally stable, and semiaromatic poly(amide–imide)s were prepared from hydrogenated trimellitic anhydride chloride (h-TAC) with various aromatic diamines. The dependence of thermostability on the monomer sequence and terminal group was investigated. Thermogravimetric/differential thermal analysis (TG/DTA) was performed to evaluate the thermostabilities, which were found to be primarily affected by the monomer sequence in the polymer units. The 5% weight loss temperature (Td5) in N2, glass transition temperature (Tg), and cutoff wavelength of the ultraviolet–visible (UV–Vis) spectrum (λcut) of the semiaromatic poly(amide–imide)s are 422–456°C, 131–274°C, and 293–321nm, respectively, while those of wholly aromatic poly(amide–imide)s are 454–480°C, 169–287°C, and 415nm, respectively.
doi_str_mv 10.1016/j.reactfunctpolym.2016.04.016
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subjects Alicyclic structure
Diamines
Differential thermogravimetric analysis
Glass transition temperature
Poly(amide–imide)
Polyamines
Polymers
Thermal analysis
Thermal stability
Thermodynamic properties
Thermogravimetric analysis
Thermostability
Transparent polymer
title Synthesis of highly transparent poly(amide–imide)s based on trimellitic acid and dependence of thermal properties on monomer sequence
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