Synthesis of preceramic organomagnesiumoxanealumoxanes

Preceramic organomagnesiumoxanealumoxanes hydrolytically stable in air and soluble in organic solvents, exhibiting fiber-forming properties at Al: Mg molar ratios of 2: 1 and 1: 1, have been synthesized for the first time. The physicochemical properties of the organomagnesiumoxanealumoxanes and cera...

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Veröffentlicht in:Inorganic materials 2017-11, Vol.53 (11), p.1209-1216
Hauptverfasser: Shcherbakova, G. I., Storozhenko, P. A., Krivtsova, N. S., Kutinova, N. B., Apukhtina, T. L., Varfolomeev, M. S., Kuznetsova, M. G., Drachev, A. I., Stolyarova, I. V., Ashmarin, A. A.
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Sprache:eng
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Zusammenfassung:Preceramic organomagnesiumoxanealumoxanes hydrolytically stable in air and soluble in organic solvents, exhibiting fiber-forming properties at Al: Mg molar ratios of 2: 1 and 1: 1, have been synthesized for the first time. The physicochemical properties of the organomagnesiumoxanealumoxanes and ceramic samples prepared from them have been studied by a variety of techniques (nuclear magnetic resonance, IR spectroscopy, scanning electron microscopy, thermogravimetric analysis, X-ray diffraction, and elemental analysis).
ISSN:0020-1685
1608-3172
DOI:10.1134/S0020168517110103