Effect of coordination of lead(II) nitrilo-tris-methylenephosphonate complexes on their thermal behavior in the compact state and in the chemisorbed layers on steel surface according to thermogravimetry and X-ray photoelectron spectroscopy in situ

The thermal decomposition of two lead(II) complexes with the same ligand, nitrilo-tris-methy-lenephosphonic acid N(CH 2 PO 3 ) 3 H 6 , but with different coordination modes, in the compact state and as chemisorbed layers on a steel surface, was studied by TGA and X-ray photoelectron spectroscopy. Us...

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Veröffentlicht in:Russian journal of coordination chemistry 2017-09, Vol.43 (9), p.583-590
Hauptverfasser: Somov, N. V., Chausov, F. F., Lomova, N. V., Shabanova, I. N., Petrov, V. G., Zhirov, D. K.
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container_end_page 590
container_issue 9
container_start_page 583
container_title Russian journal of coordination chemistry
container_volume 43
creator Somov, N. V.
Chausov, F. F.
Lomova, N. V.
Shabanova, I. N.
Petrov, V. G.
Zhirov, D. K.
description The thermal decomposition of two lead(II) complexes with the same ligand, nitrilo-tris-methy-lenephosphonic acid N(CH 2 PO 3 ) 3 H 6 , but with different coordination modes, in the compact state and as chemisorbed layers on a steel surface, was studied by TGA and X-ray photoelectron spectroscopy. Using these methods, the thermal decomposition was conducted in the spectrometer chamber with simultaneous recording of the electronic spectra in situ. The differences in the thermochemical behavior of lead(II) complexes were elucidated.
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subjects Chemistry
Chemistry and Materials Science
Coordination compounds
Electronic spectra
Inorganic Chemistry
Photoelectron spectroscopy
Physical Chemistry
Spectrum analysis
Thermal decomposition
Thermodynamic properties
Thermogravimetry
X ray photoelectron spectroscopy
X-rays
title Effect of coordination of lead(II) nitrilo-tris-methylenephosphonate complexes on their thermal behavior in the compact state and in the chemisorbed layers on steel surface according to thermogravimetry and X-ray photoelectron spectroscopy in situ
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