New difluorenylaminocoumarin photosensitizers for dye-sensitized solar cells
Three difluorenylaminocoumarin sensitizers with different π-bridges bearing thiophene ring and cyanoacrylic acid acceptor were synthesized and their photophysical properties and photoelectric conversion efficiency were investigated and compared with counterpart dyes with diphenylaminocoumarin donor....
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| Veröffentlicht in: | Research on chemical intermediates 2017-10, Vol.43 (10), p.5779-5794 |
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| container_title | Research on chemical intermediates |
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| creator | Han, Liang He, Ji Zhao, Jin’ge Jiang, Shaoliang |
| description | Three difluorenylaminocoumarin sensitizers with different π-bridges bearing thiophene ring and cyanoacrylic acid acceptor were synthesized and their photophysical properties and photoelectric conversion efficiency were investigated and compared with counterpart dyes with diphenylaminocoumarin donor. Replacement of benzene with fluorene in the donor unit contributed to superior photovoltaic performance. Among the three π-bridges, the thiophene-phenyl π-bridge improved
V
OC
and
J
SC
, resulting in a DSSC with the best photoelectric conversion efficiency (
η
= 5.94%,
V
OC
= 670 mV,
J
SC
= 14.53 mA cm
−2
, and fill factor, FF = 0.61). |
| doi_str_mv | 10.1007/s11164-017-2962-z |
| format | Article |
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V
OC
and
J
SC
, resulting in a DSSC with the best photoelectric conversion efficiency (
η
= 5.94%,
V
OC
= 670 mV,
J
SC
= 14.53 mA cm
−2
, and fill factor, FF = 0.61).</description><identifier>ISSN: 0922-6168</identifier><identifier>EISSN: 1568-5675</identifier><identifier>DOI: 10.1007/s11164-017-2962-z</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Benzene ; Catalysis ; Chemistry ; Chemistry and Materials Science ; Dye-sensitized solar cells ; Dyes ; Energy conversion efficiency ; Inorganic Chemistry ; Photoelectricity ; Photovoltaic cells ; Physical Chemistry</subject><ispartof>Research on chemical intermediates, 2017-10, Vol.43 (10), p.5779-5794</ispartof><rights>Springer Science+Business Media Dordrecht 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-2333c7cd7cfcf69e899117478b5a572a10161caa8e53c87cb1c60e1663e95c813</citedby><cites>FETCH-LOGICAL-c316t-2333c7cd7cfcf69e899117478b5a572a10161caa8e53c87cb1c60e1663e95c813</cites><orcidid>0000-0001-6213-4432</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11164-017-2962-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11164-017-2962-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Han, Liang</creatorcontrib><creatorcontrib>He, Ji</creatorcontrib><creatorcontrib>Zhao, Jin’ge</creatorcontrib><creatorcontrib>Jiang, Shaoliang</creatorcontrib><title>New difluorenylaminocoumarin photosensitizers for dye-sensitized solar cells</title><title>Research on chemical intermediates</title><addtitle>Res Chem Intermed</addtitle><description>Three difluorenylaminocoumarin sensitizers with different π-bridges bearing thiophene ring and cyanoacrylic acid acceptor were synthesized and their photophysical properties and photoelectric conversion efficiency were investigated and compared with counterpart dyes with diphenylaminocoumarin donor. Replacement of benzene with fluorene in the donor unit contributed to superior photovoltaic performance. Among the three π-bridges, the thiophene-phenyl π-bridge improved
V
OC
and
J
SC
, resulting in a DSSC with the best photoelectric conversion efficiency (
η
= 5.94%,
V
OC
= 670 mV,
J
SC
= 14.53 mA cm
−2
, and fill factor, FF = 0.61).</description><subject>Benzene</subject><subject>Catalysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dye-sensitized solar cells</subject><subject>Dyes</subject><subject>Energy conversion efficiency</subject><subject>Inorganic Chemistry</subject><subject>Photoelectricity</subject><subject>Photovoltaic cells</subject><subject>Physical Chemistry</subject><issn>0922-6168</issn><issn>1568-5675</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LxDAQhoMouK7-AG8Fz9FMsvk6yuIXLHrRc8imU-3SbdakRbq_3i4V8eJpYHifd5iHkEtg18CYvskAoBaUgabcKk73R2QGUhkqlZbHZMYs51SBMqfkLOcNYyCNYTOyesavoqyrpo8J26Hx27qNIfZbn-q22H3ELmZsc93Ve0y5qGIqygHp764scmx8KgI2TT4nJ5VvMl78zDl5u797XT7S1cvD0_J2RYMA1VEuhAg6lDpUoVIWjbUAeqHNWnqpuQcGCoL3BqUIRoc1BMUQlBJoZTAg5uRq6t2l-Nlj7twm9qkdTzqwwoBhWokxBVMqpJhzwsrtUj3-NThg7iDNTdLcKM0dpLn9yPCJyWO2fcf0p_lf6Bv8CHEE</recordid><startdate>20171001</startdate><enddate>20171001</enddate><creator>Han, Liang</creator><creator>He, Ji</creator><creator>Zhao, Jin’ge</creator><creator>Jiang, Shaoliang</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-6213-4432</orcidid></search><sort><creationdate>20171001</creationdate><title>New difluorenylaminocoumarin photosensitizers for dye-sensitized solar cells</title><author>Han, Liang ; He, Ji ; Zhao, Jin’ge ; Jiang, Shaoliang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-2333c7cd7cfcf69e899117478b5a572a10161caa8e53c87cb1c60e1663e95c813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Benzene</topic><topic>Catalysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dye-sensitized solar cells</topic><topic>Dyes</topic><topic>Energy conversion efficiency</topic><topic>Inorganic Chemistry</topic><topic>Photoelectricity</topic><topic>Photovoltaic cells</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Han, Liang</creatorcontrib><creatorcontrib>He, Ji</creatorcontrib><creatorcontrib>Zhao, Jin’ge</creatorcontrib><creatorcontrib>Jiang, Shaoliang</creatorcontrib><collection>CrossRef</collection><jtitle>Research on chemical intermediates</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Han, Liang</au><au>He, Ji</au><au>Zhao, Jin’ge</au><au>Jiang, Shaoliang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New difluorenylaminocoumarin photosensitizers for dye-sensitized solar cells</atitle><jtitle>Research on chemical intermediates</jtitle><stitle>Res Chem Intermed</stitle><date>2017-10-01</date><risdate>2017</risdate><volume>43</volume><issue>10</issue><spage>5779</spage><epage>5794</epage><pages>5779-5794</pages><issn>0922-6168</issn><eissn>1568-5675</eissn><abstract>Three difluorenylaminocoumarin sensitizers with different π-bridges bearing thiophene ring and cyanoacrylic acid acceptor were synthesized and their photophysical properties and photoelectric conversion efficiency were investigated and compared with counterpart dyes with diphenylaminocoumarin donor. Replacement of benzene with fluorene in the donor unit contributed to superior photovoltaic performance. Among the three π-bridges, the thiophene-phenyl π-bridge improved
V
OC
and
J
SC
, resulting in a DSSC with the best photoelectric conversion efficiency (
η
= 5.94%,
V
OC
= 670 mV,
J
SC
= 14.53 mA cm
−2
, and fill factor, FF = 0.61).</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s11164-017-2962-z</doi><tpages>16</tpages><orcidid>https://orcid.org/0000-0001-6213-4432</orcidid></addata></record> |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Benzene Catalysis Chemistry Chemistry and Materials Science Dye-sensitized solar cells Dyes Energy conversion efficiency Inorganic Chemistry Photoelectricity Photovoltaic cells Physical Chemistry |
| title | New difluorenylaminocoumarin photosensitizers for dye-sensitized solar cells |
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