Synthesis of multifunctional monomers from rosin for the properties enhancement of soybean-oil based thermosets
Two kinds of rosin derivatives, （2-hydroxy-3-（methacryloyloxy）propyl 7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,4b,5,6,10,10a- decahydrophenanthrene-1-carboxylate） （HMPIDDC） and （（（7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenan- thren-1-yl）methyl）azanediyl）bis（2-hydroxypropane-3,1-diyl）bis（...
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| Veröffentlicht in: | Science China. Technological sciences 2017-09, Vol.60 (9), p.1332-1338 |
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| creator | Liu, Yuan Li, Chao Dai, JinYue Jiang, YanHua Liu, XiaoQing Zhu, Jin |
| description | Two kinds of rosin derivatives, （2-hydroxy-3-（methacryloyloxy）propyl 7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,4b,5,6,10,10a- decahydrophenanthrene-1-carboxylate） （HMPIDDC） and （（（7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenan- thren-1-yl）methyl）azanediyl）bis（2-hydroxypropane-3,1-diyl）bis（2-methylacrylate） （IDOMAHM） were synthesized under mild and easy to implement conditions. The two derivatives were employed as the rigid monomers to copolymerize with acrylated epoxidized soybean oil （AESO）, as so to improve the performance of the cured resins. The chemical structures of HMPIDDC and IDOMAHM were confirmed by nuclear magnetic resonance （NMR） and Fourier Transform Infrared （FT-IR） before copolymerization. The curing behaviors of pristine AESO, AESO/HMPIDDC blend, and AESO/IDOMAHM blend were monitored by differential scanning calorimetry （DSC）. Moreover, the thermal and mechanical properties of the cured resins were evaluated by universal mechanical testing, dynamic mechanical analysis （DMA） and thermogravimetric analysis （TGA）. The results demonstrated that after the introduction of HMPIDDC and IDOMAHM, the glass transition temperature and mechanical properties of the copolymerized resin were significantly increased. In one word, HMPIDDC and IDOMAHM showed dramatic potential to be used as bio-based compounds to improve the properties of soybean-oil based thermosets. |
| doi_str_mv | 10.1007/s11431-016-0777-5 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1936254750</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><cqvip_id>673125781</cqvip_id><sourcerecordid>1936254750</sourcerecordid><originalsourceid>FETCH-LOGICAL-c380t-3e3cbdd9de15ee89d365d30c35bd00c089344f99f6583c491c304fea2e190053</originalsourceid><addsrcrecordid>eNp9UD1v2zAQFYoEqJH6B2Qj2pnpnSiK4lgY_QICdGh2QqaOtgyLtHny4H9fCg6KTLnlbngf915VPSI8IYD5yoiNQgnYSjDGSP2hWmHXWokW4K7crWmkUTV-rNbMByijOgvYrKr09xrnPfHIIgUxXY7zGC7Rz2OK_VFMKaaJMouQ0yRy4jGKkLIoDHHK6UR5HokFxX0fPU0U50WF03VLfZRpPIptzzQs-Dwlppk_VfehPzKtX_dD9fLj-8vml3z-8_P35tuz9KqDWSpSfjsMdiDURJ0dVKsHBV7p7QDgobOqaYK1odWd8o1Fr6AJ1Ne0RNbqofpyky1fni_EszukSy6R2KFVba0bo6Gg8IbyJRpnCu6Ux6nPV4fglmbdrVlXmnVLs25Rrm8cLti4o_xG-R3S51ejfYq7c-H9d2qNwlqbDtU_DICIxw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1936254750</pqid></control><display><type>article</type><title>Synthesis of multifunctional monomers from rosin for the properties enhancement of soybean-oil based thermosets</title><source>Springer Nature - Complete Springer Journals</source><source>Alma/SFX Local Collection</source><creator>Liu, Yuan ; Li, Chao ; Dai, JinYue ; Jiang, YanHua ; Liu, XiaoQing ; Zhu, Jin</creator><creatorcontrib>Liu, Yuan ; Li, Chao ; Dai, JinYue ; Jiang, YanHua ; Liu, XiaoQing ; Zhu, Jin</creatorcontrib><description>Two kinds of rosin derivatives, （2-hydroxy-3-（methacryloyloxy）propyl 7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,4b,5,6,10,10a- decahydrophenanthrene-1-carboxylate） （HMPIDDC） and （（（7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenan- thren-1-yl）methyl）azanediyl）bis（2-hydroxypropane-3,1-diyl）bis（2-methylacrylate） （IDOMAHM） were synthesized under mild and easy to implement conditions. The two derivatives were employed as the rigid monomers to copolymerize with acrylated epoxidized soybean oil （AESO）, as so to improve the performance of the cured resins. The chemical structures of HMPIDDC and IDOMAHM were confirmed by nuclear magnetic resonance （NMR） and Fourier Transform Infrared （FT-IR） before copolymerization. The curing behaviors of pristine AESO, AESO/HMPIDDC blend, and AESO/IDOMAHM blend were monitored by differential scanning calorimetry （DSC）. Moreover, the thermal and mechanical properties of the cured resins were evaluated by universal mechanical testing, dynamic mechanical analysis （DMA） and thermogravimetric analysis （TGA）. The results demonstrated that after the introduction of HMPIDDC and IDOMAHM, the glass transition temperature and mechanical properties of the copolymerized resin were significantly increased. In one word, HMPIDDC and IDOMAHM showed dramatic potential to be used as bio-based compounds to improve the properties of soybean-oil based thermosets.</description><identifier>ISSN: 1674-7321</identifier><identifier>EISSN: 1869-1900</identifier><identifier>DOI: 10.1007/s11431-016-0777-5</identifier><language>eng</language><publisher>Beijing: Science China Press</publisher><subject>Copolymerization ; Derivatives ; Dynamic mechanical analysis ; Engineering ; Fourier transforms ; Glass transition temperature ; Heat measurement ; Mechanical properties ; Mechanical tests ; Monomers ; NMR ; Nuclear magnetic resonance ; Performance enhancement ; Polymers ; Resins ; Rosin ; Soybean oil ; Soybeans ; Thermodynamic properties ; Thermogravimetric analysis ; 单体合成 ; 多功能 ; 大豆油 ; 差示扫描量热法 ; 性能增强 ; 松香衍生物 ; 热固性 ; 环氧豆油丙烯酸酯</subject><ispartof>Science China. Technological sciences, 2017-09, Vol.60 (9), p.1332-1338</ispartof><rights>Science China Press and Springer-Verlag Berlin Heidelberg 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c380t-3e3cbdd9de15ee89d365d30c35bd00c089344f99f6583c491c304fea2e190053</citedby><cites>FETCH-LOGICAL-c380t-3e3cbdd9de15ee89d365d30c35bd00c089344f99f6583c491c304fea2e190053</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/60110X/60110X.jpg</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11431-016-0777-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11431-016-0777-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27907,27908,41471,42540,51302</link.rule.ids></links><search><creatorcontrib>Liu, Yuan</creatorcontrib><creatorcontrib>Li, Chao</creatorcontrib><creatorcontrib>Dai, JinYue</creatorcontrib><creatorcontrib>Jiang, YanHua</creatorcontrib><creatorcontrib>Liu, XiaoQing</creatorcontrib><creatorcontrib>Zhu, Jin</creatorcontrib><title>Synthesis of multifunctional monomers from rosin for the properties enhancement of soybean-oil based thermosets</title><title>Science China. Technological sciences</title><addtitle>Sci. China Technol. Sci</addtitle><addtitle>SCIENCE CHINA Technological Sciences</addtitle><description>Two kinds of rosin derivatives, （2-hydroxy-3-（methacryloyloxy）propyl 7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,4b,5,6,10,10a- decahydrophenanthrene-1-carboxylate） （HMPIDDC） and （（（7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenan- thren-1-yl）methyl）azanediyl）bis（2-hydroxypropane-3,1-diyl）bis（2-methylacrylate） （IDOMAHM） were synthesized under mild and easy to implement conditions. The two derivatives were employed as the rigid monomers to copolymerize with acrylated epoxidized soybean oil （AESO）, as so to improve the performance of the cured resins. The chemical structures of HMPIDDC and IDOMAHM were confirmed by nuclear magnetic resonance （NMR） and Fourier Transform Infrared （FT-IR） before copolymerization. The curing behaviors of pristine AESO, AESO/HMPIDDC blend, and AESO/IDOMAHM blend were monitored by differential scanning calorimetry （DSC）. Moreover, the thermal and mechanical properties of the cured resins were evaluated by universal mechanical testing, dynamic mechanical analysis （DMA） and thermogravimetric analysis （TGA）. The results demonstrated that after the introduction of HMPIDDC and IDOMAHM, the glass transition temperature and mechanical properties of the copolymerized resin were significantly increased. In one word, HMPIDDC and IDOMAHM showed dramatic potential to be used as bio-based compounds to improve the properties of soybean-oil based thermosets.</description><subject>Copolymerization</subject><subject>Derivatives</subject><subject>Dynamic mechanical analysis</subject><subject>Engineering</subject><subject>Fourier transforms</subject><subject>Glass transition temperature</subject><subject>Heat measurement</subject><subject>Mechanical properties</subject><subject>Mechanical tests</subject><subject>Monomers</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Performance enhancement</subject><subject>Polymers</subject><subject>Resins</subject><subject>Rosin</subject><subject>Soybean oil</subject><subject>Soybeans</subject><subject>Thermodynamic properties</subject><subject>Thermogravimetric analysis</subject><subject>单体合成</subject><subject>多功能</subject><subject>大豆油</subject><subject>差示扫描量热法</subject><subject>性能增强</subject><subject>松香衍生物</subject><subject>热固性</subject><subject>环氧豆油丙烯酸酯</subject><issn>1674-7321</issn><issn>1869-1900</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp9UD1v2zAQFYoEqJH6B2Qj2pnpnSiK4lgY_QICdGh2QqaOtgyLtHny4H9fCg6KTLnlbngf915VPSI8IYD5yoiNQgnYSjDGSP2hWmHXWokW4K7crWmkUTV-rNbMByijOgvYrKr09xrnPfHIIgUxXY7zGC7Rz2OK_VFMKaaJMouQ0yRy4jGKkLIoDHHK6UR5HokFxX0fPU0U50WF03VLfZRpPIptzzQs-Dwlppk_VfehPzKtX_dD9fLj-8vml3z-8_P35tuz9KqDWSpSfjsMdiDURJ0dVKsHBV7p7QDgobOqaYK1odWd8o1Fr6AJ1Ne0RNbqofpyky1fni_EszukSy6R2KFVba0bo6Gg8IbyJRpnCu6Ux6nPV4fglmbdrVlXmnVLs25Rrm8cLti4o_xG-R3S51ejfYq7c-H9d2qNwlqbDtU_DICIxw</recordid><startdate>20170901</startdate><enddate>20170901</enddate><creator>Liu, Yuan</creator><creator>Li, Chao</creator><creator>Dai, JinYue</creator><creator>Jiang, YanHua</creator><creator>Liu, XiaoQing</creator><creator>Zhu, Jin</creator><general>Science China Press</general><general>Springer Nature B.V</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>W92</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20170901</creationdate><title>Synthesis of multifunctional monomers from rosin for the properties enhancement of soybean-oil based thermosets</title><author>Liu, Yuan ; Li, Chao ; Dai, JinYue ; Jiang, YanHua ; Liu, XiaoQing ; Zhu, Jin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c380t-3e3cbdd9de15ee89d365d30c35bd00c089344f99f6583c491c304fea2e190053</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Copolymerization</topic><topic>Derivatives</topic><topic>Dynamic mechanical analysis</topic><topic>Engineering</topic><topic>Fourier transforms</topic><topic>Glass transition temperature</topic><topic>Heat measurement</topic><topic>Mechanical properties</topic><topic>Mechanical tests</topic><topic>Monomers</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Performance enhancement</topic><topic>Polymers</topic><topic>Resins</topic><topic>Rosin</topic><topic>Soybean oil</topic><topic>Soybeans</topic><topic>Thermodynamic properties</topic><topic>Thermogravimetric analysis</topic><topic>单体合成</topic><topic>多功能</topic><topic>大豆油</topic><topic>差示扫描量热法</topic><topic>性能增强</topic><topic>松香衍生物</topic><topic>热固性</topic><topic>环氧豆油丙烯酸酯</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Yuan</creatorcontrib><creatorcontrib>Li, Chao</creatorcontrib><creatorcontrib>Dai, JinYue</creatorcontrib><creatorcontrib>Jiang, YanHua</creatorcontrib><creatorcontrib>Liu, XiaoQing</creatorcontrib><creatorcontrib>Zhu, Jin</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库-工程技术</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>CrossRef</collection><jtitle>Science China. Technological sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Yuan</au><au>Li, Chao</au><au>Dai, JinYue</au><au>Jiang, YanHua</au><au>Liu, XiaoQing</au><au>Zhu, Jin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of multifunctional monomers from rosin for the properties enhancement of soybean-oil based thermosets</atitle><jtitle>Science China. Technological sciences</jtitle><stitle>Sci. China Technol. Sci</stitle><addtitle>SCIENCE CHINA Technological Sciences</addtitle><date>2017-09-01</date><risdate>2017</risdate><volume>60</volume><issue>9</issue><spage>1332</spage><epage>1338</epage><pages>1332-1338</pages><issn>1674-7321</issn><eissn>1869-1900</eissn><abstract>Two kinds of rosin derivatives, （2-hydroxy-3-（methacryloyloxy）propyl 7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,4b,5,6,10,10a- decahydrophenanthrene-1-carboxylate） （HMPIDDC） and （（（7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenan- thren-1-yl）methyl）azanediyl）bis（2-hydroxypropane-3,1-diyl）bis（2-methylacrylate） （IDOMAHM） were synthesized under mild and easy to implement conditions. The two derivatives were employed as the rigid monomers to copolymerize with acrylated epoxidized soybean oil （AESO）, as so to improve the performance of the cured resins. The chemical structures of HMPIDDC and IDOMAHM were confirmed by nuclear magnetic resonance （NMR） and Fourier Transform Infrared （FT-IR） before copolymerization. The curing behaviors of pristine AESO, AESO/HMPIDDC blend, and AESO/IDOMAHM blend were monitored by differential scanning calorimetry （DSC）. Moreover, the thermal and mechanical properties of the cured resins were evaluated by universal mechanical testing, dynamic mechanical analysis （DMA） and thermogravimetric analysis （TGA）. The results demonstrated that after the introduction of HMPIDDC and IDOMAHM, the glass transition temperature and mechanical properties of the copolymerized resin were significantly increased. In one word, HMPIDDC and IDOMAHM showed dramatic potential to be used as bio-based compounds to improve the properties of soybean-oil based thermosets.</abstract><cop>Beijing</cop><pub>Science China Press</pub><doi>10.1007/s11431-016-0777-5</doi><tpages>7</tpages></addata></record> |
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| subjects | Copolymerization Derivatives Dynamic mechanical analysis Engineering Fourier transforms Glass transition temperature Heat measurement Mechanical properties Mechanical tests Monomers NMR Nuclear magnetic resonance Performance enhancement Polymers Resins Rosin Soybean oil Soybeans Thermodynamic properties Thermogravimetric analysis 单体合成 多功能 大豆油 差示扫描量热法 性能增强 松香衍生物 热固性 环氧豆油丙烯酸酯 |
| title | Synthesis of multifunctional monomers from rosin for the properties enhancement of soybean-oil based thermosets |
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