Combined mechanochemical/thermal synthesis of microcrystalline pyroxene LiFeSi2O6 and one-step mechanosynthesis of nanoglassy LiFeSi2O6−based composite
Both, microcrystalline LiFeSi2O6 pyroxene and nanoglassy LiFeSi2O6−based composite are prepared via non-conventional mechanochemical/thermal processing and one-step mechanosynthesis, respectively. The structural state of the as-prepared materials on the long-range and local atomic scales is characte...
Gespeichert in:
| Veröffentlicht in: | Journal of alloys and compounds 2017-06, Vol.707, p.310-314 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 314 |
|---|---|
| container_issue | |
| container_start_page | 310 |
| container_title | Journal of alloys and compounds |
| container_volume | 707 |
| creator | Turianicová, Erika Witte, Ralf Da Silva, Klebson L. Zorkovská, Anna Senna, Mamoru Hahn, Horst Heitjans, Paul Šepelák, Vladimír |
| description | Both, microcrystalline LiFeSi2O6 pyroxene and nanoglassy LiFeSi2O6−based composite are prepared via non-conventional mechanochemical/thermal processing and one-step mechanosynthesis, respectively. The structural state of the as-prepared materials on the long-range and local atomic scales is characterized by XRD and 57Fe Mössbauer spectroscopy, respectively. The derived hyperfine interaction parameters indicate that the nanoglassy nature of the mechanosynthesized LiFeSi2O6−based composite is characterized, on the short-range scale, by a broadly distorted geometry of the constituent structural units, and on the long-range scale, by the raptured chains of the edge-sharing FeO6 octahedra and of the corner-sharing SiO4 tetrahedra.
[Display omitted]
•Preparation of microcrystalline and nanoglassy LiFeSi2O6 pyroxene.•Non-conventional mechanochemical/thermal processing and one-step mechanosynthesis.•Characterization on a local atomic scale via nuclear 57Fe Mössbauer spectroscopy. |
| doi_str_mv | 10.1016/j.jallcom.2016.11.172 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1935797803</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0925838816336520</els_id><sourcerecordid>1935797803</sourcerecordid><originalsourceid>FETCH-LOGICAL-c403t-2f4e85e5b8d84c7de8c693f0fe9dfc10a6e6f197404f95558648adb5939cfb533</originalsourceid><addsrcrecordid>eNqFUctKxDAUDaLgOPoJQsF1O0nbtMlKZPAFAy7UdUjTGyelbWpSxf6Ba3f-nl9ihhkRV65yc3PPOffkIHRKcEIwKRZN0si2VbZL0nBNCElIme6hGWFlFudFwffRDPOUxixj7BAded9gjAnPyAx9Lm1XmR7qqAO1lr1Va-iMku1iXIPrZBv5qQ-lNz6yOgpPzio3-TEoBlg0TM6-QShW5gruTXpXRLKvI9tD7EcYflj_kPSh8dRK76df1Nf7RyV9WCPYGKw3IxyjAy1bDye7c44ery4fljfx6u76dnmxilWOszFOdQ6MAq1YzXJV1sBUwTONNfBaK4JlAYUmvMxxrjmllBU5k3VFecaVrmiWzdHZlndw9vkF_Cga--L6ICnCF9GSlwxvpuh2Kvj33oEWgzOddJMgWGxSEI3YpSA2KQhCREgh4M63OAgWXg044ZWBXkFtHKhR1Nb8w_ANBp2YMg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1935797803</pqid></control><display><type>article</type><title>Combined mechanochemical/thermal synthesis of microcrystalline pyroxene LiFeSi2O6 and one-step mechanosynthesis of nanoglassy LiFeSi2O6−based composite</title><source>ScienceDirect Journals (5 years ago - present)</source><creator>Turianicová, Erika ; Witte, Ralf ; Da Silva, Klebson L. ; Zorkovská, Anna ; Senna, Mamoru ; Hahn, Horst ; Heitjans, Paul ; Šepelák, Vladimír</creator><creatorcontrib>Turianicová, Erika ; Witte, Ralf ; Da Silva, Klebson L. ; Zorkovská, Anna ; Senna, Mamoru ; Hahn, Horst ; Heitjans, Paul ; Šepelák, Vladimír</creatorcontrib><description>Both, microcrystalline LiFeSi2O6 pyroxene and nanoglassy LiFeSi2O6−based composite are prepared via non-conventional mechanochemical/thermal processing and one-step mechanosynthesis, respectively. The structural state of the as-prepared materials on the long-range and local atomic scales is characterized by XRD and 57Fe Mössbauer spectroscopy, respectively. The derived hyperfine interaction parameters indicate that the nanoglassy nature of the mechanosynthesized LiFeSi2O6−based composite is characterized, on the short-range scale, by a broadly distorted geometry of the constituent structural units, and on the long-range scale, by the raptured chains of the edge-sharing FeO6 octahedra and of the corner-sharing SiO4 tetrahedra.
[Display omitted]
•Preparation of microcrystalline and nanoglassy LiFeSi2O6 pyroxene.•Non-conventional mechanochemical/thermal processing and one-step mechanosynthesis.•Characterization on a local atomic scale via nuclear 57Fe Mössbauer spectroscopy.</description><identifier>ISSN: 0925-8388</identifier><identifier>EISSN: 1873-4669</identifier><identifier>DOI: 10.1016/j.jallcom.2016.11.172</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Chemical synthesis ; Composite materials ; Interaction parameters ; Mechanosynthesis ; Mössbauer spectroscopy ; Nanoglass ; Polycrystals ; Pyroxene ; Pyroxenes ; Solid state reaction ; Spectrum analysis</subject><ispartof>Journal of alloys and compounds, 2017-06, Vol.707, p.310-314</ispartof><rights>2016 Elsevier B.V.</rights><rights>Copyright Elsevier BV Jun 15, 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c403t-2f4e85e5b8d84c7de8c693f0fe9dfc10a6e6f197404f95558648adb5939cfb533</citedby><cites>FETCH-LOGICAL-c403t-2f4e85e5b8d84c7de8c693f0fe9dfc10a6e6f197404f95558648adb5939cfb533</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jallcom.2016.11.172$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3548,27922,27923,45993</link.rule.ids></links><search><creatorcontrib>Turianicová, Erika</creatorcontrib><creatorcontrib>Witte, Ralf</creatorcontrib><creatorcontrib>Da Silva, Klebson L.</creatorcontrib><creatorcontrib>Zorkovská, Anna</creatorcontrib><creatorcontrib>Senna, Mamoru</creatorcontrib><creatorcontrib>Hahn, Horst</creatorcontrib><creatorcontrib>Heitjans, Paul</creatorcontrib><creatorcontrib>Šepelák, Vladimír</creatorcontrib><title>Combined mechanochemical/thermal synthesis of microcrystalline pyroxene LiFeSi2O6 and one-step mechanosynthesis of nanoglassy LiFeSi2O6−based composite</title><title>Journal of alloys and compounds</title><description>Both, microcrystalline LiFeSi2O6 pyroxene and nanoglassy LiFeSi2O6−based composite are prepared via non-conventional mechanochemical/thermal processing and one-step mechanosynthesis, respectively. The structural state of the as-prepared materials on the long-range and local atomic scales is characterized by XRD and 57Fe Mössbauer spectroscopy, respectively. The derived hyperfine interaction parameters indicate that the nanoglassy nature of the mechanosynthesized LiFeSi2O6−based composite is characterized, on the short-range scale, by a broadly distorted geometry of the constituent structural units, and on the long-range scale, by the raptured chains of the edge-sharing FeO6 octahedra and of the corner-sharing SiO4 tetrahedra.
[Display omitted]
•Preparation of microcrystalline and nanoglassy LiFeSi2O6 pyroxene.•Non-conventional mechanochemical/thermal processing and one-step mechanosynthesis.•Characterization on a local atomic scale via nuclear 57Fe Mössbauer spectroscopy.</description><subject>Chemical synthesis</subject><subject>Composite materials</subject><subject>Interaction parameters</subject><subject>Mechanosynthesis</subject><subject>Mössbauer spectroscopy</subject><subject>Nanoglass</subject><subject>Polycrystals</subject><subject>Pyroxene</subject><subject>Pyroxenes</subject><subject>Solid state reaction</subject><subject>Spectrum analysis</subject><issn>0925-8388</issn><issn>1873-4669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqFUctKxDAUDaLgOPoJQsF1O0nbtMlKZPAFAy7UdUjTGyelbWpSxf6Ba3f-nl9ihhkRV65yc3PPOffkIHRKcEIwKRZN0si2VbZL0nBNCElIme6hGWFlFudFwffRDPOUxixj7BAded9gjAnPyAx9Lm1XmR7qqAO1lr1Va-iMku1iXIPrZBv5qQ-lNz6yOgpPzio3-TEoBlg0TM6-QShW5gruTXpXRLKvI9tD7EcYflj_kPSh8dRK76df1Nf7RyV9WCPYGKw3IxyjAy1bDye7c44ery4fljfx6u76dnmxilWOszFOdQ6MAq1YzXJV1sBUwTONNfBaK4JlAYUmvMxxrjmllBU5k3VFecaVrmiWzdHZlndw9vkF_Cga--L6ICnCF9GSlwxvpuh2Kvj33oEWgzOddJMgWGxSEI3YpSA2KQhCREgh4M63OAgWXg044ZWBXkFtHKhR1Nb8w_ANBp2YMg</recordid><startdate>20170615</startdate><enddate>20170615</enddate><creator>Turianicová, Erika</creator><creator>Witte, Ralf</creator><creator>Da Silva, Klebson L.</creator><creator>Zorkovská, Anna</creator><creator>Senna, Mamoru</creator><creator>Hahn, Horst</creator><creator>Heitjans, Paul</creator><creator>Šepelák, Vladimír</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20170615</creationdate><title>Combined mechanochemical/thermal synthesis of microcrystalline pyroxene LiFeSi2O6 and one-step mechanosynthesis of nanoglassy LiFeSi2O6−based composite</title><author>Turianicová, Erika ; Witte, Ralf ; Da Silva, Klebson L. ; Zorkovská, Anna ; Senna, Mamoru ; Hahn, Horst ; Heitjans, Paul ; Šepelák, Vladimír</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c403t-2f4e85e5b8d84c7de8c693f0fe9dfc10a6e6f197404f95558648adb5939cfb533</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Chemical synthesis</topic><topic>Composite materials</topic><topic>Interaction parameters</topic><topic>Mechanosynthesis</topic><topic>Mössbauer spectroscopy</topic><topic>Nanoglass</topic><topic>Polycrystals</topic><topic>Pyroxene</topic><topic>Pyroxenes</topic><topic>Solid state reaction</topic><topic>Spectrum analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Turianicová, Erika</creatorcontrib><creatorcontrib>Witte, Ralf</creatorcontrib><creatorcontrib>Da Silva, Klebson L.</creatorcontrib><creatorcontrib>Zorkovská, Anna</creatorcontrib><creatorcontrib>Senna, Mamoru</creatorcontrib><creatorcontrib>Hahn, Horst</creatorcontrib><creatorcontrib>Heitjans, Paul</creatorcontrib><creatorcontrib>Šepelák, Vladimír</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of alloys and compounds</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Turianicová, Erika</au><au>Witte, Ralf</au><au>Da Silva, Klebson L.</au><au>Zorkovská, Anna</au><au>Senna, Mamoru</au><au>Hahn, Horst</au><au>Heitjans, Paul</au><au>Šepelák, Vladimír</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Combined mechanochemical/thermal synthesis of microcrystalline pyroxene LiFeSi2O6 and one-step mechanosynthesis of nanoglassy LiFeSi2O6−based composite</atitle><jtitle>Journal of alloys and compounds</jtitle><date>2017-06-15</date><risdate>2017</risdate><volume>707</volume><spage>310</spage><epage>314</epage><pages>310-314</pages><issn>0925-8388</issn><eissn>1873-4669</eissn><abstract>Both, microcrystalline LiFeSi2O6 pyroxene and nanoglassy LiFeSi2O6−based composite are prepared via non-conventional mechanochemical/thermal processing and one-step mechanosynthesis, respectively. The structural state of the as-prepared materials on the long-range and local atomic scales is characterized by XRD and 57Fe Mössbauer spectroscopy, respectively. The derived hyperfine interaction parameters indicate that the nanoglassy nature of the mechanosynthesized LiFeSi2O6−based composite is characterized, on the short-range scale, by a broadly distorted geometry of the constituent structural units, and on the long-range scale, by the raptured chains of the edge-sharing FeO6 octahedra and of the corner-sharing SiO4 tetrahedra.
[Display omitted]
•Preparation of microcrystalline and nanoglassy LiFeSi2O6 pyroxene.•Non-conventional mechanochemical/thermal processing and one-step mechanosynthesis.•Characterization on a local atomic scale via nuclear 57Fe Mössbauer spectroscopy.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jallcom.2016.11.172</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0925-8388 |
| ispartof | Journal of alloys and compounds, 2017-06, Vol.707, p.310-314 |
| issn | 0925-8388 1873-4669 |
| language | eng |
| recordid | cdi_proquest_journals_1935797803 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Chemical synthesis Composite materials Interaction parameters Mechanosynthesis Mössbauer spectroscopy Nanoglass Polycrystals Pyroxene Pyroxenes Solid state reaction Spectrum analysis |
| title | Combined mechanochemical/thermal synthesis of microcrystalline pyroxene LiFeSi2O6 and one-step mechanosynthesis of nanoglassy LiFeSi2O6−based composite |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-09T20%3A50%3A29IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Combined%20mechanochemical/thermal%20synthesis%20of%20microcrystalline%20pyroxene%20LiFeSi2O6%20and%20one-step%20mechanosynthesis%20of%20nanoglassy%20LiFeSi2O6%E2%88%92based%20composite&rft.jtitle=Journal%20of%20alloys%20and%20compounds&rft.au=Turianicov%C3%A1,%20Erika&rft.date=2017-06-15&rft.volume=707&rft.spage=310&rft.epage=314&rft.pages=310-314&rft.issn=0925-8388&rft.eissn=1873-4669&rft_id=info:doi/10.1016/j.jallcom.2016.11.172&rft_dat=%3Cproquest_cross%3E1935797803%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1935797803&rft_id=info:pmid/&rft_els_id=S0925838816336520&rfr_iscdi=true |