Electrical conductivity of potassium titanyl phosphate KTiOPO4 pure crystals and those doped with Na+, Rb+, and F– ions
KTiOPO 4 crystals, both pure and doped with rubidium Rb + and fluorine F – ions, were grown in temperature range from 1060 to 846°С from salt solvent containing potassium metaphosphate КРО 3 and potassium orthophosphate К3РО 4 by using a Czochralski modified method. Potassium–sodium titanyl phosphat...
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| Veröffentlicht in: | Russian journal of electrochemistry 2017-08, Vol.53 (8), p.846-851 |
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| container_title | Russian journal of electrochemistry |
| container_volume | 53 |
| creator | Glumov, O. V. Bodnar, V. A. Mel’nikova, N. A. Yakobson, V. E. Murin, I. V. |
| description | KTiOPO
4
crystals, both pure and doped with rubidium Rb
+
and fluorine F
–
ions, were grown in temperature range from 1060 to 846°С from salt solvent containing potassium metaphosphate КРО
3
and potassium orthophosphate К3РО
4
by using a Czochralski modified method. Potassium–sodium titanyl phosphate crystals were obtained from KTiOPO
4
crystals by the potassium isomorphic replacement with sodium; to this purpose, sodium chemical diffusion from NaNO
3
melt was used. Their ionic conductivity was studied by the electrochemical impedance spectroscopy method. The KTiOPO
4
crystal doping with rubidium and sodium ions was shown to lower the conductivity, whereas the doping with fluorine ions results in increased conductivity. |
| doi_str_mv | 10.1134/S1023193517080055 |
| format | Article |
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4
crystals, both pure and doped with rubidium Rb
+
and fluorine F
–
ions, were grown in temperature range from 1060 to 846°С from salt solvent containing potassium metaphosphate КРО
3
and potassium orthophosphate К3РО
4
by using a Czochralski modified method. Potassium–sodium titanyl phosphate crystals were obtained from KTiOPO
4
crystals by the potassium isomorphic replacement with sodium; to this purpose, sodium chemical diffusion from NaNO
3
melt was used. Their ionic conductivity was studied by the electrochemical impedance spectroscopy method. The KTiOPO
4
crystal doping with rubidium and sodium ions was shown to lower the conductivity, whereas the doping with fluorine ions results in increased conductivity.</description><identifier>ISSN: 1023-1935</identifier><identifier>EISSN: 1608-3342</identifier><identifier>DOI: 10.1134/S1023193517080055</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemical diffusion ; Chemistry ; Chemistry and Materials Science ; Conductivity ; Doping ; Electrical resistivity ; Electrochemical impedance spectroscopy ; Electrochemistry ; Fluorine ; Ion currents ; Physical Chemistry ; Potassium ; Rubidium ; Sodium</subject><ispartof>Russian journal of electrochemistry, 2017-08, Vol.53 (8), p.846-851</ispartof><rights>Pleiades Publishing, Ltd. 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-9aa47779b98f3ba1fe20026ef3e5ff7d7fc587cfbe630a2ddf48e633625a0f453</citedby><cites>FETCH-LOGICAL-c316t-9aa47779b98f3ba1fe20026ef3e5ff7d7fc587cfbe630a2ddf48e633625a0f453</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1023193517080055$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1023193517080055$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Glumov, O. V.</creatorcontrib><creatorcontrib>Bodnar, V. A.</creatorcontrib><creatorcontrib>Mel’nikova, N. A.</creatorcontrib><creatorcontrib>Yakobson, V. E.</creatorcontrib><creatorcontrib>Murin, I. V.</creatorcontrib><title>Electrical conductivity of potassium titanyl phosphate KTiOPO4 pure crystals and those doped with Na+, Rb+, and F– ions</title><title>Russian journal of electrochemistry</title><addtitle>Russ J Electrochem</addtitle><description>KTiOPO
4
crystals, both pure and doped with rubidium Rb
+
and fluorine F
–
ions, were grown in temperature range from 1060 to 846°С from salt solvent containing potassium metaphosphate КРО
3
and potassium orthophosphate К3РО
4
by using a Czochralski modified method. Potassium–sodium titanyl phosphate crystals were obtained from KTiOPO
4
crystals by the potassium isomorphic replacement with sodium; to this purpose, sodium chemical diffusion from NaNO
3
melt was used. Their ionic conductivity was studied by the electrochemical impedance spectroscopy method. The KTiOPO
4
crystal doping with rubidium and sodium ions was shown to lower the conductivity, whereas the doping with fluorine ions results in increased conductivity.</description><subject>Chemical diffusion</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Conductivity</subject><subject>Doping</subject><subject>Electrical resistivity</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrochemistry</subject><subject>Fluorine</subject><subject>Ion currents</subject><subject>Physical Chemistry</subject><subject>Potassium</subject><subject>Rubidium</subject><subject>Sodium</subject><issn>1023-1935</issn><issn>1608-3342</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1UMtKxDAUDaLgOPoB7gIutZpXm3Ypg6Pi4IiO65KmiZOh09QkVbrzH_xDv8QM40IQF_feA-dx4QBwjNE5xpRdPGFEKC5oijnKEUrTHTDCGcoTShnZjTjSyYbfBwferxBCOcfFCAxXjZLBGSkaKG1b9zKYNxMGaDXsbBDem34NgwmiHRrYLa3vliIoeLcw84c5g13vFJRu8EE0Hoq2hiFqFKxtp2r4bsIS3ovTM_hYxbWhp18fn9DY1h-CPR096ujnjsHz9GoxuUlm8-vbyeUskRRnISmEYJzzoipyTSuBtSIIkUxpqlKtec21THMudaUyigSpa83yCGlGUoE0S-kYnGxzO2dfe-VDubK9a-PLMvbB0jiMRBXeqqSz3july86ZtXBDiVG5abj803D0kK3HR237otyv5H9N30tzfjw</recordid><startdate>20170801</startdate><enddate>20170801</enddate><creator>Glumov, O. V.</creator><creator>Bodnar, V. A.</creator><creator>Mel’nikova, N. A.</creator><creator>Yakobson, V. E.</creator><creator>Murin, I. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20170801</creationdate><title>Electrical conductivity of potassium titanyl phosphate KTiOPO4 pure crystals and those doped with Na+, Rb+, and F– ions</title><author>Glumov, O. V. ; Bodnar, V. A. ; Mel’nikova, N. A. ; Yakobson, V. E. ; Murin, I. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-9aa47779b98f3ba1fe20026ef3e5ff7d7fc587cfbe630a2ddf48e633625a0f453</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Chemical diffusion</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Conductivity</topic><topic>Doping</topic><topic>Electrical resistivity</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrochemistry</topic><topic>Fluorine</topic><topic>Ion currents</topic><topic>Physical Chemistry</topic><topic>Potassium</topic><topic>Rubidium</topic><topic>Sodium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Glumov, O. V.</creatorcontrib><creatorcontrib>Bodnar, V. A.</creatorcontrib><creatorcontrib>Mel’nikova, N. A.</creatorcontrib><creatorcontrib>Yakobson, V. E.</creatorcontrib><creatorcontrib>Murin, I. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Glumov, O. V.</au><au>Bodnar, V. A.</au><au>Mel’nikova, N. A.</au><au>Yakobson, V. E.</au><au>Murin, I. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrical conductivity of potassium titanyl phosphate KTiOPO4 pure crystals and those doped with Na+, Rb+, and F– ions</atitle><jtitle>Russian journal of electrochemistry</jtitle><stitle>Russ J Electrochem</stitle><date>2017-08-01</date><risdate>2017</risdate><volume>53</volume><issue>8</issue><spage>846</spage><epage>851</epage><pages>846-851</pages><issn>1023-1935</issn><eissn>1608-3342</eissn><abstract>KTiOPO
4
crystals, both pure and doped with rubidium Rb
+
and fluorine F
–
ions, were grown in temperature range from 1060 to 846°С from salt solvent containing potassium metaphosphate КРО
3
and potassium orthophosphate К3РО
4
by using a Czochralski modified method. Potassium–sodium titanyl phosphate crystals were obtained from KTiOPO
4
crystals by the potassium isomorphic replacement with sodium; to this purpose, sodium chemical diffusion from NaNO
3
melt was used. Their ionic conductivity was studied by the electrochemical impedance spectroscopy method. The KTiOPO
4
crystal doping with rubidium and sodium ions was shown to lower the conductivity, whereas the doping with fluorine ions results in increased conductivity.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1023193517080055</doi><tpages>6</tpages></addata></record> |
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| ispartof | Russian journal of electrochemistry, 2017-08, Vol.53 (8), p.846-851 |
| issn | 1023-1935 1608-3342 |
| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Chemical diffusion Chemistry Chemistry and Materials Science Conductivity Doping Electrical resistivity Electrochemical impedance spectroscopy Electrochemistry Fluorine Ion currents Physical Chemistry Potassium Rubidium Sodium |
| title | Electrical conductivity of potassium titanyl phosphate KTiOPO4 pure crystals and those doped with Na+, Rb+, and F– ions |
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