The structure and application of amine‐terminated hyperbranched polymer shale inhibitor for water‐based drilling fluid

ABSTRACT Amine‐terminated hyperbranched polymer (HBP‐NH2), as an inhibitor in water‐based drilling fluid, is prepared by the polycondensation of diamine AB2 monomers. The primary amine and secondary amide structures are confirmed by Fourier transform infrared spectroscopy and nuclear magnetic resona...

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Veröffentlicht in:Journal of applied polymer science 2017-12, Vol.134 (46), p.n/a
Hauptverfasser: Bai, Xiaodong, Wang, Hao, Luo, Yumei, Zheng, Xiaoxu, Zhang, Xingyuan, Zhou, Song, Pu, Xiaolin
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container_issue 46
container_start_page
container_title Journal of applied polymer science
container_volume 134
creator Bai, Xiaodong
Wang, Hao
Luo, Yumei
Zheng, Xiaoxu
Zhang, Xingyuan
Zhou, Song
Pu, Xiaolin
description ABSTRACT Amine‐terminated hyperbranched polymer (HBP‐NH2), as an inhibitor in water‐based drilling fluid, is prepared by the polycondensation of diamine AB2 monomers. The primary amine and secondary amide structures are confirmed by Fourier transform infrared spectroscopy and nuclear magnetic resonance hydrogen spectroscopy. Through time of flight mass spectrometry, the molecular weight of HBP‐NH2 is mainly distributed in the range of 200–1400. Also, the quasi‐spherical shape and the high temperature resistance (200 °C) performance of HBP‐NH2 are, respectively, certified through the environmental scanning electron microscope and the thermogravimetric analysis. In the inhibition performance test, the linear expansion rate of sodium bentonite in 3 wt % HBP‐NH2 aqueous solution is only 11.42%, which is lower than other inhibitors (KCl, FA‐367, and HPAM). Zeta potential analysis shows that HBP‐NH2 has a strong ability to inhibit the hydration and dispersion of sodium bentonite by protonated primary amine groups. Compared with the base slurry, the absolute value of zeta potential is reduced by 25.5 mV in the slurry containing 3 wt % HBP‐NH2 at 180 rpm. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 45466.
doi_str_mv 10.1002/app.45466
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The primary amine and secondary amide structures are confirmed by Fourier transform infrared spectroscopy and nuclear magnetic resonance hydrogen spectroscopy. Through time of flight mass spectrometry, the molecular weight of HBP‐NH2 is mainly distributed in the range of 200–1400. Also, the quasi‐spherical shape and the high temperature resistance (200 °C) performance of HBP‐NH2 are, respectively, certified through the environmental scanning electron microscope and the thermogravimetric analysis. In the inhibition performance test, the linear expansion rate of sodium bentonite in 3 wt % HBP‐NH2 aqueous solution is only 11.42%, which is lower than other inhibitors (KCl, FA‐367, and HPAM). Zeta potential analysis shows that HBP‐NH2 has a strong ability to inhibit the hydration and dispersion of sodium bentonite by protonated primary amine groups. 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The primary amine and secondary amide structures are confirmed by Fourier transform infrared spectroscopy and nuclear magnetic resonance hydrogen spectroscopy. Through time of flight mass spectrometry, the molecular weight of HBP‐NH2 is mainly distributed in the range of 200–1400. Also, the quasi‐spherical shape and the high temperature resistance (200 °C) performance of HBP‐NH2 are, respectively, certified through the environmental scanning electron microscope and the thermogravimetric analysis. In the inhibition performance test, the linear expansion rate of sodium bentonite in 3 wt % HBP‐NH2 aqueous solution is only 11.42%, which is lower than other inhibitors (KCl, FA‐367, and HPAM). Zeta potential analysis shows that HBP‐NH2 has a strong ability to inhibit the hydration and dispersion of sodium bentonite by protonated primary amine groups. 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source Wiley Online Library Journals Frontfile Complete
subjects applications
Bentonite
clay
dendrimers
Drilling
Fourier transforms
hyperbranched polymers and macrocycles
Infrared spectroscopy
Inhibitors
Mass spectrometry
Materials science
Molecular weight distribution
Monomers
NMR
Nuclear magnetic resonance
oil and gas
Polymers
Slurries
Sodium
Thermogravimetric analysis
Zeta potential
title The structure and application of amine‐terminated hyperbranched polymer shale inhibitor for water‐based drilling fluid
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