Magnetic and magnetocaloric properties of the ternary cadmium based intermetallic compounds of Gd2Cu2Cd and Er2Cu2Cd

The magnetic properties, magnetocaloric effect (MCE) and universal behaviour of ternary Cadmium compounds Gd2Cu2Cd and Er2Cu2Cd have been investigated systematically. A second order magnetic phase transition from a paramagnetic to ferromagnetic state is observed for Gd2Cu2Cd and Er2Cu2Cd at their ow...

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Veröffentlicht in:Journal of alloys and compounds 2017-01, Vol.692, p.665-669
Hauptverfasser: Yang, Yang, Zhang, Yikun, Xu, Xiao, Geng, Shuhua, Hou, Long, Li, Xi, Ren, Zhongming, Wilde, Gerhard
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container_title Journal of alloys and compounds
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Zhang, Yikun
Xu, Xiao
Geng, Shuhua
Hou, Long
Li, Xi
Ren, Zhongming
Wilde, Gerhard
description The magnetic properties, magnetocaloric effect (MCE) and universal behaviour of ternary Cadmium compounds Gd2Cu2Cd and Er2Cu2Cd have been investigated systematically. A second order magnetic phase transition from a paramagnetic to ferromagnetic state is observed for Gd2Cu2Cd and Er2Cu2Cd at their own Curie temperatures of TC ∼120 and 36 K, respectively. A large reversible MCE occurs near its own TC for both compounds. The maximum values of magnetic entropy change (−ΔSMmax) are 10.1 and 19.1 J/kg K under a magnetic field change of 0–7 T with no obviously hysteresis loss for Gd2Cu2Cd and Er2Cu2Cd, respectively. The corresponding values of refrigerant capacity (RC) and relative cooling power (RCP) are evaluated to be 386 and 373 J/kg, and to be 525 and 489 J/kg, respectively. The rescaled magnetic entropy change curves collapse onto a single curve for various magnetic fields, further confirming the Gd2Cu2Cd and Er2Cu2Cd compounds with the second order phase transition. •Magnetism and magnetocaloric effect in Gd2Cu2Cd and Er2Cu2Cd were studied.•A considerable reversible MCE was observed for both compounds around its own TC.•The origin of MCE and its potential application in Gd2Cu2Cd and Er2Cu2Cd were discussed.
doi_str_mv 10.1016/j.jallcom.2016.09.104
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The rescaled magnetic entropy change curves collapse onto a single curve for various magnetic fields, further confirming the Gd2Cu2Cd and Er2Cu2Cd compounds with the second order phase transition. •Magnetism and magnetocaloric effect in Gd2Cu2Cd and Er2Cu2Cd were studied.•A considerable reversible MCE was observed for both compounds around its own TC.•The origin of MCE and its potential application in Gd2Cu2Cd and Er2Cu2Cd were discussed.</description><identifier>ISSN: 0925-8388</identifier><identifier>EISSN: 1873-4669</identifier><identifier>DOI: 10.1016/j.jallcom.2016.09.104</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Cadmium ; Copper ; Core loss ; Entropy ; Erbium compounds ; Ferromagnetism ; Gadolinium compounds ; Gd2Cu2Cd and Er2Cu2Cd compounds ; Intermetallic compounds ; Magnetic fields ; Magnetic phase transition ; Magnetic properties ; Magnetocaloric effect ; Phase transitions ; Refrigeration</subject><ispartof>Journal of alloys and compounds, 2017-01, Vol.692, p.665-669</ispartof><rights>2016 Elsevier B.V.</rights><rights>Copyright Elsevier BV Jan 25, 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-483a50fa8e958bc02971236eab187c8d5555b2aca09cdb3658b08346d2f67f93</citedby><cites>FETCH-LOGICAL-c337t-483a50fa8e958bc02971236eab187c8d5555b2aca09cdb3658b08346d2f67f93</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0925838816328560$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Yang, Yang</creatorcontrib><creatorcontrib>Zhang, Yikun</creatorcontrib><creatorcontrib>Xu, Xiao</creatorcontrib><creatorcontrib>Geng, Shuhua</creatorcontrib><creatorcontrib>Hou, Long</creatorcontrib><creatorcontrib>Li, Xi</creatorcontrib><creatorcontrib>Ren, Zhongming</creatorcontrib><creatorcontrib>Wilde, Gerhard</creatorcontrib><title>Magnetic and magnetocaloric properties of the ternary cadmium based intermetallic compounds of Gd2Cu2Cd and Er2Cu2Cd</title><title>Journal of alloys and compounds</title><description>The magnetic properties, magnetocaloric effect (MCE) and universal behaviour of ternary Cadmium compounds Gd2Cu2Cd and Er2Cu2Cd have been investigated systematically. 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The rescaled magnetic entropy change curves collapse onto a single curve for various magnetic fields, further confirming the Gd2Cu2Cd and Er2Cu2Cd compounds with the second order phase transition. •Magnetism and magnetocaloric effect in Gd2Cu2Cd and Er2Cu2Cd were studied.•A considerable reversible MCE was observed for both compounds around its own TC.•The origin of MCE and its potential application in Gd2Cu2Cd and Er2Cu2Cd were discussed.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jallcom.2016.09.104</doi><tpages>5</tpages></addata></record>
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subjects Cadmium
Copper
Core loss
Entropy
Erbium compounds
Ferromagnetism
Gadolinium compounds
Gd2Cu2Cd and Er2Cu2Cd compounds
Intermetallic compounds
Magnetic fields
Magnetic phase transition
Magnetic properties
Magnetocaloric effect
Phase transitions
Refrigeration
title Magnetic and magnetocaloric properties of the ternary cadmium based intermetallic compounds of Gd2Cu2Cd and Er2Cu2Cd
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