Extremely conductive RuO^sub 2^-coated LiNi^sub 0.5^Mn^sub 1.5^O^sub 4^ for lithium-ion batteries

An unprecedentedly high electronic conductivity of 0.27 S cm-1 is achieved by depositing 0.56 wt% crystalline RuO2 on LNMO via a wet-chemical route. Systematic assessment of the electrochemical performance of bare and RuO2-coated LNMO electrodes unambiguously demonstrates that the high electronic co...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Electrochimica acta 2017-04, Vol.232, p.236
Hauptverfasser: Jung, Sung Hoo, Kim, Dong Hyeon, Brüner, Philipp, Lee, Hyeyoun, Hah, Hoe Jin, Kim, Seok Koo, Jung, Yoon Seok
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue
container_start_page 236
container_title Electrochimica acta
container_volume 232
creator Jung, Sung Hoo
Kim, Dong Hyeon
Brüner, Philipp
Lee, Hyeyoun
Hah, Hoe Jin
Kim, Seok Koo
Jung, Yoon Seok
description An unprecedentedly high electronic conductivity of 0.27 S cm-1 is achieved by depositing 0.56 wt% crystalline RuO2 on LNMO via a wet-chemical route. Systematic assessment of the electrochemical performance of bare and RuO2-coated LNMO electrodes unambiguously demonstrates that the high electronic conductivity of RuO2 enables significant enhancement in rate capability. These improvements are dramatic for the electrodes in which extremely low amounts of carbon additives are included and/or the loading amount is high. This finding highlights the importance of electronic conduction in composite electrodes, not only for high power but also for high energy density. The RuO2-coated LNMO electrode with 1 wt% carbon additives exhibits a high capacity of 100 mA h g-1 at 1C in the range 3.0-5.0 V (vs. Li/Li+). This result is in sharp contrast to the negligible capacity exhibited by the bare LNMO electrode. In addition, the chemical/electrochemical stability of the RuO2 coating under repeated cycling is confirmed, explaining the observed improvement in durability of the RuO2-coated LNMO over the bare LNMO.
format Article
fullrecord <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_journals_1932355947</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1932355947</sourcerecordid><originalsourceid>FETCH-proquest_journals_19323559473</originalsourceid><addsrcrecordid>eNqNikkKwjAARYMoWIc7BFxHkqbjWiouHEBcp6RtiiltoxlEb29RD-DqP_57I-CRJKaIJmE6Bh7GhKIgSqIpmBnTYIzjKMYe4NnTatGJ9gVL1VeutPIh4NmdmHEF9BkqFbeignt5lJ8Lr0N26D9IBvx2AYO10rCV9ipdh6TqYcGtFVoKswCTmrdGLH87B6ttdtns0E2ruxPG5o1yuh9UTlLq0zBMg5j-V70BjrdFDA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1932355947</pqid></control><display><type>article</type><title>Extremely conductive RuO^sub 2^-coated LiNi^sub 0.5^Mn^sub 1.5^O^sub 4^ for lithium-ion batteries</title><source>Elsevier ScienceDirect Journals Complete</source><creator>Jung, Sung Hoo ; Kim, Dong Hyeon ; Brüner, Philipp ; Lee, Hyeyoun ; Hah, Hoe Jin ; Kim, Seok Koo ; Jung, Yoon Seok</creator><creatorcontrib>Jung, Sung Hoo ; Kim, Dong Hyeon ; Brüner, Philipp ; Lee, Hyeyoun ; Hah, Hoe Jin ; Kim, Seok Koo ; Jung, Yoon Seok</creatorcontrib><description>An unprecedentedly high electronic conductivity of 0.27 S cm-1 is achieved by depositing 0.56 wt% crystalline RuO2 on LNMO via a wet-chemical route. Systematic assessment of the electrochemical performance of bare and RuO2-coated LNMO electrodes unambiguously demonstrates that the high electronic conductivity of RuO2 enables significant enhancement in rate capability. These improvements are dramatic for the electrodes in which extremely low amounts of carbon additives are included and/or the loading amount is high. This finding highlights the importance of electronic conduction in composite electrodes, not only for high power but also for high energy density. The RuO2-coated LNMO electrode with 1 wt% carbon additives exhibits a high capacity of 100 mA h g-1 at 1C in the range 3.0-5.0 V (vs. Li/Li+). This result is in sharp contrast to the negligible capacity exhibited by the bare LNMO electrode. In addition, the chemical/electrochemical stability of the RuO2 coating under repeated cycling is confirmed, explaining the observed improvement in durability of the RuO2-coated LNMO over the bare LNMO.</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><language>eng</language><publisher>Oxford: Elsevier BV</publisher><subject>Additives ; Batteries ; Chemical compounds ; Coated electrodes ; Conductivity ; Crystal structure ; Electrochemical analysis ; Electrodes ; Flux density ; Lithium ; Lithium-ion batteries ; Rechargeable batteries ; Ruthenium oxide ; Studies</subject><ispartof>Electrochimica acta, 2017-04, Vol.232, p.236</ispartof><rights>Copyright Elsevier BV Apr 1, 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784</link.rule.ids></links><search><creatorcontrib>Jung, Sung Hoo</creatorcontrib><creatorcontrib>Kim, Dong Hyeon</creatorcontrib><creatorcontrib>Brüner, Philipp</creatorcontrib><creatorcontrib>Lee, Hyeyoun</creatorcontrib><creatorcontrib>Hah, Hoe Jin</creatorcontrib><creatorcontrib>Kim, Seok Koo</creatorcontrib><creatorcontrib>Jung, Yoon Seok</creatorcontrib><title>Extremely conductive RuO^sub 2^-coated LiNi^sub 0.5^Mn^sub 1.5^O^sub 4^ for lithium-ion batteries</title><title>Electrochimica acta</title><description>An unprecedentedly high electronic conductivity of 0.27 S cm-1 is achieved by depositing 0.56 wt% crystalline RuO2 on LNMO via a wet-chemical route. Systematic assessment of the electrochemical performance of bare and RuO2-coated LNMO electrodes unambiguously demonstrates that the high electronic conductivity of RuO2 enables significant enhancement in rate capability. These improvements are dramatic for the electrodes in which extremely low amounts of carbon additives are included and/or the loading amount is high. This finding highlights the importance of electronic conduction in composite electrodes, not only for high power but also for high energy density. The RuO2-coated LNMO electrode with 1 wt% carbon additives exhibits a high capacity of 100 mA h g-1 at 1C in the range 3.0-5.0 V (vs. Li/Li+). This result is in sharp contrast to the negligible capacity exhibited by the bare LNMO electrode. In addition, the chemical/electrochemical stability of the RuO2 coating under repeated cycling is confirmed, explaining the observed improvement in durability of the RuO2-coated LNMO over the bare LNMO.</description><subject>Additives</subject><subject>Batteries</subject><subject>Chemical compounds</subject><subject>Coated electrodes</subject><subject>Conductivity</subject><subject>Crystal structure</subject><subject>Electrochemical analysis</subject><subject>Electrodes</subject><subject>Flux density</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Rechargeable batteries</subject><subject>Ruthenium oxide</subject><subject>Studies</subject><issn>0013-4686</issn><issn>1873-3859</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqNikkKwjAARYMoWIc7BFxHkqbjWiouHEBcp6RtiiltoxlEb29RD-DqP_57I-CRJKaIJmE6Bh7GhKIgSqIpmBnTYIzjKMYe4NnTatGJ9gVL1VeutPIh4NmdmHEF9BkqFbeignt5lJ8Lr0N26D9IBvx2AYO10rCV9ipdh6TqYcGtFVoKswCTmrdGLH87B6ttdtns0E2ruxPG5o1yuh9UTlLq0zBMg5j-V70BjrdFDA</recordid><startdate>20170401</startdate><enddate>20170401</enddate><creator>Jung, Sung Hoo</creator><creator>Kim, Dong Hyeon</creator><creator>Brüner, Philipp</creator><creator>Lee, Hyeyoun</creator><creator>Hah, Hoe Jin</creator><creator>Kim, Seok Koo</creator><creator>Jung, Yoon Seok</creator><general>Elsevier BV</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20170401</creationdate><title>Extremely conductive RuO^sub 2^-coated LiNi^sub 0.5^Mn^sub 1.5^O^sub 4^ for lithium-ion batteries</title><author>Jung, Sung Hoo ; Kim, Dong Hyeon ; Brüner, Philipp ; Lee, Hyeyoun ; Hah, Hoe Jin ; Kim, Seok Koo ; Jung, Yoon Seok</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_journals_19323559473</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Additives</topic><topic>Batteries</topic><topic>Chemical compounds</topic><topic>Coated electrodes</topic><topic>Conductivity</topic><topic>Crystal structure</topic><topic>Electrochemical analysis</topic><topic>Electrodes</topic><topic>Flux density</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>Rechargeable batteries</topic><topic>Ruthenium oxide</topic><topic>Studies</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jung, Sung Hoo</creatorcontrib><creatorcontrib>Kim, Dong Hyeon</creatorcontrib><creatorcontrib>Brüner, Philipp</creatorcontrib><creatorcontrib>Lee, Hyeyoun</creatorcontrib><creatorcontrib>Hah, Hoe Jin</creatorcontrib><creatorcontrib>Kim, Seok Koo</creatorcontrib><creatorcontrib>Jung, Yoon Seok</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jung, Sung Hoo</au><au>Kim, Dong Hyeon</au><au>Brüner, Philipp</au><au>Lee, Hyeyoun</au><au>Hah, Hoe Jin</au><au>Kim, Seok Koo</au><au>Jung, Yoon Seok</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Extremely conductive RuO^sub 2^-coated LiNi^sub 0.5^Mn^sub 1.5^O^sub 4^ for lithium-ion batteries</atitle><jtitle>Electrochimica acta</jtitle><date>2017-04-01</date><risdate>2017</risdate><volume>232</volume><spage>236</spage><pages>236-</pages><issn>0013-4686</issn><eissn>1873-3859</eissn><abstract>An unprecedentedly high electronic conductivity of 0.27 S cm-1 is achieved by depositing 0.56 wt% crystalline RuO2 on LNMO via a wet-chemical route. Systematic assessment of the electrochemical performance of bare and RuO2-coated LNMO electrodes unambiguously demonstrates that the high electronic conductivity of RuO2 enables significant enhancement in rate capability. These improvements are dramatic for the electrodes in which extremely low amounts of carbon additives are included and/or the loading amount is high. This finding highlights the importance of electronic conduction in composite electrodes, not only for high power but also for high energy density. The RuO2-coated LNMO electrode with 1 wt% carbon additives exhibits a high capacity of 100 mA h g-1 at 1C in the range 3.0-5.0 V (vs. Li/Li+). This result is in sharp contrast to the negligible capacity exhibited by the bare LNMO electrode. In addition, the chemical/electrochemical stability of the RuO2 coating under repeated cycling is confirmed, explaining the observed improvement in durability of the RuO2-coated LNMO over the bare LNMO.</abstract><cop>Oxford</cop><pub>Elsevier BV</pub></addata></record>
fulltext fulltext
identifier ISSN: 0013-4686
ispartof Electrochimica acta, 2017-04, Vol.232, p.236
issn 0013-4686
1873-3859
language eng
recordid cdi_proquest_journals_1932355947
source Elsevier ScienceDirect Journals Complete
subjects Additives
Batteries
Chemical compounds
Coated electrodes
Conductivity
Crystal structure
Electrochemical analysis
Electrodes
Flux density
Lithium
Lithium-ion batteries
Rechargeable batteries
Ruthenium oxide
Studies
title Extremely conductive RuO^sub 2^-coated LiNi^sub 0.5^Mn^sub 1.5^O^sub 4^ for lithium-ion batteries
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T17%3A24%3A06IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Extremely%20conductive%20RuO%5Esub%202%5E-coated%20LiNi%5Esub%200.5%5EMn%5Esub%201.5%5EO%5Esub%204%5E%20for%20lithium-ion%20batteries&rft.jtitle=Electrochimica%20acta&rft.au=Jung,%20Sung%20Hoo&rft.date=2017-04-01&rft.volume=232&rft.spage=236&rft.pages=236-&rft.issn=0013-4686&rft.eissn=1873-3859&rft_id=info:doi/&rft_dat=%3Cproquest%3E1932355947%3C/proquest%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1932355947&rft_id=info:pmid/&rfr_iscdi=true