Amino-substituted Tröger’s base: electrochemical polymerization and characterization of the polymer film
The amino-substituted coumarin derivative of Tröger’s base (CTB) was electrochemically polymerized on the surface of gold electrodes. The obtained polymer films were characterized by SEM, Raman spectroscopy, cyclic voltammetry and in-situ conductometry. Spectroscopic analysis indicates that the poly...
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| Veröffentlicht in: | Electrochimica acta 2017-01, Vol.224, p.439-445 |
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| container_title | Electrochimica acta |
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| creator | Shishkanova, Tatiana V. Havlík, Martin Král, Vladimír Kopecký, Dušan Matějka, Pavel Dendisová, Marcela Mirsky, Vladimir M. |
| description | The amino-substituted coumarin derivative of Tröger’s base (CTB) was electrochemically polymerized on the surface of gold electrodes. The obtained polymer films were characterized by SEM, Raman spectroscopy, cyclic voltammetry and in-situ conductometry. Spectroscopic analysis indicates that the polymerization of CTB takes place via oxidation of the aniline fragment of CTB molecule, similar to the polymerization of aniline. The similarity of the polymer backbone to that of the polyaniline is also confirmed by the influence of potential on the film’s conductivity, however the conductivity of the new material is in principle lower than that of polyaniline. SEM shows that the polymer forms a thin layer with a thickness of ∼100nm. Possible applications of the new material as an artificial receptor for aromatic analytes containing carboxy-group are proposed. |
| doi_str_mv | 10.1016/j.electacta.2016.12.061 |
| format | Article |
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The obtained polymer films were characterized by SEM, Raman spectroscopy, cyclic voltammetry and in-situ conductometry. Spectroscopic analysis indicates that the polymerization of CTB takes place via oxidation of the aniline fragment of CTB molecule, similar to the polymerization of aniline. The similarity of the polymer backbone to that of the polyaniline is also confirmed by the influence of potential on the film’s conductivity, however the conductivity of the new material is in principle lower than that of polyaniline. SEM shows that the polymer forms a thin layer with a thickness of ∼100nm. Possible applications of the new material as an artificial receptor for aromatic analytes containing carboxy-group are proposed.</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><identifier>DOI: 10.1016/j.electacta.2016.12.061</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Aniline ; Coumarin ; Electrochemical analysis ; electrochemical polymerization ; Electrodes ; Gold ; nitrogen heterocycle ; Oxidation ; Polyanilines ; polymer film ; Polymer films ; polymeric Tröger’s base ; Polymerization ; Raman spectroscopy ; Scanning electron microscopy ; Spectroscopic analysis ; spectroscopic characterization ; Studies ; Thickness</subject><ispartof>Electrochimica acta, 2017-01, Vol.224, p.439-445</ispartof><rights>2016 Elsevier Ltd</rights><rights>Copyright Elsevier BV Jan 10, 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c380t-b9c19148331230868cac2fcaf8e0183e4ade9d8fb24560420effc41a4dffb2093</citedby><cites>FETCH-LOGICAL-c380t-b9c19148331230868cac2fcaf8e0183e4ade9d8fb24560420effc41a4dffb2093</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S001346861632607X$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,65309</link.rule.ids></links><search><creatorcontrib>Shishkanova, Tatiana V.</creatorcontrib><creatorcontrib>Havlík, Martin</creatorcontrib><creatorcontrib>Král, Vladimír</creatorcontrib><creatorcontrib>Kopecký, Dušan</creatorcontrib><creatorcontrib>Matějka, Pavel</creatorcontrib><creatorcontrib>Dendisová, Marcela</creatorcontrib><creatorcontrib>Mirsky, Vladimir M.</creatorcontrib><title>Amino-substituted Tröger’s base: electrochemical polymerization and characterization of the polymer film</title><title>Electrochimica acta</title><description>The amino-substituted coumarin derivative of Tröger’s base (CTB) was electrochemically polymerized on the surface of gold electrodes. The obtained polymer films were characterized by SEM, Raman spectroscopy, cyclic voltammetry and in-situ conductometry. Spectroscopic analysis indicates that the polymerization of CTB takes place via oxidation of the aniline fragment of CTB molecule, similar to the polymerization of aniline. The similarity of the polymer backbone to that of the polyaniline is also confirmed by the influence of potential on the film’s conductivity, however the conductivity of the new material is in principle lower than that of polyaniline. SEM shows that the polymer forms a thin layer with a thickness of ∼100nm. Possible applications of the new material as an artificial receptor for aromatic analytes containing carboxy-group are proposed.</description><subject>Aniline</subject><subject>Coumarin</subject><subject>Electrochemical analysis</subject><subject>electrochemical polymerization</subject><subject>Electrodes</subject><subject>Gold</subject><subject>nitrogen heterocycle</subject><subject>Oxidation</subject><subject>Polyanilines</subject><subject>polymer film</subject><subject>Polymer films</subject><subject>polymeric Tröger’s base</subject><subject>Polymerization</subject><subject>Raman spectroscopy</subject><subject>Scanning electron microscopy</subject><subject>Spectroscopic analysis</subject><subject>spectroscopic characterization</subject><subject>Studies</subject><subject>Thickness</subject><issn>0013-4686</issn><issn>1873-3859</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqFUEtOwzAQtRBIlMIZiMQ6YWynqcOuqvhJldjA2nKcMXVJ4mKnSGXFNbgIF-AmnASX8lkijTTS0_vMPEKOKWQUaHG6yLBB3as4GYtARlkGBd0hAyrGPOViVO6SAQDlaV6IYp8chLAAgHExhgF5mLS2c2lYVaG3_arHOrn172_36D9eXkNSqYBnyVeAd3qOrdWqSZauWbfo7bPqresS1dWJnisfT_gDnUn6Of5QE2Ob9pDsGdUEPPreQ3J3cX47vUpnN5fX08ks1VxAn1alpiXNBeeUcRCF0Eozo5URCFRwzFWNZS1MxfJRATkDNEbnVOW1iRiUfEhOtr5L7x5XGHq5cCvfxUhJS84og1H0GZLxlqW9C8GjkUtvW-XXkoLcNCsX8rdZuWlWUiZjs1E52SoxPvFk0cugLXYaa-sjX9bO_uvxCau2ikQ</recordid><startdate>20170110</startdate><enddate>20170110</enddate><creator>Shishkanova, Tatiana V.</creator><creator>Havlík, Martin</creator><creator>Král, Vladimír</creator><creator>Kopecký, Dušan</creator><creator>Matějka, Pavel</creator><creator>Dendisová, Marcela</creator><creator>Mirsky, Vladimir M.</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20170110</creationdate><title>Amino-substituted Tröger’s base: electrochemical polymerization and characterization of the polymer film</title><author>Shishkanova, Tatiana V. ; Havlík, Martin ; Král, Vladimír ; Kopecký, Dušan ; Matějka, Pavel ; Dendisová, Marcela ; Mirsky, Vladimir M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c380t-b9c19148331230868cac2fcaf8e0183e4ade9d8fb24560420effc41a4dffb2093</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Aniline</topic><topic>Coumarin</topic><topic>Electrochemical analysis</topic><topic>electrochemical polymerization</topic><topic>Electrodes</topic><topic>Gold</topic><topic>nitrogen heterocycle</topic><topic>Oxidation</topic><topic>Polyanilines</topic><topic>polymer film</topic><topic>Polymer films</topic><topic>polymeric Tröger’s base</topic><topic>Polymerization</topic><topic>Raman spectroscopy</topic><topic>Scanning electron microscopy</topic><topic>Spectroscopic analysis</topic><topic>spectroscopic characterization</topic><topic>Studies</topic><topic>Thickness</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shishkanova, Tatiana V.</creatorcontrib><creatorcontrib>Havlík, Martin</creatorcontrib><creatorcontrib>Král, Vladimír</creatorcontrib><creatorcontrib>Kopecký, Dušan</creatorcontrib><creatorcontrib>Matějka, Pavel</creatorcontrib><creatorcontrib>Dendisová, Marcela</creatorcontrib><creatorcontrib>Mirsky, Vladimir M.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shishkanova, Tatiana V.</au><au>Havlík, Martin</au><au>Král, Vladimír</au><au>Kopecký, Dušan</au><au>Matějka, Pavel</au><au>Dendisová, Marcela</au><au>Mirsky, Vladimir M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Amino-substituted Tröger’s base: electrochemical polymerization and characterization of the polymer film</atitle><jtitle>Electrochimica acta</jtitle><date>2017-01-10</date><risdate>2017</risdate><volume>224</volume><spage>439</spage><epage>445</epage><pages>439-445</pages><issn>0013-4686</issn><eissn>1873-3859</eissn><abstract>The amino-substituted coumarin derivative of Tröger’s base (CTB) was electrochemically polymerized on the surface of gold electrodes. 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| subjects | Aniline Coumarin Electrochemical analysis electrochemical polymerization Electrodes Gold nitrogen heterocycle Oxidation Polyanilines polymer film Polymer films polymeric Tröger’s base Polymerization Raman spectroscopy Scanning electron microscopy Spectroscopic analysis spectroscopic characterization Studies Thickness |
| title | Amino-substituted Tröger’s base: electrochemical polymerization and characterization of the polymer film |
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