Improving the performance of organic light-emitting devices by incorporating non-doped TCNQ as electron buffer layer

The performance of organic light-emitting devices (OLEDs) is improved by inserting non-doped tetracyanoquinodimethane (TCNQ) electron buffer layer (EBL) between 4,7-diphnenyl-1,10-phe-nanthroline (Bphen) electron transport layer (ETL) and LiF/Al cathode. By optimizing the thickness of TCNQ layer, we...

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Veröffentlicht in:Journal of materials science. Materials in electronics 2017-09, Vol.28 (17), p.12761-12767
Hauptverfasser: Zhang, Juan, Xin, Liwen, Gao, Jian, Liu, Yang, Rui, Hongsong, Lin, Xin, Hua, Yulin, Wu, Xiaoming, Yin, Shougen
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container_end_page 12767
container_issue 17
container_start_page 12761
container_title Journal of materials science. Materials in electronics
container_volume 28
creator Zhang, Juan
Xin, Liwen
Gao, Jian
Liu, Yang
Rui, Hongsong
Lin, Xin
Hua, Yulin
Wu, Xiaoming
Yin, Shougen
description The performance of organic light-emitting devices (OLEDs) is improved by inserting non-doped tetracyanoquinodimethane (TCNQ) electron buffer layer (EBL) between 4,7-diphnenyl-1,10-phe-nanthroline (Bphen) electron transport layer (ETL) and LiF/Al cathode. By optimizing the thickness of TCNQ layer, we find that the device with 6 nm TCNQ buffer layer can achieve the best performance. The maximum luminance, current efficiency, power efficiency and half-lifetime of the optimal device are increased by 27.32, 51.70, 127.55, and 73.89%, respectively, compared with those of the control device without TCNQ buffer layer. This improvement can be attributed to that the insertion of non-doped TCNQ buffer layer which is a simple approach can enhance the electron injection and operational stability of the devices. Moreover, we have carried out the tests of the atomic force microscope (AFM), scanning electron microscopy (SEM) and Kelvin probe to explore the effect of insering TCNQ. These tests results further verify that TCNQ layer not only smooth the surface of the films but also improve the electron injection and transport characteristics. As a result, the performances of the OLEDs can be effectively improved.
doi_str_mv 10.1007/s10854-017-7103-3
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By optimizing the thickness of TCNQ layer, we find that the device with 6 nm TCNQ buffer layer can achieve the best performance. The maximum luminance, current efficiency, power efficiency and half-lifetime of the optimal device are increased by 27.32, 51.70, 127.55, and 73.89%, respectively, compared with those of the control device without TCNQ buffer layer. This improvement can be attributed to that the insertion of non-doped TCNQ buffer layer which is a simple approach can enhance the electron injection and operational stability of the devices. Moreover, we have carried out the tests of the atomic force microscope (AFM), scanning electron microscopy (SEM) and Kelvin probe to explore the effect of insering TCNQ. These tests results further verify that TCNQ layer not only smooth the surface of the films but also improve the electron injection and transport characteristics. 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Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>The performance of organic light-emitting devices (OLEDs) is improved by inserting non-doped tetracyanoquinodimethane (TCNQ) electron buffer layer (EBL) between 4,7-diphnenyl-1,10-phe-nanthroline (Bphen) electron transport layer (ETL) and LiF/Al cathode. By optimizing the thickness of TCNQ layer, we find that the device with 6 nm TCNQ buffer layer can achieve the best performance. The maximum luminance, current efficiency, power efficiency and half-lifetime of the optimal device are increased by 27.32, 51.70, 127.55, and 73.89%, respectively, compared with those of the control device without TCNQ buffer layer. This improvement can be attributed to that the insertion of non-doped TCNQ buffer layer which is a simple approach can enhance the electron injection and operational stability of the devices. 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subjects Atomic force microscopes
Atomic force microscopy
Buffers
Characterization and Evaluation of Materials
Chemistry and Materials Science
Current efficiency
Devices
Diodes
Electron transport
Materials Science
Optical and Electronic Materials
Optimization
Organic light emitting diodes
Power efficiency
Scanning electron microscopy
Service life assessment
Tetracyanoquinodimethane
Thickness
title Improving the performance of organic light-emitting devices by incorporating non-doped TCNQ as electron buffer layer
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