Synthesis, Characterization and Biological Activity of New 3-substitued-4-amino-5-hydrazino-1,2,4-triazole Schiff Bases and Their Cu(II) Complexes: A New Approach to CuO Nanoparticles for Photocatalytic Degradation of Methylene Blue Dye
Three new Schiff base compounds were synthesized via condensation of 3-R-4-amino-5-hydrazino-1,2,4-triazole with dibenzoylmethane [R = H, CH 3 , and CH 2 CH 3 namely L1, L2, and L3, respectively]. The synthesized Schiff bases were characterized using melting point, CHN elemental analyses, FT-IR, and...
Gespeichert in:
| Veröffentlicht in: | Journal of inorganic and organometallic polymers and materials 2017-09, Vol.27 (5), p.1220-1233 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1233 |
|---|---|
| container_issue | 5 |
| container_start_page | 1220 |
| container_title | Journal of inorganic and organometallic polymers and materials |
| container_volume | 27 |
| creator | Nassar, Mostafa Y. Aly, Hisham M. Moustafa, Moustafa E. Abdelrahman, Ehab A. |
| description | Three new Schiff base compounds were synthesized via condensation of 3-R-4-amino-5-hydrazino-1,2,4-triazole with dibenzoylmethane [R = H, CH
3
, and CH
2
CH
3
namely L1, L2, and L3, respectively]. The synthesized Schiff bases were characterized using melting point, CHN elemental analyses, FT-IR, and
1
H-NMR. The corresponding Cu(II) Schiff base complexes were synthesized via refluxing the prepared Schiff bases with CuCl
2
·2H
2
O. The synthesized complexes have been characterized by means of different spectral tools (FT-IR, ESR, and UV–Vis spectra) in addition to elemental analysis, magnetic moment, conductivity, and thermal analysis. The synthesized copper complexes are nonelectrolytes in
N,N
-dimethylformamide (DMF) based on their conductance values. Using modified Bauer-Kirby method, the Schiff bases and their Cu(II) complexes have been tested for antifungal (
Candida albicans
and
Aspergillus flavus
) and antibacterial (
Staphylococcus aureus
and
Escherichia coli
) activities. Moreover, CuO nanoparticles were produced via thermal decomposition of the synthesized Cu(II) complexes at 650 °C. The produced nanoparticles were characterized using XRD, HR-TEM, FT-IR, and UV–Vis spectroscopy. The CuO nanostructures exhibited good photocatalytic activity for the degradation of methylene blue dye in the presence of hydrogen peroxide with 77.36% degradation efficiency in 360 min.
Graphical Abstract
Proposed structure of the synthesized Cu(II) complexes |
| doi_str_mv | 10.1007/s10904-017-0569-x |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1929825871</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1929825871</sourcerecordid><originalsourceid>FETCH-LOGICAL-c353t-32d9c010e7c6345734082ba9132b3724cb3507caf238c8ddacd33600c3e6c4373</originalsourceid><addsrcrecordid>eNp1UcFu1DAUjBBIlMIHcLPEBaQ12LGzSbjtprSsVFqklnP01nnZuPLGwXZgs9_MR-BtEOLC6Y2eZubN0yTJa87ec8byD56zkknKeE5Ztizp4UlyxrNcUi4z_vQvluJ58sL7B8ZEwTJ-lvy6m_rQodd-QaoOHKiATh8haNsT6Buy1tbYnVZgyEoF_UOHidiW3OBPIqgftz7oMGJDJYW97i3NaDc1Do4nzBfpQtLgNBytQXKnOt22ZA0e_aP3fYfakWp8u9m8I5XdDwYP6D-S1aP9ahicBdWRYCPnltxAbwdwQSsT9a115Gtng1UQwExxSy5w56CZo8eIXzB0k8EeydqMSC4mfJk8a8F4fPVnniffLj_dV5_p9e3VplpdUyUyEahIm1IxzjBXSyGzXEhWpFsouUi3Ik-l2oqM5QraVBSqaBpQjRBLxpTApZIiF-fJm9k3PvB9RB_qBzu6Pp6seZmWRZoVOY8sPrOUs947bOvB6T24qeasPpVaz6XWsdT6VGp9iJp01vjI7Xfo_nH-r-g30SOnHA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1929825871</pqid></control><display><type>article</type><title>Synthesis, Characterization and Biological Activity of New 3-substitued-4-amino-5-hydrazino-1,2,4-triazole Schiff Bases and Their Cu(II) Complexes: A New Approach to CuO Nanoparticles for Photocatalytic Degradation of Methylene Blue Dye</title><source>SpringerLink Journals - AutoHoldings</source><creator>Nassar, Mostafa Y. ; Aly, Hisham M. ; Moustafa, Moustafa E. ; Abdelrahman, Ehab A.</creator><creatorcontrib>Nassar, Mostafa Y. ; Aly, Hisham M. ; Moustafa, Moustafa E. ; Abdelrahman, Ehab A.</creatorcontrib><description>Three new Schiff base compounds were synthesized via condensation of 3-R-4-amino-5-hydrazino-1,2,4-triazole with dibenzoylmethane [R = H, CH
3
, and CH
2
CH
3
namely L1, L2, and L3, respectively]. The synthesized Schiff bases were characterized using melting point, CHN elemental analyses, FT-IR, and
1
H-NMR. The corresponding Cu(II) Schiff base complexes were synthesized via refluxing the prepared Schiff bases with CuCl
2
·2H
2
O. The synthesized complexes have been characterized by means of different spectral tools (FT-IR, ESR, and UV–Vis spectra) in addition to elemental analysis, magnetic moment, conductivity, and thermal analysis. The synthesized copper complexes are nonelectrolytes in
N,N
-dimethylformamide (DMF) based on their conductance values. Using modified Bauer-Kirby method, the Schiff bases and their Cu(II) complexes have been tested for antifungal (
Candida albicans
and
Aspergillus flavus
) and antibacterial (
Staphylococcus aureus
and
Escherichia coli
) activities. Moreover, CuO nanoparticles were produced via thermal decomposition of the synthesized Cu(II) complexes at 650 °C. The produced nanoparticles were characterized using XRD, HR-TEM, FT-IR, and UV–Vis spectroscopy. The CuO nanostructures exhibited good photocatalytic activity for the degradation of methylene blue dye in the presence of hydrogen peroxide with 77.36% degradation efficiency in 360 min.
Graphical Abstract
Proposed structure of the synthesized Cu(II) complexes</description><identifier>ISSN: 1574-1443</identifier><identifier>EISSN: 1574-1451</identifier><identifier>DOI: 10.1007/s10904-017-0569-x</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Biological activity ; Catalytic activity ; Chemistry ; Chemistry and Materials Science ; Coordination compounds ; Copper compounds ; Copper oxides ; Degradation ; Dyes ; E coli ; Fourier transforms ; Fungicides ; Hydrogen peroxide ; Infrared radiation ; Infrared spectroscopy ; Inorganic Chemistry ; Magnetic moments ; Methylene blue ; Nanoparticles ; Nonelectrolytes ; Organic Chemistry ; Photocatalysis ; Polymer Sciences ; Resistance ; Spectrum analysis ; Synthesis ; Thermal analysis ; Thermal decomposition</subject><ispartof>Journal of inorganic and organometallic polymers and materials, 2017-09, Vol.27 (5), p.1220-1233</ispartof><rights>Springer Science+Business Media New York 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-32d9c010e7c6345734082ba9132b3724cb3507caf238c8ddacd33600c3e6c4373</citedby><cites>FETCH-LOGICAL-c353t-32d9c010e7c6345734082ba9132b3724cb3507caf238c8ddacd33600c3e6c4373</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10904-017-0569-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10904-017-0569-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Nassar, Mostafa Y.</creatorcontrib><creatorcontrib>Aly, Hisham M.</creatorcontrib><creatorcontrib>Moustafa, Moustafa E.</creatorcontrib><creatorcontrib>Abdelrahman, Ehab A.</creatorcontrib><title>Synthesis, Characterization and Biological Activity of New 3-substitued-4-amino-5-hydrazino-1,2,4-triazole Schiff Bases and Their Cu(II) Complexes: A New Approach to CuO Nanoparticles for Photocatalytic Degradation of Methylene Blue Dye</title><title>Journal of inorganic and organometallic polymers and materials</title><addtitle>J Inorg Organomet Polym</addtitle><description>Three new Schiff base compounds were synthesized via condensation of 3-R-4-amino-5-hydrazino-1,2,4-triazole with dibenzoylmethane [R = H, CH
3
, and CH
2
CH
3
namely L1, L2, and L3, respectively]. The synthesized Schiff bases were characterized using melting point, CHN elemental analyses, FT-IR, and
1
H-NMR. The corresponding Cu(II) Schiff base complexes were synthesized via refluxing the prepared Schiff bases with CuCl
2
·2H
2
O. The synthesized complexes have been characterized by means of different spectral tools (FT-IR, ESR, and UV–Vis spectra) in addition to elemental analysis, magnetic moment, conductivity, and thermal analysis. The synthesized copper complexes are nonelectrolytes in
N,N
-dimethylformamide (DMF) based on their conductance values. Using modified Bauer-Kirby method, the Schiff bases and their Cu(II) complexes have been tested for antifungal (
Candida albicans
and
Aspergillus flavus
) and antibacterial (
Staphylococcus aureus
and
Escherichia coli
) activities. Moreover, CuO nanoparticles were produced via thermal decomposition of the synthesized Cu(II) complexes at 650 °C. The produced nanoparticles were characterized using XRD, HR-TEM, FT-IR, and UV–Vis spectroscopy. The CuO nanostructures exhibited good photocatalytic activity for the degradation of methylene blue dye in the presence of hydrogen peroxide with 77.36% degradation efficiency in 360 min.
Graphical Abstract
Proposed structure of the synthesized Cu(II) complexes</description><subject>Biological activity</subject><subject>Catalytic activity</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination compounds</subject><subject>Copper compounds</subject><subject>Copper oxides</subject><subject>Degradation</subject><subject>Dyes</subject><subject>E coli</subject><subject>Fourier transforms</subject><subject>Fungicides</subject><subject>Hydrogen peroxide</subject><subject>Infrared radiation</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Magnetic moments</subject><subject>Methylene blue</subject><subject>Nanoparticles</subject><subject>Nonelectrolytes</subject><subject>Organic Chemistry</subject><subject>Photocatalysis</subject><subject>Polymer Sciences</subject><subject>Resistance</subject><subject>Spectrum analysis</subject><subject>Synthesis</subject><subject>Thermal analysis</subject><subject>Thermal decomposition</subject><issn>1574-1443</issn><issn>1574-1451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1UcFu1DAUjBBIlMIHcLPEBaQ12LGzSbjtprSsVFqklnP01nnZuPLGwXZgs9_MR-BtEOLC6Y2eZubN0yTJa87ec8byD56zkknKeE5Ztizp4UlyxrNcUi4z_vQvluJ58sL7B8ZEwTJ-lvy6m_rQodd-QaoOHKiATh8haNsT6Buy1tbYnVZgyEoF_UOHidiW3OBPIqgftz7oMGJDJYW97i3NaDc1Do4nzBfpQtLgNBytQXKnOt22ZA0e_aP3fYfakWp8u9m8I5XdDwYP6D-S1aP9ahicBdWRYCPnltxAbwdwQSsT9a115Gtng1UQwExxSy5w56CZo8eIXzB0k8EeydqMSC4mfJk8a8F4fPVnniffLj_dV5_p9e3VplpdUyUyEahIm1IxzjBXSyGzXEhWpFsouUi3Ik-l2oqM5QraVBSqaBpQjRBLxpTApZIiF-fJm9k3PvB9RB_qBzu6Pp6seZmWRZoVOY8sPrOUs947bOvB6T24qeasPpVaz6XWsdT6VGp9iJp01vjI7Xfo_nH-r-g30SOnHA</recordid><startdate>20170901</startdate><enddate>20170901</enddate><creator>Nassar, Mostafa Y.</creator><creator>Aly, Hisham M.</creator><creator>Moustafa, Moustafa E.</creator><creator>Abdelrahman, Ehab A.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20170901</creationdate><title>Synthesis, Characterization and Biological Activity of New 3-substitued-4-amino-5-hydrazino-1,2,4-triazole Schiff Bases and Their Cu(II) Complexes: A New Approach to CuO Nanoparticles for Photocatalytic Degradation of Methylene Blue Dye</title><author>Nassar, Mostafa Y. ; Aly, Hisham M. ; Moustafa, Moustafa E. ; Abdelrahman, Ehab A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-32d9c010e7c6345734082ba9132b3724cb3507caf238c8ddacd33600c3e6c4373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Biological activity</topic><topic>Catalytic activity</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination compounds</topic><topic>Copper compounds</topic><topic>Copper oxides</topic><topic>Degradation</topic><topic>Dyes</topic><topic>E coli</topic><topic>Fourier transforms</topic><topic>Fungicides</topic><topic>Hydrogen peroxide</topic><topic>Infrared radiation</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Magnetic moments</topic><topic>Methylene blue</topic><topic>Nanoparticles</topic><topic>Nonelectrolytes</topic><topic>Organic Chemistry</topic><topic>Photocatalysis</topic><topic>Polymer Sciences</topic><topic>Resistance</topic><topic>Spectrum analysis</topic><topic>Synthesis</topic><topic>Thermal analysis</topic><topic>Thermal decomposition</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nassar, Mostafa Y.</creatorcontrib><creatorcontrib>Aly, Hisham M.</creatorcontrib><creatorcontrib>Moustafa, Moustafa E.</creatorcontrib><creatorcontrib>Abdelrahman, Ehab A.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nassar, Mostafa Y.</au><au>Aly, Hisham M.</au><au>Moustafa, Moustafa E.</au><au>Abdelrahman, Ehab A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, Characterization and Biological Activity of New 3-substitued-4-amino-5-hydrazino-1,2,4-triazole Schiff Bases and Their Cu(II) Complexes: A New Approach to CuO Nanoparticles for Photocatalytic Degradation of Methylene Blue Dye</atitle><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle><stitle>J Inorg Organomet Polym</stitle><date>2017-09-01</date><risdate>2017</risdate><volume>27</volume><issue>5</issue><spage>1220</spage><epage>1233</epage><pages>1220-1233</pages><issn>1574-1443</issn><eissn>1574-1451</eissn><abstract>Three new Schiff base compounds were synthesized via condensation of 3-R-4-amino-5-hydrazino-1,2,4-triazole with dibenzoylmethane [R = H, CH
3
, and CH
2
CH
3
namely L1, L2, and L3, respectively]. The synthesized Schiff bases were characterized using melting point, CHN elemental analyses, FT-IR, and
1
H-NMR. The corresponding Cu(II) Schiff base complexes were synthesized via refluxing the prepared Schiff bases with CuCl
2
·2H
2
O. The synthesized complexes have been characterized by means of different spectral tools (FT-IR, ESR, and UV–Vis spectra) in addition to elemental analysis, magnetic moment, conductivity, and thermal analysis. The synthesized copper complexes are nonelectrolytes in
N,N
-dimethylformamide (DMF) based on their conductance values. Using modified Bauer-Kirby method, the Schiff bases and their Cu(II) complexes have been tested for antifungal (
Candida albicans
and
Aspergillus flavus
) and antibacterial (
Staphylococcus aureus
and
Escherichia coli
) activities. Moreover, CuO nanoparticles were produced via thermal decomposition of the synthesized Cu(II) complexes at 650 °C. The produced nanoparticles were characterized using XRD, HR-TEM, FT-IR, and UV–Vis spectroscopy. The CuO nanostructures exhibited good photocatalytic activity for the degradation of methylene blue dye in the presence of hydrogen peroxide with 77.36% degradation efficiency in 360 min.
Graphical Abstract
Proposed structure of the synthesized Cu(II) complexes</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10904-017-0569-x</doi><tpages>14</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1574-1443 |
| ispartof | Journal of inorganic and organometallic polymers and materials, 2017-09, Vol.27 (5), p.1220-1233 |
| issn | 1574-1443 1574-1451 |
| language | eng |
| recordid | cdi_proquest_journals_1929825871 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Biological activity Catalytic activity Chemistry Chemistry and Materials Science Coordination compounds Copper compounds Copper oxides Degradation Dyes E coli Fourier transforms Fungicides Hydrogen peroxide Infrared radiation Infrared spectroscopy Inorganic Chemistry Magnetic moments Methylene blue Nanoparticles Nonelectrolytes Organic Chemistry Photocatalysis Polymer Sciences Resistance Spectrum analysis Synthesis Thermal analysis Thermal decomposition |
| title | Synthesis, Characterization and Biological Activity of New 3-substitued-4-amino-5-hydrazino-1,2,4-triazole Schiff Bases and Their Cu(II) Complexes: A New Approach to CuO Nanoparticles for Photocatalytic Degradation of Methylene Blue Dye |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-27T20%3A17%3A41IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis,%20Characterization%20and%20Biological%20Activity%20of%20New%203-substitued-4-amino-5-hydrazino-1,2,4-triazole%20Schiff%20Bases%20and%20Their%20Cu(II)%20Complexes:%20A%20New%20Approach%20to%20CuO%20Nanoparticles%20for%20Photocatalytic%20Degradation%20of%20Methylene%20Blue%20Dye&rft.jtitle=Journal%20of%20inorganic%20and%20organometallic%20polymers%20and%20materials&rft.au=Nassar,%20Mostafa%20Y.&rft.date=2017-09-01&rft.volume=27&rft.issue=5&rft.spage=1220&rft.epage=1233&rft.pages=1220-1233&rft.issn=1574-1443&rft.eissn=1574-1451&rft_id=info:doi/10.1007/s10904-017-0569-x&rft_dat=%3Cproquest_cross%3E1929825871%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1929825871&rft_id=info:pmid/&rfr_iscdi=true |