Cleaning graphene: Comparing heat treatments in air and in vacuum

Surface impurities and contamination often seriously degrade the properties of two‐dimensional materials such as graphene. To remove contamination, thermal annealing is commonly used. We present a comparative analysis of annealing treatments in air and in vacuum, both ex situ and “pre situ,” where an ultra‐high vacuum treatment chamber is directly connected to an aberration‐corrected scanning transmission electron microscope. While ex situ treatments do remove contamination, it is challenging to obtain atomically clean surfaces after ambient transfer. However, pre situ cleaning with radiative or laser heating appears reliable and well suited to clean graphene without damage to most suspended areas. Pre situ annealing of typical dirty graphene samples yields atomically clean areas several hundred nm2 in size. One‐atom‐thick graphene is often covered by adsorbed contamination, often making it challenging to observe and manipulate its atomic structure. By heating the sample in a vacuum chamber directly connected to an electron microscope, it is possible to obtain large atomically clean areas to enable many further studies.