Dealing at Arm's Length: Catalysis with N‐Heterocyclic Carbene Ligands Bearing Anionic Tethers
The catalytic transformations enabled by bidentate N‐heterocyclic carbenes bearing anionic substituents (tethered NHCs) are presented. The use of tethered NHCs as a ligand class for transition‐metal‐catalyzed reactions and their employment in organocatalytic and Lewis‐base‐catalyzed processes is dis...
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| Veröffentlicht in: | European journal of organic chemistry 2017-08, Vol.2017 (29), p.4206-4229 |
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| container_title | European journal of organic chemistry |
| container_volume | 2017 |
| creator | Pape, Felix Teichert, Johannes F. |
| description | The catalytic transformations enabled by bidentate N‐heterocyclic carbenes bearing anionic substituents (tethered NHCs) are presented. The use of tethered NHCs as a ligand class for transition‐metal‐catalyzed reactions and their employment in organocatalytic and Lewis‐base‐catalyzed processes is discussed, with a focus on the influence of the anionic tether on the catalyzed reactions of interest.
An overview of the applications of bidentate N‐heterocyclic carbenes (NHCs) bearing anionic heteroatom‐based tethers in catalysis is presented. |
| doi_str_mv | 10.1002/ejoc.201700124 |
| format | Article |
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An overview of the applications of bidentate N‐heterocyclic carbenes (NHCs) bearing anionic heteroatom‐based tethers in catalysis is presented.</description><subject>Asymmetric catalysis</subject><subject>Carbene ligands</subject><subject>Carbenes</subject><subject>Catalysis</subject><subject>Chemical reactions</subject><subject>N‐heterocyclic carbenes</subject><subject>Reaction mechanisms</subject><subject>Selectivity</subject><subject>Tethers</subject><issn>1434-193X</issn><issn>1099-0690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqFkDFPwzAQhSMEEqWwMltiYEo5J5Yds5VQKCiiS5HYjONcWldpAnaqKhs_gd_ILyFVEYxMd9L73jvdC4JzCiMKEF3hqjGjCKgAoBE7CAYUpAyBSzjsdxazkMr45Tg48X4FAJJzOgheb1FXtl4Q3ZKxW196kmG9aJfXJNWtrjpvPdnadkmevj4-p9iia0xnKmt63eVYI8nsQteFJzeo3S5oXNum7vU5tkt0_jQ4KnXl8exnDoPnu8k8nYbZ7P4hHWehialgITKIysSYnDGUZaE55KzkXMda0qSI4sSwUvY_UBA8z7UQwBNRYAHABeQ8j4fBxT73zTXvG_StWjUbV_cnFZWRYBxAsJ4a7SnjGu8dlurN2bV2naKgdi2qXYvqt8XeIPeGra2w-4dWk8dZ-uf9BuUxdoc</recordid><startdate>20170810</startdate><enddate>20170810</enddate><creator>Pape, Felix</creator><creator>Teichert, Johannes F.</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-0057-4306</orcidid><orcidid>https://orcid.org/0000-0003-1043-8092</orcidid></search><sort><creationdate>20170810</creationdate><title>Dealing at Arm's Length: Catalysis with N‐Heterocyclic Carbene Ligands Bearing Anionic Tethers</title><author>Pape, Felix ; Teichert, Johannes F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3174-e402f8ccb44e9fda60b4f66a3a918d238c4f94341076bba770687ded00670b6b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Asymmetric catalysis</topic><topic>Carbene ligands</topic><topic>Carbenes</topic><topic>Catalysis</topic><topic>Chemical reactions</topic><topic>N‐heterocyclic carbenes</topic><topic>Reaction mechanisms</topic><topic>Selectivity</topic><topic>Tethers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pape, Felix</creatorcontrib><creatorcontrib>Teichert, Johannes F.</creatorcontrib><collection>CrossRef</collection><jtitle>European journal of organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pape, Felix</au><au>Teichert, Johannes F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dealing at Arm's Length: Catalysis with N‐Heterocyclic Carbene Ligands Bearing Anionic Tethers</atitle><jtitle>European journal of organic chemistry</jtitle><date>2017-08-10</date><risdate>2017</risdate><volume>2017</volume><issue>29</issue><spage>4206</spage><epage>4229</epage><pages>4206-4229</pages><issn>1434-193X</issn><eissn>1099-0690</eissn><abstract>The catalytic transformations enabled by bidentate N‐heterocyclic carbenes bearing anionic substituents (tethered NHCs) are presented. The use of tethered NHCs as a ligand class for transition‐metal‐catalyzed reactions and their employment in organocatalytic and Lewis‐base‐catalyzed processes is discussed, with a focus on the influence of the anionic tether on the catalyzed reactions of interest.
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| issn | 1434-193X 1099-0690 |
| language | eng |
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| subjects | Asymmetric catalysis Carbene ligands Carbenes Catalysis Chemical reactions N‐heterocyclic carbenes Reaction mechanisms Selectivity Tethers |
| title | Dealing at Arm's Length: Catalysis with N‐Heterocyclic Carbene Ligands Bearing Anionic Tethers |
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