Large reduction in electrical contact resistance of flexible carbon nanotube/silicone rubber composites by trifluoroacetic acid treatment

We report a large reduction in contact resistance between stretchable carbon nanotube/silicone rubber composites and silver electrodes by a chemical surface treatment, accompanied by an enhancement in the electrical conductivity of the composites. The reactive solvent, trifluoroacetic acid, works fo...

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Veröffentlicht in:Composites science and technology 2017-05, Vol.143, p.98-105
Hauptverfasser: Lee, Sang-Eui, Jee, Sang Soo, Park, Hyokeun, Park, Sung-Hoon, Han, Intaek, Mizusaki, Soichiro
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container_end_page 105
container_issue
container_start_page 98
container_title Composites science and technology
container_volume 143
creator Lee, Sang-Eui
Jee, Sang Soo
Park, Hyokeun
Park, Sung-Hoon
Han, Intaek
Mizusaki, Soichiro
description We report a large reduction in contact resistance between stretchable carbon nanotube/silicone rubber composites and silver electrodes by a chemical surface treatment, accompanied by an enhancement in the electrical conductivity of the composites. The reactive solvent, trifluoroacetic acid, works for the purpose. In addition, the treatment makes a uniform etching in a micro level with little sacrifice in surface roughness of the nanocomposites. The electrical conductivity of 1.0 wt% nanotube composite was enhanced approximately two-fold and three-fold by ten- and thirty-second treatment, which was induced by the reduction in the contact resistance to one half of an original value. It is meaningful that our finding can be an approach to reduce the nanoparticle loading while keeping electrical conductivity in a high level, which can be crucial for securing flexibility or stretchability in a viewpoint that the elongation is inversely proportional to the conductive particle loading.
doi_str_mv 10.1016/j.compscitech.2017.03.004
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subjects Carbon nanotube
Composite materials
Contact resistance
Electric contacts
Electric resistance
Electrical contact resistance
Electrical resistance
Electrical resistivity
Elongation
Etching
Flexible composite
Nanocomposites
Nanotubes
Reduction
Silicone rubber
Silicones
Stretchability
Stretchable composite
Studies
Surface roughness
Surface treatment
Trifluoroacetic acid
title Large reduction in electrical contact resistance of flexible carbon nanotube/silicone rubber composites by trifluoroacetic acid treatment
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