Frontispiece: Excess Electron Transfer through DNA Duplexes Comprising a Metal‐Mediated Base Pair
DNA‐mediated charge transfer represents a topical area of research. The influence of the site‐specific introduction of a metal ion into the base pair stack is a matter of current debate. In their communication on page 10244 ff., U. Karst, J. Müller et al. contribute to this debate by reporting an ex...
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| Veröffentlicht in: | Chemistry : a European journal 2017-08, Vol.23 (43), p.n/a |
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| container_title | Chemistry : a European journal |
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| creator | Hensel, Susanne Eckey, Kevin Scharf, Philipp Megger, Nicole Karst, Uwe Müller, Jens |
| description | DNA‐mediated charge transfer represents a topical area of research. The influence of the site‐specific introduction of a metal ion into the base pair stack is a matter of current debate. In their communication on page 10244 ff., U. Karst, J. Müller et al. contribute to this debate by reporting an experimental study on excess electron transfer across a metal‐mediated base pair within a DNA double helix. To this end, LC/ICP‐MS was applied for the first time to quantify the electron‐transfer efficiency. The data suggest that a thymine–HgII–thymine base pair influences charge transfer in the same way as a thymine:thymine mispair does. |
| doi_str_mv | 10.1002/chem.201784362 |
| format | Article |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Charge transfer Chemistry Data transfer (computers) Deoxyribonucleic acid DNA DNA polymerase Electron transfer Karst mercury metal-mediated base pair Metals Thymine |
| title | Frontispiece: Excess Electron Transfer through DNA Duplexes Comprising a Metal‐Mediated Base Pair |
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