Group preconcentration of ions from acid aqueous solutions with a low-melting extractant
A possibility of the analytical application of a low-melting extractant, antipyrinium acetylsalicylate, to the extraction of a number of ions from acid aqueous solutions is studied. The distribution of Al, As, Cd, Co, Cr, Cu, Fe, Mg, Mn, Mo, Ni, Pb, Sb, Sn, Ti, V, and Zn ions between the aqueous sol...
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| Veröffentlicht in: | Journal of analytical chemistry (New York, N.Y.) N.Y.), 2017-08, Vol.72 (8), p.849-853 |
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| container_title | Journal of analytical chemistry (New York, N.Y.) |
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| creator | Temerev, S. V. Petrov, B. I. Savakova, Yu. P. |
| description | A possibility of the analytical application of a low-melting extractant, antipyrinium acetylsalicylate, to the extraction of a number of ions from acid aqueous solutions is studied. The distribution of Al, As, Cd, Co, Cr, Cu, Fe, Mg, Mn, Mo, Ni, Pb, Sb, Sn, Ti, V, and Zn ions between the aqueous solution and an organic extractant is studied by atomic emission spectrometry. The efficiency of ion extraction from acid solutions with a low-melting flux of antipyrinium acetylsalicylate is calculated. It is shown that single extraction with an extractant flux ensures the efficient extraction of Fe, Mo, Sn, and Ti from the water phase of the analyzed solution to the flux. The introduction of chloride ions into the analyzed acid aqueous solution significantly increases the efficiency of the group preconcentration of ions by the ion-exchange mechanism. |
| doi_str_mv | 10.1134/S1061934817080123 |
| format | Article |
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The introduction of chloride ions into the analyzed acid aqueous solution significantly increases the efficiency of the group preconcentration of ions by the ion-exchange mechanism.</description><identifier>ISSN: 1061-9348</identifier><identifier>EISSN: 1608-3199</identifier><identifier>DOI: 10.1134/S1061934817080123</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Acids ; Aluminum ; Analytical Chemistry ; Antimony ; Aqueous solutions ; Cadmium ; Chemical properties ; Chemistry ; Chemistry and Materials Science ; Chloride ions ; Chromium ; Cobalt ; Copper ; Emission analysis ; Extraction (Chemistry) ; Flux ; Ion exchange ; Ion extraction ; Ions ; Iron ; Lead ; Magnesium ; Manganese ; Melting ; Methods ; Molybdenum ; Nickel ; Salicylates ; Spectrometry ; Titanium</subject><ispartof>Journal of analytical chemistry (New York, N.Y.), 2017-08, Vol.72 (8), p.849-853</ispartof><rights>Pleiades Publishing, Ltd. 2017</rights><rights>COPYRIGHT 2017 Springer</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c407t-ad8cd494530c40082ea7a34b8cf71cd892d1dcbd92c93f046536338108a2f1133</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1061934817080123$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1061934817080123$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Temerev, S. V.</creatorcontrib><creatorcontrib>Petrov, B. I.</creatorcontrib><creatorcontrib>Savakova, Yu. P.</creatorcontrib><title>Group preconcentration of ions from acid aqueous solutions with a low-melting extractant</title><title>Journal of analytical chemistry (New York, N.Y.)</title><addtitle>J Anal Chem</addtitle><description>A possibility of the analytical application of a low-melting extractant, antipyrinium acetylsalicylate, to the extraction of a number of ions from acid aqueous solutions is studied. The distribution of Al, As, Cd, Co, Cr, Cu, Fe, Mg, Mn, Mo, Ni, Pb, Sb, Sn, Ti, V, and Zn ions between the aqueous solution and an organic extractant is studied by atomic emission spectrometry. The efficiency of ion extraction from acid solutions with a low-melting flux of antipyrinium acetylsalicylate is calculated. It is shown that single extraction with an extractant flux ensures the efficient extraction of Fe, Mo, Sn, and Ti from the water phase of the analyzed solution to the flux. The introduction of chloride ions into the analyzed acid aqueous solution significantly increases the efficiency of the group preconcentration of ions by the ion-exchange mechanism.</description><subject>Acids</subject><subject>Aluminum</subject><subject>Analytical Chemistry</subject><subject>Antimony</subject><subject>Aqueous solutions</subject><subject>Cadmium</subject><subject>Chemical properties</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chloride ions</subject><subject>Chromium</subject><subject>Cobalt</subject><subject>Copper</subject><subject>Emission analysis</subject><subject>Extraction (Chemistry)</subject><subject>Flux</subject><subject>Ion exchange</subject><subject>Ion extraction</subject><subject>Ions</subject><subject>Iron</subject><subject>Lead</subject><subject>Magnesium</subject><subject>Manganese</subject><subject>Melting</subject><subject>Methods</subject><subject>Molybdenum</subject><subject>Nickel</subject><subject>Salicylates</subject><subject>Spectrometry</subject><subject>Titanium</subject><issn>1061-9348</issn><issn>1608-3199</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kU1LJDEQhptlhXXVH-At4GkPPaaSTHdyHIbdURAEP8BbiOmkjXQns0kad_-9GUfYHRzJoUK9z1upVFXVKeAZAGXnt4AbEJRxaDHHQOiX6hAazGsKQnwt9yLXG_1b9T2lZ4yx4NAcVg-rGKY1Wkejg9fG56iyCx4Fi0pIyMYwIqVdh9TvyYQpoRSGKb9pLy4_IYWG8FKPZsjO98j8KQV0Vj4fVwdWDcmcvMej6v7Xz7vlRX11vbpcLq5qzXCba9Vx3THB5hSXBObEqFZR9si1bUF3XJAOOv3YCaIFtZg1c9pQygFzRWz5OT2qzrZ11zGUDlOWz2GKvjwpQRBGGmha8Y_q1WCk8zZs-hxd0nIxB9YS1kJTqHoP1RtvohqCN9aV9A4_28OX05nR6b2GHzuGwuQysl5NKcnL25tdFrasjiGlaKxcRzeq-FcClpudyw87Lx6y9aTC-t7E_4bxqekV1r6q3g</recordid><startdate>20170801</startdate><enddate>20170801</enddate><creator>Temerev, S. V.</creator><creator>Petrov, B. I.</creator><creator>Savakova, Yu. P.</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20170801</creationdate><title>Group preconcentration of ions from acid aqueous solutions with a low-melting extractant</title><author>Temerev, S. V. ; Petrov, B. I. ; Savakova, Yu. 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V.</creatorcontrib><creatorcontrib>Petrov, B. I.</creatorcontrib><creatorcontrib>Savakova, Yu. P.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Temerev, S. V.</au><au>Petrov, B. I.</au><au>Savakova, Yu. P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Group preconcentration of ions from acid aqueous solutions with a low-melting extractant</atitle><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle><stitle>J Anal Chem</stitle><date>2017-08-01</date><risdate>2017</risdate><volume>72</volume><issue>8</issue><spage>849</spage><epage>853</epage><pages>849-853</pages><issn>1061-9348</issn><eissn>1608-3199</eissn><abstract>A possibility of the analytical application of a low-melting extractant, antipyrinium acetylsalicylate, to the extraction of a number of ions from acid aqueous solutions is studied. The distribution of Al, As, Cd, Co, Cr, Cu, Fe, Mg, Mn, Mo, Ni, Pb, Sb, Sn, Ti, V, and Zn ions between the aqueous solution and an organic extractant is studied by atomic emission spectrometry. The efficiency of ion extraction from acid solutions with a low-melting flux of antipyrinium acetylsalicylate is calculated. It is shown that single extraction with an extractant flux ensures the efficient extraction of Fe, Mo, Sn, and Ti from the water phase of the analyzed solution to the flux. The introduction of chloride ions into the analyzed acid aqueous solution significantly increases the efficiency of the group preconcentration of ions by the ion-exchange mechanism.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1061934817080123</doi><tpages>5</tpages></addata></record> |
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| subjects | Acids Aluminum Analytical Chemistry Antimony Aqueous solutions Cadmium Chemical properties Chemistry Chemistry and Materials Science Chloride ions Chromium Cobalt Copper Emission analysis Extraction (Chemistry) Flux Ion exchange Ion extraction Ions Iron Lead Magnesium Manganese Melting Methods Molybdenum Nickel Salicylates Spectrometry Titanium |
| title | Group preconcentration of ions from acid aqueous solutions with a low-melting extractant |
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